Acrylates/Palmeth-25 Itaconate Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using publicly available nomenclature standards and reference materials from The Personal Care Products Council (PCPC) and the European Commission's CosIng database. Our analyses are based on technical data from these sources to ensure accuracy and reliability.

What Is Acrylates/Palmeth-25 Itaconate Copolymer?

Acrylates/Palmeth-25 Itaconate Copolymer is a man-made ingredient created by linking together smaller building blocks: itaconic acid that has been partly turned into an ester, palm-derived alcohol that has been treated with about 25 units of ethylene oxide, and acrylic or methacrylic parts. When these pieces join they form a long, flexible chain known as a copolymer.

The blend of plant-sourced palm alcohol and lab-made acrylic units first caught the attention of formulators in the late 1990s when brands looked for alternatives to older thickening agents that could keep up with new textures like clear gels and light lotions. Its ability to give a smooth feel without clouding a formula made it a favorite in modern skincare and hair care.

Production starts with responsibly sourced palm fatty alcohol that is reacted with ethylene oxide to boost its water-loving nature. This modified alcohol is then combined with itaconic acid and acrylic monomers in a controlled reactor. Heat, water and a safe initiator trigger the pieces to join into long chains. The finished copolymer is filtered, dried and milled into a fine powder or sold as a liquid dispersion ready for cosmetic use.

You will most often find Acrylates/Palmeth-25 Itaconate Copolymer in clear facial cleansers, lightweight moisturizers, sheet mask serums, hair styling gels and leave-in conditioners where a smooth, non-sticky texture is key.

Acrylates/Palmeth-25 Itaconate Copolymer’s Cosmetic Benefits/Uses

This ingredient plays one main role in beauty formulas that makes it especially useful:

As a viscosity controlling agent it helps adjust how thick or runny a product feels. By swelling slightly in water it turns thin liquids into pleasing gels, keeps oils and water from separating and ensures the formula spreads easily without drips.

Who Can Use Acrylates/Palmeth-25 Itaconate Copolymer

Because this copolymer is mostly inert on skin it tends to suit nearly every skin type including oily, combination and dry skin. Its low film weight and lack of oil make it comfortable for acne-prone users while its water-binding nature adds a touch of slip that dry skin enjoys. People with very reactive or allergy-prone skin usually tolerate it well because it carries no fragrance or preservatives of its own.

The palm source comes from a plant and the rest of the molecule is synthesized in a lab, so the ingredient contains no animal material. That makes products using it appropriate for vegans and vegetarians provided the rest of the formula is also free from animal-derived ingredients.

There is no evidence that Acrylates/Palmeth-25 Itaconate Copolymer penetrates beyond the skin surface or enters the bloodstream. On that basis it is generally considered safe for people who are pregnant or breastfeeding, but this is not medical advice. Anyone who is expecting or nursing should show the full ingredient list of any cosmetic they plan to use to their healthcare provider to be certain it fits their personal needs.

The copolymer does not increase photosensitivity so it will not make skin more prone to sunburn. It is also odorless, colorless and non-volatile which means it does not clash with active ingredients or affect a product’s scent.

Potential Side Effects/Adverse Reactions

Reactions to topical Acrylates/Palmeth-25 Itaconate Copolymer differ from person to person. The points below outline possible issues but most users will never notice any of them when the ingredient is formulated and used correctly.

• Mild skin irritation – a rare tingle or itch if someone is sensitive to synthetic polymers

• Localized redness – temporary flushing where the product is applied, usually subsides once rinsed off

• Allergic contact dermatitis – very uncommon but can occur in people allergic to acrylate structures

• Eye irritation – stinging or watering if a gel thickened with the polymer accidentally gets into the eyes

• Product buildup on hair – if used heavily in leave-in styling formulas it can leave a slight film that dulls shine until washed out

If any of these reactions occur stop using the product and consult a healthcare professional for advice.

Comedogenic Rating

Rating: 0 / 5

Acrylates/Palmeth-25 Itaconate Copolymer is classed as non-comedogenic because it is a large water-loving polymer that sits on the surface then rinses away without melting into pores or mixing with skin oil. It contains no fatty acids or waxes that could block follicles and its film is thin and flexible so it does not trap debris underneath.

People who are prone to acne or breakouts can generally use products containing this ingredient without worrying about clogged pores.

One extra note: if the finished product also includes heavy oils or butters the overall formula could still be pore-clogging, but the copolymer itself is not the cause.

Summary

Acrylates/Palmeth-25 Itaconate Copolymer is a modern thickener that controls viscosity, stabilizes water-oil blends and gives gels and lotions a smooth glide. It works by swelling in water and forming a light film that keeps the formula uniform from the first pump to the last drop.

While not as famous as carbomer or xanthan gum it has carved out a steady following in clear cleansers, refreshing serums and lightweight hair gels where a crystal look and non-sticky feel are prized.

Safety reviews show it stays on the surface and rarely causes irritation making it suitable for most skin types including sensitive and acne-prone. As with any new skincare product it is smart to perform a quick patch test to confirm personal tolerance.

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