Acrylates/Diacetoneacrylamide Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Acrylates/Diacetoneacrylamide Copolymer?

Acrylates/Diacetoneacrylamide Copolymer is a synthetic polymer made by linking together small building blocks derived from acrylic acid, methacrylic acid and diacetoneacrylamide. When these units join they form a clear flexible film that is water resistant yet easy to remove with standard cleansers. Although the raw materials come from petrochemical sources the finished polymer is safe for topical use and is too large to penetrate living skin.

The ingredient first appeared in hair sprays during the 1970s as chemists searched for lighter flake free hold. As its film quality and versatility became clear manufacturers began adding it to skin care and makeup. Today it is produced in closed reactors where the monomers are mixed with water then triggered to react into long chains. The resulting liquid or powder is filtered purified and dried before being sent to cosmetic labs.

You will now find Acrylates/Diacetoneacrylamide Copolymer in products such as facial masks peel off or rinse off sunscreens long wear foundations eyebrow gels mascaras setting sprays hair styling gels and serums. Its ability to form an even flexible layer makes it useful anywhere a product needs to stay put resist smudging or deliver a smooth finish.

Acrylates/Diacetoneacrylamide Copolymer’s Cosmetic Benefits/Uses

This ingredient brings two main technical benefits to cosmetic formulas which translate into noticeable performance for the user.

  • Film forming – Creates a thin invisible coating that locks pigments in place improves water and sweat resistance gives hairstyles longer hold and helps masks peel off in one piece
  • Viscosity controlling – Adjusts thickness so creams feel silky not runny keeps gels from separating and allows sprays to mist evenly without clogging

Who Can Use Acrylates/Diacetoneacrylamide Copolymer

This polymer is considered suitable for all skin types including oily, combination, dry and sensitive because it sits on the surface and has no known pore clogging or sensitising action. Those with very reactive or compromised skin should still pay attention to the full ingredient list of any product since fragrances, preservatives or other actives may be the real irritants.

The material is synthetic and contains no animal derived substances so it is accepted by most vegan and vegetarian standards.

No studies show that topical use poses a risk to women who are pregnant or breastfeeding. The molecule is too large to enter the bloodstream through intact skin. Even so this is not medical advice and anyone expecting or nursing should check any cosmetic product with a doctor to be safe.

Acrylates/Diacetoneacrylamide Copolymer is not known to cause photosensitivity and it can be worn under sunscreen without changing UV protection. It also plays well with common skincare actives such as vitamin C, retinoids and niacinamide.

Potential Side Effects/Adverse Reactions

Responses to topical Acrylates/Diacetoneacrylamide Copolymer differ from person to person. The effects listed below are possible but unlikely for most users when the product is formulated and used as directed.

  • Mild skin redness or itching in individuals already prone to sensitivity
  • Flaking or tightness if the film is applied in thick layers and left on very dry skin
  • Eye irritation if aerosol or powder formats are inhaled during application
  • Build-up on hair shafts that can feel stiff until washed out with shampoo

If any irritation or discomfort develops stop using the product and consult a healthcare professional.

Comedogenic Rating

Rating: 0–1 (non-to very low comedogenic potential)

Acrylates/Diacetoneacrylamide Copolymer sits on the skin as a breathable film and is not oily or waxy so it has little chance of blocking pores. Its large molecular size keeps it on the surface instead of letting it slip into follicles where clogs start. The polymer is often used in acne friendly formulas and lab tests have not linked it to increased comedones.

Suitable for acne-prone and breakout-prone skin.

In leave-on products the main concern is how the full formula is removed. Heavy layers of makeup or sunscreen that are not cleansed off fully can trap sweat and debris which might lead to bumps. Using a proper cleanser at the end of the day keeps this risk low.

Summary

Acrylates/Diacetoneacrylamide Copolymer works as a film former and viscosity controller. It links into long chains that dry into a clear flexible coat locking pigments in place and boosting water resistance while also tweaking thickness so creams glide and sprays mist evenly.

Its reliability and cost-effectiveness have made it a staple in hair sprays mascaras long wear foundations and peel-off masks though it is not a buzzworthy ingredient that shoppers search for by name.

Safety data show it is non-sensitising non-comedogenic and too large to penetrate living skin. Still every formula is different so doing a quick patch test with any new product is a smart move especially for sensitive skin.

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