Acrylates/Hema Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
Share:
Inside this article:

All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Acrylates/Hema Copolymer?

Acrylates/HEMA Copolymer is a man-made blend of 2-hydroxyethyl methacrylate (better known as HEMA) with acrylic acid, methacrylic acid or their simple esters. These small molecules are linked together to form a flexible, film-forming network that holds its shape once it dries. The raw materials are typically derived from petroleum, which is purified then reacted under controlled heat and pressure to create the finished copolymer. First explored in the 1970s for industrial coatings, its strong yet lightweight film soon caught the attention of nail product chemists who needed a durable finish that could flex with the natural nail. Today the ingredient is produced in large reactors, then filtered, dried and milled into a fine powder or delivered as a pre-blended solution for easy mixing.

Because of its ability to form a clear, tough layer, Acrylates/HEMA Copolymer shows up most often in nail polishes, gel nail systems, nail strengtheners, top coats and press-on nail adhesives. It may also appear in specialty cosmetic glues such as those used for nail tips or decorative appliqués.

Acrylates/Hema Copolymer’s Cosmetic Benefits/Uses

This copolymer serves one key role in cosmetics: nail conditioning. By forming a smooth, protective film over the nail plate, it helps reinforce fragile nails, improves gloss and extends the wear time of colored polish. The film limits water loss from the nail surface, reducing brittleness, while its flexibility prevents cracking or chipping. Formulators rely on it for a salon-quality finish that lasts through daily hand washing and routine chores.

Who Can Use Acrylates/Hema Copolymer

Acrylates/HEMA Copolymer suits all skin types because it sits on the nail plate instead of soaking into facial skin. People with very sensitive skin around the nails should still keep an eye on any redness or itching when using new nail products, but most will have no trouble.

The ingredient is made from petroleum derived raw materials and contains no animal by-products so it is considered suitable for both vegans and vegetarians.

Current data shows no special risk for pregnant or breastfeeding women when this copolymer is used in nail products. That said this is not medical advice. Expectant or nursing mothers should check with their health care provider before adding any new cosmetic to their routine.

Acrylates/HEMA Copolymer does not increase photosensitivity so it will not make nails or surrounding skin more prone to sun damage.

Potential Side Effects/Adverse Reactions

Responses to topical Acrylates/HEMA Copolymer vary from person to person. The points below outline possible side effects but most users will not experience them when the ingredient is properly formulated and applied.

  • Allergic contact dermatitis presenting as redness itching or swelling around the nail folds
  • Mild nail bed irritation or tenderness after repeated exposure in salon settings
  • Brittle or peeling nails if harsh removers are used to take off products containing the copolymer
  • Eye or respiratory irritation from inhaling dust particles when filing cured product
  • Skin sensitization that may develop over time in individuals already sensitive to acrylates

If any of these reactions occur stop using the product and consult a medical professional

Comedogenic Rating

Rating: 0 / 5

Acrylates/HEMA Copolymer forms a solid film on the nail plate and is not designed to stay on facial or body skin, so it has no reasonable pathway to block pores or contribute to blackheads. Because it is polymerized, the particles are too large and inert to lodge inside sebaceous follicles even if a small amount touches the skin during application. The ingredient is therefore suitable for acne-prone users. Only the dust created when filing cured product could settle on the face, but a quick rinse removes it and does not affect pore health.

Summary

Acrylates/HEMA Copolymer is a film-forming nail conditioner that strengthens the nail surface, boosts shine and extends polish wear by creating a flexible yet durable layer that locks in moisture and resists chipping. It works by linking small acrylic and methacrylic units into a clear network that bonds tightly to the nail plate.

Its ability to deliver salon-level durability has made it a staple in mainstream and professional nail polishes, gels and adhesives, though it is rarely discussed outside nail technician circles.

Overall safety data are reassuring; major concerns arise only from dust inhalation or rare acrylate sensitivities. Still, every new product can hold surprises, so perform a quick patch test before regular use and enjoy longer-lasting manicures with confidence.

Was this article helpful?
More from Glooshi:
ADVERTISEMENT
Get all our top headlines in beauty.
Delivered right to your inbox each week. Zero spam, all goodness, opt-out at anytime.
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Get the latest beauty news, top product recommendations & brand-exclusive discount codes direct to your inbox.
Send good feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Send bad feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Search