Acrylates/Vp/Dimethylaminoethyl Methacrylate/Diacetone Acrylamide/Hydroxypropyl Acrylate Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Acrylates/Vp/Dimethylaminoethyl Methacrylate/Diacetone Acrylamide/Hydroxypropyl Acrylate Copolymer?

Acrylates/Vp/Dimethylaminoethyl Methacrylate/Diacetone Acrylamide/Hydroxypropyl Acrylate Copolymer is a large synthetic molecule created by linking several smaller building blocks known as monomers. The key monomers in this case are vinylpyrrolidone, dimethylaminoethyl methacrylate, diacetone acrylamide and hydroxypropyl acrylate, along with a touch of acrylic or methacrylic acid. When these pieces join they form a flexible film-forming network that can sit on skin or hair. The ingredient first gained attention in the late 1980s when formulators looked for lightweight styling polymers that resisted humidity. Over time its ability to deliver smooth, long-lasting hold without a stiff feel made it a favorite in hair sprays and styling gels.

Manufacturing starts with each monomer being mixed in water or solvent, then a catalyst is added to kick off polymerization. Heat or UV light drives the reaction until a viscous solution or dried resin forms. After purification and safety checks the copolymer is ready for use in cosmetic labs.

You will most often see this ingredient in aerosol and pump hair sprays, styling mousses, gels and edge tamers. Some long-wear brow gels, mascara films and setting sprays also rely on it to lock color in place. A few skincare primers use small amounts to create a smooth canvas for makeup.

Acrylates/Vp/Dimethylaminoethyl Methacrylate/Diacetone Acrylamide/Hydroxypropyl Acrylate Copolymer’s Cosmetic Benefits/Uses

This copolymer serves one main purpose in formulas

Film forming: Once applied and allowed to dry it creates an invisible yet flexible layer that clings to hair or skin. In hair products the film helps lock strands in the desired shape, fights frizz and adds shine. In color cosmetics and primers the film holds pigments in place so makeup lasts longer and resists smudging.

Who Can Use Acrylates/Vp/Dimethylaminoethyl Methacrylate/Diacetone Acrylamide/Hydroxypropyl Acrylate Copolymer

This film-forming polymer suits most skin and hair types. Its molecules sit on the surface and do not clog pores, so oily or acne-prone users usually tolerate it well. Normal and dry skin benefit from the smooth, flexible layer it leaves behind. Very sensitive skin can occasionally react to trace monomers or solvents left from manufacturing, so those users may want to choose formulas labeled for sensitive skin.

The ingredient is fully synthetic with no animal-derived components, making it appropriate for vegans and vegetarians as long as the finished product is certified cruelty free.

Because the polymer is large and stays on the surface, systemic absorption is negligible. Current safety assessments find no fertility or developmental risks, so products containing it are generally considered safe during pregnancy or while breastfeeding. This is not medical advice and pregnant or nursing individuals should have any skincare or haircare routine reviewed by their healthcare provider.

The copolymer does not absorb UV light or make skin more reactive to sunshine, so it is not linked to photosensitivity. It also plays well with common actives such as vitamins, plant extracts and sunscreens, making it a flexible option in day-to-day routines.

Potential Side Effects/Adverse Reactions

Reactions to topical Acrylates/Vp/Dimethylaminoethyl Methacrylate/Diacetone Acrylamide/Hydroxypropyl Acrylate Copolymer differ from person to person. The points below list potential issues but most consumers will not notice any problems when the ingredient is used correctly in a well-formulated product.

  • Mild skin irritation such as redness or itching
  • Allergic contact dermatitis in individuals sensitized to acrylate chemicals
  • Eye irritation if aerosolized particles or wet product enter the eyes
  • Dryness or flaking of the scalp when high-hold hairsprays are used daily without proper cleansing
  • Buildup that can leave hair dull or stiff until washed out

If any adverse effect occurs stop using the product and consult a healthcare professional.

Comedogenic Rating

Rating: 0 / 5 – This polymer sits on top of skin rather than sinking into pores, contains no heavy oils or waxes and is easily removed with regular cleansing, so it is not expected to trigger clogged pores.

Suitable for acne-prone or breakout-prone skin.

The only time buildup could become an issue is if very high hold hair sprays are used daily without washing the overspray from facial skin, but under normal use conditions the risk remains negligible.

Summary

Acrylates/Vp/Dimethylaminoethyl Methacrylate/Diacetone Acrylamide/Hydroxypropyl Acrylate Copolymer is a film former that creates a light flexible layer which tames hair, locks makeup in place and holds pigments where you want them. It does this by drying down into a clear network that resists humidity and movement while still bending with hair and skin so the finish never feels crunchy.

Although not a buzzworthy ingredient outside professional formulating circles it is a quiet workhorse in many hair sprays, gels, brow fixers and long-wear cosmetic products.

Current safety data show very low toxicity, minimal irritation potential and no comedogenicity, making it safe for daily use by most people. As with any new product it is smart to patch test first to ensure personal compatibility.

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