Acrylic Acid/Acrylonitrogens Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using publicly available nomenclature standards and reference materials from The Personal Care Products Council (PCPC) and the European Commission's CosIng database. Our analyses are based on technical data from these sources to ensure accuracy and reliability.

What Is Acrylic Acid/Acrylonitrogens Copolymer?

Acrylic Acid/Acrylonitrogens Copolymer is a man-made polymer created by linking together small molecules of acrylic acid and acrylonitrile, then partly hydrolyzing the chain to make it more water friendly. This adjustment lets the ingredient dissolve or swell in water while still keeping the toughness of the original plastic-like structure. The raw materials come from petrochemical feedstocks, so the final powder or liquid resin is entirely synthetic and free from animal or plant content.

The cosmetic world first noticed these polymers in the 1970s when formulators wanted lightweight, flexible films that could hold pigments and active ingredients in place without feeling sticky. Over time the recipe was refined to improve clarity and skin feel, leading to today’s hydrolyzed version that blends easily into both water-based and emulsified products.

Manufacturing starts with a controlled reaction of acrylic acid and acrylonitrile under heat and pressure, using safe free-radical initiators to kick off the chain building. After polymerization, the mixture is cooled, washed to remove leftovers, and partly hydrolyzed with water and mild alkali. The result is dried, milled, and sieved into a fine powder or left as a pre-neutralized liquid that dissolves quickly during production.

You will most often find Acrylic Acid/Acrylonitrogens Copolymer in face masks, peel-off treatments, long-wear foundations, hair gels, styling creams, oil-free moisturizers, pore-blurring primers and certain anti-aging serums that need a smooth flexible film on the skin.

Acrylic Acid/Acrylonitrogens Copolymer’s Cosmetic Benefits/Uses

In a formula this multitasking polymer steps in to solve several common texture and performance problems.

  • Binding: Acts like glue that holds powders, pigments and other particles together so the product stays uniform and doesn’t separate in the jar or on your skin
  • Film Forming: Creates an invisible flexible layer that locks in active ingredients, boosts wear time and provides a smooth satiny feel without clogging pores
  • Skin Conditioning: Leaves a light, soft finish that can reduce roughness and give a more polished look to the skin surface
  • Viscosity Controlling: Thickens water-based systems with only a small amount, letting chemists fine-tune gels, creams or sprays to the perfect consistency

Who Can Use Acrylic Acid/Acrylonitrogens Copolymer

Acrylic Acid/Acrylonitrogens Copolymer is generally well tolerated by most skin types including oily, combination, dry and sensitive. Its lightweight film is non occlusive and water friendly so it rarely traps excess sebum or causes flaking. People with extremely reactive or allergy prone skin should still evaluate the full formula because irritation is more often caused by other ingredients paired with the polymer than by the polymer itself.

The polymer is fully synthetic and made without any animal derived raw materials so it is suitable for vegetarians and vegans.

No research suggests the ingredient poses a special risk during pregnancy or while nursing. That said this information is not medical advice and anyone who is pregnant or breastfeeding should ask a doctor before adding new skincare products.

The molecule does not increase skin sensitivity to sunlight and will not interfere with sunscreen filters. It is also odorless and colorless so it fits well in fragrance free or dye free routines for those avoiding extra additives.

Potential Side Effects/Adverse Reactions

Side effects and reactions to topical Acrylic Acid/Acrylonitrogens Copolymer can vary from person to person. The following points list potential issues but they are uncommon when the ingredient is used correctly in finished products.

  • Mild redness or stinging upon application, especially on compromised skin
  • Temporary itching or tightness as the film sets
  • Dry patches if used in high concentrations without enough humectants
  • Allergic contact dermatitis in individuals sensitive to acrylate chemistry
  • Eye irritation if gel or spray drifts into the eyes
  • In hair styling products buildup that leaves strands stiff or flaky
  • For those extremely prone to breakouts a heavy film may trap sebum and worsen acne in rare cases

If any irritation or other unwanted effect occurs stop using the product and consult a healthcare professional.

Comedogenic Rating

Rating: 1 out of 5. Acrylic Acid/Acrylonitrogens Copolymer is a large water friendly molecule that stays on the surface and rinses off easily so it is not likely to wedge into pores or harden inside sebaceous filaments. The breathable film it forms also allows sebum and sweat to escape which further lowers its clogging potential.

This low score means the ingredient is generally suitable for people who are prone to acne or breakouts.

Keep in mind that a finished product can still cause congestion if it contains rich oils, waxes or heavy silicones even when this polymer itself is low risk.

Summary

Acrylic Acid/Acrylonitrogens Copolymer works as a multitasking helper in skincare and makeup. It binds powders so formulas stay even, thickens water based systems for a smooth feel, conditions the skin surface with a soft touch and lays down an invisible flexible film that locks active ingredients in place.

While not as famous as hyaluronic acid or glycerin, it shows up in many long wear foundations, peel off masks and lightweight gels because chemists value its reliability and clean finish. Its safety record is strong with low irritation and almost no clogging issues when used at normal levels.

Most users can enjoy products containing this polymer without worry but it is always smart to patch test any new product especially if your skin is sensitive or reactive.

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