Acrylates/Vinyl Neodecanoate Crosspolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Acrylates/Vinyl Neodecanoate Crosspolymer?

Acrylates/Vinyl Neodecanoate Crosspolymer is a lab made substance created by linking vinyl neodecanoate with acrylic or methacrylic building blocks, then crosslinking the chain with small allyl ethers of trimethylolpropane or pentaerythritol. All of its components are sourced from petrochemical feedstocks, so no animal or plant material is involved. The polymer first gained attention in the late 1990s when chemists were looking for a way to give lightweight lotions the smooth feel of silicone without the greasy afterfeel. By the early 2000s it began appearing in long wear makeup and water resistant sunscreens because of its ability to form a flexible film on the skin.

The material is produced through a free radical polymerization process: the monomers are mixed in a reactor, an initiator sparks the reaction, and the growing chains link together into a fine network. After purification and drying the result is a white powder or pre-neutralized dispersion that dissolves or swells when added to water or alcohol. This ingredient now shows up in a wide range of products including moisturizers, anti-aging serums, sheet mask essences, gel creams, color cosmetics such as foundations and mascaras, styling gels and even some spray sunscreens.

Acrylates/Vinyl Neodecanoate Crosspolymer’s Cosmetic Benefits/Uses

In a formula this multifunctional polymer offers several practical benefits

  • Emulsion stabilising: It helps oil and water stay mixed so lotions and creams remain smooth and uniform from the factory line to your bathroom shelf
  • Film forming: Once the product dries it leaves behind an invisible flexible layer that boosts water resistance, improves wear time for makeup and locks in the active ingredients so they can work longer on the skin
  • Viscosity controlling: It thickens liquids into appealing gels or creams and keeps them from separating while still allowing an easy spreadable texture

Who Can Use Acrylates/Vinyl Neodecanoate Crosspolymer

This polymer is considered gentle and non occlusive so it suits most skin types including oily, combination, normal and dry. Sensitive or redness-prone skin usually tolerates it well because the molecule is large and stays on the surface rather than penetrating.

Since the raw materials are petrochemical and contain no animal-derived substances, products that rely on this polymer are suitable for vegetarians and vegans.

Current safety data show no reproductive or developmental concerns, so products with Acrylates/Vinyl Neodecanoate Crosspolymer are generally viewed as safe for pregnant or breastfeeding women. That said this is not medical advice and anyone who is pregnant or nursing should clear any skincare routine with a healthcare professional first.

The polymer does not increase photosensitivity and it is UV stable, meaning it will not break down or make the skin more reactive to sunlight. It also plays nicely with most common skincare actives including retinoids, vitamin C, niacinamide and chemical sunscreens.

Potential Side Effects/Adverse Reactions

Reactions to topical Acrylates/Vinyl Neodecanoate Crosspolymer vary from person to person. The points below list potential issues that could occur although most users will not notice any of them when the ingredient is used correctly in a finished product.

  • Mild skin irritation such as stinging or itching, usually linked to very high concentrations or contact with broken skin
  • Transient redness especially in people with highly reactive or compromised skin barriers
  • Allergic contact dermatitis is rare but possible in individuals sensitive to acrylic compounds
  • Eye irritation if the product accidentally gets into the eyes while still wet
  • Dry or tight feeling when combined with high levels of alcohol or astringent actives in the same formula

If any negative reaction occurs stop using the product and consult a healthcare professional

Comedogenic Rating

Rating: 0 / 5. Acrylates/Vinyl Neodecanoate Crosspolymer is a large, water-swellable molecule that sits on the surface of the skin and does not dissolve into sebum or clog pores. It forms a breathable film that allows moisture exchange so it is generally regarded as non-comedogenic. People who are prone to acne or breakouts can usually use products containing this polymer without worries. If a breakout occurs it is more likely caused by other ingredients in the same formula such as heavy oils or waxes rather than by the polymer itself.

Summary

Acrylates/Vinyl Neodecanoate Crosspolymer stabilises emulsions, thickens watery bases into pleasant gels or creams and creates a flexible film that improves wear and water resistance. It does this by swelling in the water phase, increasing viscosity, then drying down to form a uniform lattice that holds oil and water together while shielding the skin.

The ingredient is a quiet workhorse found in everything from moisturisers and sunscreens to long wear foundations though it rarely appears on the front label because chemists value it mostly for behind-the-scenes texture and stability improvements.

Current safety data show it is low risk, non-sensitising and non-comedogenic. As with any new skincare product a quick patch test is wise to rule out personal sensitivities before full-face use.

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