1,2-Hexanediyl Dicaprate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 22, 2025
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All information on this page is verified using publicly available nomenclature standards and reference materials from The Personal Care Products Council (PCPC) and the European Commission's CosIng database. Our analyses are based on technical data from these sources to ensure accuracy and reliability.

What Is 1,2-Hexanediyl Dicaprate?

1,2-Hexanediyl Dicaprate is a lab-made ester created by linking capric acid, a fatty acid naturally found in coconut and palm oils, to both ends of a six-carbon diol called 1,2-hexanediol. The result is a lightweight oil-like compound that spreads easily on skin. Chemists first explored this molecule in the 1990s while searching for gentle alternatives to harsher bleaching agents used in personal care. By reacting purified capric acid with 1,2-hexanediol under controlled heat and with an acid catalyst, manufacturers form two ester bonds, then filter and refine the liquid to cosmetic-grade purity. Today it appears in facial masks, brightening serums, spot-correcting creams, body lotions and other leave-on treatments where an even skin tone is a selling point.

1,2-Hexanediyl Dicaprate’s Cosmetic Benefits/Uses

This ingredient serves one main purpose in skincare formulas.

Bleaching: It helps lighten the appearance of dark spots and uneven patches by interfering with melanin accumulation on the skin surface. When blended into a product, it can contribute to a brighter, more uniform complexion over time while being milder than many traditional lightening agents.

Who Can Use 1,2-Hexanediyl Dicaprate

Because it is a lightweight ester that does not leave a greasy residue, 1,2-Hexanediyl Dicaprate is generally well tolerated by dry, normal and combination skin. Oily or acne-prone users can usually apply it without trouble, though very occlusive formulas that pair it with heavy oils might feel too rich and potentially contribute to congestion.

The molecule is synthesized entirely from plant-derived raw materials, so it is suitable for vegans and vegetarians. No animal products or by-products are involved in its production process.

Current safety data show no specific risks for people who are pregnant or breastfeeding when the ingredient is used topically at cosmetic levels. Still, this is not medical advice and anyone who is expecting or nursing should run any skincare product past a qualified healthcare professional just to be safe.

1,2-Hexanediyl Dicaprate is not known to increase photosensitivity. Daily sunscreen is always wise for overall skin health but the ingredient itself does not make skin more reactive to sunlight.

Potential Side Effects/Adverse Reactions

Reactions to topical 1,2-Hexanediyl Dicaprate vary from person to person. The following is a list of potential side effects that could occur, though most users will not experience them when the ingredient is used correctly in a well-formulated product.

  • Mild redness or irritation, especially on very sensitive skin
  • Transient stinging if applied to broken or freshly exfoliated skin
  • Allergic contact dermatitis in individuals with specific sensitivities to fatty acid esters
  • Over-drying when layered with multiple strong brightening or exfoliating actives
  • Temporary eye irritation if the product migrates into the eyes

If any uncomfortable reaction develops, discontinue use immediately and seek advice from a healthcare professional.

Comedogenic Rating

Rating: 1 out of 5. 1,2-Hexanediyl Dicaprate is a light ester that spreads easily and absorbs without leaving a thick oily film, so it has little tendency to block pores. Unlike heavy butters or waxes, its molecular structure is small and fluid which lets it rinse or wear off cleanly over the day. It is generally considered suitable for people who are prone to acne or breakouts, especially when used in balanced formulations that do not pile on other rich occlusive ingredients. Because individual skin can react differently, products that combine this ester with heavier plant oils could still pose a clogging risk for some users.

Summary

1,2-Hexanediyl Dicaprate is primarily a skin-brightening ester used to help fade dark spots and create a more even complexion. It works by limiting how much melanin builds up on the surface of the skin while doubling as a lightweight emollient that improves product spreadability. Although it is not a household name like vitamin C or niacinamide, formulators appreciate its gentle profile so it turns up in a modest number of brightening serums, masks and lotions.

Current research and consumer feedback point to a strong safety record with low rates of irritation or pore clogging at typical cosmetic levels. As with any new skincare ingredient it is wise to patch test a product on a small area first to confirm personal tolerance before applying it more widely.

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