Acrylates/Behenyl Methacrylate/Dimethicone Methacrylate Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Acrylates/Behenyl Methacrylate/Dimethicone Methacrylate Copolymer?

Acrylates/Behenyl Methacrylate/Dimethicone Methacrylate Copolymer is a man-made ingredient created by linking together small building blocks called monomers. These blocks include acrylates, behenyl methacrylate which comes from behenic acid found in rapeseed oil, and dimethicone methacrylate, a silicone piece known for its silky feel. Chemists began experimenting with these combinations in the late 1990s when the beauty industry started looking for light, flexible film formers that would hold makeup in place without feeling stiff.

To make the copolymer, the different monomers are mixed and triggered to bond in a controlled reactor. Heat or a special starter called an initiator kicks off the reaction, turning the liquid blend into a smooth, easy-to-use powder or dispersion. No animal parts are involved and the process is carefully filtered to remove leftover substances.

Because of its balance of oil-friendly chains and airy silicone parts, the copolymer shows up in many products that need a weightless finish. You will often find it in loose or pressed powders, long-wear foundations, primers, waterproof sunscreens, blotting balms, hair styling sprays, cream eye shadows and even some non-sticky lip colors.

Acrylates/Behenyl Methacrylate/Dimethicone Methacrylate Copolymer’s Cosmetic Benefits/Uses

When added to a formula this copolymer works behind the scenes to improve texture, wear time and skin feel.

  • Anticaking: Keeps powder particles from clumping so they glide on evenly and stay smooth in the jar or compact
  • Film Forming: Creates a thin breathable layer that locks pigments in place, boosts water and sweat resistance and helps makeup last longer without cracking
  • Skin Conditioning: Adds a soft touch finish that makes skin feel silky, reduces the chalky look of powders and helps products spread more easily

Who Can Use Acrylates/Behenyl Methacrylate/Dimethicone Methacrylate Copolymer

This copolymer is considered friendly for most skin types. Oily and combination skins often appreciate its ability to cut down shine and keep makeup locked in place. Dry and mature skins can use it as well because the silicone portion leaves a light silky feel without drawing moisture away. Sensitive skin usually tolerates it since the molecule sits on the surface and is too large to sink deep, but anyone prone to redness or contact dermatitis should keep an eye on how their skin responds.

The ingredient is made entirely from lab-created or plant-derived sources with no animal by-products so it suits both vegans and vegetarians.

Pregnant or breastfeeding women can generally use products containing this copolymer as it is not known to penetrate the skin or act like a hormone. Still, this is not medical advice and anyone who is expecting or nursing should run their routine past a doctor to be completely sure.

The copolymer does not make skin more sensitive to sunlight and has no known effect on tanning or burning. It also plays well with common actives such as vitamin C, retinoids and acids because it forms a neutral film that does not react with them.

Potential Side Effects/Adverse Reactions

Reactions to topical Acrylates/Behenyl Methacrylate/Dimethicone Methacrylate Copolymer differ from person to person. The points below list potential side effects only and are not likely to occur for most users when the ingredient is properly formulated.

  • Transient dryness or tightness if used in very high amounts in powder formulas
  • Mild irritation or redness in individuals with existing silicone sensitivity
  • Rare allergic contact dermatitis presenting as itching or small bumps
  • Product buildup on hair shafts that may feel heavy if a cleansing step is skipped

If you notice any discomfort or persistent change in your skin after applying a product with this copolymer stop using it and consult a healthcare professional or dermatologist.

Comedogenic Rating

Rating: 1/5. This copolymer is a large, lightweight molecule that stays on the surface and does not mix with skin oils, so it has little tendency to block pores. It lacks heavy fatty acids or waxes that commonly cause congestion. Formulas using a high percentage of occlusive butters or oils could still contribute to breakouts, but those issues stem from the overall recipe not this polymer itself. In most cases the ingredient is considered suitable for people prone to acne or blackheads.

Summary

Acrylates/Behenyl Methacrylate/Dimethicone Methacrylate Copolymer acts as an anticaking agent, film former and skin conditioner. Its silicone and long-chain ester parts spread into a thin mesh that keeps powder particles separated, forms a flexible layer that locks pigment in place and leaves a soft glide on skin. Although it is not a household name, formulators value it for boosting long-wear claims in makeup, sunscreens and hair sprays without adding weight.

The safety profile is strong with very low irritation or comedogenic risk reported in standard use levels. As with any new product it is smart to patch test first to make sure your skin agrees with the full formula.

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