Acetyl Ethylhexyl Polyhydroxystearate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using publicly available nomenclature standards and reference materials from The Personal Care Products Council (PCPC) and the European Commission's CosIng database. Our analyses are based on technical data from these sources to ensure accuracy and reliability.

What Is Acetyl Ethylhexyl Polyhydroxystearate?

Acetyl Ethylhexyl Polyhydroxystearate is a plant-derived lipid made by first linking many molecules of 12-hydroxystearic acid into a soft waxy polymer, then reacting that polymer with 2-ethylhexyl alcohol and a small amount of acetic acid. The result is a silky ester that feels lighter than most natural oils yet still carries their comforting qualities. Chemists began experimenting with this material in the 1990s while searching for alternatives to petrolatum and heavier mineral oils. Its easy spreadability, plus a talent for trapping water in the skin, quickly earned it a place in modern cosmetic labs. Today you will spot it in moisturizers, night creams, protective balms, face masks, primers, tinted moisturizers, anti-aging blends and even some long-wear foundations where it helps pigments glide smoothly.

Acetyl Ethylhexyl Polyhydroxystearate’s Cosmetic Benefits/Uses

This ingredient pulls triple duty in a formula, making it a favorite of product developers.

  • Humectant: Draws moisture from the air and holds it against the skin so dryness is less likely to return during the day
  • Skin conditioning: Softens and smooths rough patches, leaving the surface looking healthier and more even
  • Emollient: Adds slip and a cushiony feel to creams and makeup, reduces flaking, helps other actives spread uniformly and improves overall texture

Who Can Use Acetyl Ethylhexyl Polyhydroxystearate

This silky ester works for almost every skin type. Dry, sensitive or mature skin will appreciate its moisture-sealing and soothing nature while normal and combination skin benefit from its lightweight feel that does not leave a greasy film. Oily and acne-prone users can usually tolerate it too because it absorbs faster than many plant oils, though extremely breakout-prone individuals may want to monitor how their skin responds.

Because the ingredient is synthesized from plant-derived fatty acids and alcohols with no animal by-products, it is suitable for both vegans and vegetarians.

Current research shows no reproductive or developmental concerns, so products containing Acetyl Ethylhexyl Polyhydroxystearate are generally considered safe for women who are pregnant or breastfeeding. This is not medical advice and anyone who is expecting or nursing should have their doctor review any skincare they plan to use.

The molecule does not make skin more sensitive to sunlight, so it will not heighten the risk of sunburn. It also plays well with common actives such as retinoids, vitamin C and exfoliating acids without altering their effectiveness.

Potential Side Effects/Adverse Reactions

Reactions to topical Acetyl Ethylhexyl Polyhydroxystearate vary from person to person. The following is a list of potential side effects but most users will not experience any of them when the ingredient is properly formulated and used as directed.

  • Mild skin irritation such as redness or itching in very sensitive individuals
  • Clogged pores or small comedones in those highly prone to acne
  • Rare allergic contact dermatitis for people with a pre-existing sensitivity to fatty esters

If irritation or any unwanted reaction occurs discontinue use and consult a healthcare professional.

Comedogenic Rating

Rating: 1 / 5 – Laboratory and anecdotal data place Acetyl Ethylhexyl Polyhydroxystearate on the low end of the pore-clogging scale. Its bulky, branched structure keeps it from packing tightly inside follicles and it absorbs faster than thicker plant butters or mineral oils. While it still forms a light protective film, that film is breathable rather than waxy.

Most people who are prone to acne can use products containing this ester without major issues, though ultra-sensitive or very oily skin might prefer lighter alternatives.

Keep in mind that the final formula, concentration and presence of other richer oils can raise or lower the real-world risk of congestion.

Summary

Acetyl Ethylhexyl Polyhydroxystearate acts as a humectant, skin conditioner and emollient. It draws ambient moisture toward the skin, smooths the surface by filling in tiny gaps then lays down a soft flexible layer that reduces water loss and boosts the slip of creams or makeup. Because the molecule is a modern plant-derived alternative to heavier occlusives its popularity has grown steadily among brands that market clean or vegan-friendly products, though it is still less common than classic ingredients like glycerin or squalane.

Overall safety data look solid: studies report low irritation potential and no long-term health concerns. Nevertheless every complexion is unique so it is smart to perform a short patch test whenever you introduce a new product that contains this ingredient.

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