Acryloyloxyethyl Phthalate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using publicly available nomenclature standards and reference materials from The Personal Care Products Council (PCPC) and the European Commission's CosIng database. Our analyses are based on technical data from these sources to ensure accuracy and reliability.

What Is Acryloyloxyethyl Phthalate?

Acryloyloxyethyl Phthalate is a man-made ingredient created by linking phthalic acid with an acryloyl-modified alcohol. The result is a liquid or soft solid that belongs to a family of substances known for their ability to form flexible films. Chemists first explored this material in the late twentieth century while seeking safer plasticisers for household goods, and its film-forming skill soon made it attractive for beauty formulas.

Manufacturing starts with phthalic anhydride, a common petrochemical feedstock. This reacts with 2-hydroxyethyl acrylate in a controlled setting, producing a stable ester that carries both an adhesive acrylate group and the phthalate backbone. The process is tightly monitored to remove leftover monomers and ensure purity suitable for skin-contact products.

In cosmetics you will spot Acryloyloxyethyl Phthalate in nail polishes, long-wear foundations, liquid eyeliners, peel-off masks, transfer-resistant lip colors and hair-setting sprays. Any formula that needs a thin, flexible coating to lock pigments or styling agents in place can benefit from this ingredient.

Acryloyloxyethyl Phthalate’s Cosmetic Benefits/Uses

Below are the key roles it plays when blended into beauty products.

  • Film forming: Creates a uniform layer on skin, hair or nails that keeps makeup in place, boosts water resistance and adds gloss
  • Plasticiser: Softens otherwise brittle polymers, allowing formulas like nail polish or mascara to flex with movement without cracking or flaking

Who Can Use Acryloyloxyethyl Phthalate

This ingredient is considered non-comedogenic and lightweight so it suits most skin types including oily, combination, normal and dry. Sensitive skin can usually tolerate it because it sits on the surface and does not penetrate deeply, though anyone with a known phthalate allergy should steer clear.

Acryloyloxyethyl Phthalate is synthetic and sourced from petrochemicals, not animals, so it is suitable for vegans and vegetarians.

Current safety data show no specific risks for pregnant or breastfeeding women when the ingredient is used in rinse-off or leave-on cosmetics at approved levels. Still, this is not medical advice and anyone who is pregnant or nursing should check with a doctor before adding new products.

The molecule does not make skin more sensitive to sunlight so there is no added need for extra sun protection beyond your usual SPF routine.

Potential Side Effects/Adverse Reactions

Reactions to topical Acryloyloxyethyl Phthalate vary from person to person. The points below reflect potential side effects and they are unlikely for most users when the ingredient is used within regulatory limits.

  • Contact irritation in the form of redness stinging or itchiness, particularly on broken or very sensitive skin
  • Allergic contact dermatitis in individuals already sensitised to acrylates or phthalates
  • Eye irritation if a product containing the ingredient accidentally gets into the eyes
  • Respiratory discomfort from inhaling fine mist or dust during spray or powder application

If you notice any of the above signs stop using the product and consult a healthcare professional.

Comedogenic Rating

Rating: 1 / 5

Acryloyloxyethyl Phthalate is classed as a low clogging risk because its molecules are large and designed to sit on the surface rather than seep into pores. It forms a breathable film that lets skin function normally without trapping significant amounts of oil or debris. For most people, including those prone to acne, this low score means the ingredient is unlikely to trigger breakouts. Keep in mind that the overall formula matters too; heavy waxes or oils paired with it could still feel greasy.

Summary

Acryloyloxyethyl Phthalate works mainly as a film former and plasticiser. It lays down a thin flexible coat that locks pigments in place, boosts water and rub resistance and adds a smooth glossy finish. At the same time it softens brittle polymers so nail polish, mascara or long wear foundation can move with facial expressions or daily activity instead of cracking.

The ingredient is moderately popular, showing up most often in long wearing makeup and nail products but less so in basic skincare where simpler polymers dominate.

Current studies and regulatory reviews label it low risk for skin irritation or systemic toxicity when used at cosmetic levels. Still, everyone’s skin is unique so it is wise to patch test any new product before full use.

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