Acrylates/Methacryloyloxyethyl Phosphate Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Acrylates/Methacryloyloxyethyl Phosphate Copolymer?

Acrylates/Methacryloyloxyethyl Phosphate Copolymer is a lab made polymer created by linking together two kinds of building blocks: acrylic or methacrylic units and a phosphate containing unit called methacryloyloxyethyl phosphate. Chemists start with simple liquids such as acrylic acid, methacrylic acid and their esters then combine them with the phosphate monomer in water using a process called emulsion polymerization. The result is a smooth white dispersion that blends well with water based formulas.

Although acrylic polymers first found fame in paints and adhesives back in the mid 1900s, cosmetic chemists began adapting them for skincare in the late 1990s when they noticed the gentle film they create on the surface of skin. Adding the phosphate portion improved the polymer’s ability to stick evenly yet rinse away without harsh scrubbing, making it ideal for daily beauty products.

Today you will spot Acrylates/Methacryloyloxyethyl Phosphate Copolymer in a wide range of items such as facial moisturizers, lightweight lotions, hydrating serums, sheet masks, makeup primers, tinted foundations, sunscreens and some after shave balms. Its versatile nature lets brands offer a clean non tacky finish while still giving skin a protected feeling.

Acrylates/Methacryloyloxyethyl Phosphate Copolymer’s Cosmetic Benefits/Uses

This ingredient is prized for its skin protecting ability. Once it dries it forms a thin breathable film that shields the surface from pollutants and external irritants, helps keep moisture from evaporating and supports the skin barrier. The film also improves the texture of the final product so creams glide on smoothly and makeup stays in place longer without feeling heavy.

Who Can Use Acrylates/Methacryloyloxyethyl Phosphate Copolymer

This polymer is light and water based so it suits almost every skin type including oily, combination, normal, dry and even sensitive skin. Because it forms a breathable film instead of a heavy seal it rarely clogs pores which makes it an option for people who tend to break out, though those with very acne prone skin may still prefer lighter textures overall.

The ingredient is made entirely in a lab from petrochemical and mineral sources with no animal by products so it is considered vegan and vegetarian friendly.

No studies show any risk linked to pregnancy or breastfeeding when the ingredient is used on intact skin. That said this is not medical advice and anyone who is pregnant or nursing should ask a doctor before adding new skincare just to be safe.

Acrylates/Methacryloyloxyethyl Phosphate Copolymer does not make skin more sensitive to sunlight so there is no special need for extra sun precautions beyond daily sunscreen.

Potential Side Effects/Adverse Reactions

Everyone’s skin is different so reactions can vary. The points below list potential side effects yet most people will not notice any problems when the product is well made and used as directed.

  • Mild stinging or burning especially on very dry or freshly exfoliated skin
  • Temporary redness in sensitive areas like around the eyes or nose
  • Itching or tightness if the film is applied in a thick layer
  • Contact dermatitis in rare cases for those allergic to acrylic type materials
  • Eye irritation if the product accidentally gets into the eyes before it sets

If any of these effects occur stop using the product and seek advice from a healthcare professional.

Comedogenic Rating

Rating: 1 / 5

Acrylates/Methacryloyloxyethyl Phosphate Copolymer earns a low score because its large water-friendly molecules sit on top of the skin then rinse away easily instead of seeping into pores. The thin breathable film it makes lets sweat and sebum escape, reducing the chance of blocked follicles. For most people who get pimples or blackheads this ingredient is considered safe and unlikely to worsen breakouts.

One thing to remember is that a product’s full recipe matters. Heavy oils, waxes or fragrances paired with the polymer could still clog pores even if the polymer itself does not.

Summary

Acrylates/Methacryloyloxyethyl Phosphate Copolymer is a lab crafted film former that protects skin from moisture loss and daily grime while giving lotions, serums and makeup a smooth long-lasting finish. It does its job by spreading out in a thin flexible layer that hugs the surface yet washes off without scrubbing.

You will not see this polymer splashed across ads, but chemists use it in many mainstream formulas because it delivers reliable performance at a fair cost.

Current research and decades of use show it is low risk for irritation, allergy and pore clogging when applied to healthy skin. Still, everyone’s skin is different so it is smart to patch test any new product that contains this or any other unfamiliar ingredient.

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