Bis-Hea Poly(1,4-Butanediol)-9/Ipdi Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Bis-Hea Poly(1,4-Butanediol)-9/Ipdi Copolymer?

Bis-Hea Poly(1,4-Butanediol)-9/Ipdi Copolymer is a lab-made polymer created by linking together polytetramethylene glycol (a flexible polyester that starts with the simple alcohol 1,4-butanediol) and isophorone diisocyanate, then capping the chain with 2-hydroxyethyl acrylate. This process produces long, stretchy molecules that can form tough yet flexible films once they cure. The ingredient is completely synthetic, so it does not come from plants or animals.

Polyurethane-acrylate hybrids like this one first appeared in the 1990s when formulators searched for nail polish resins that could combine durability with comfort. Over time, the balance of flexibility, adhesion and high-gloss finish made these polymers a favorite in modern nail technology.

Manufacturing starts with reacting polytetramethylene glycol and isophorone diisocyanate under controlled heat to build a prepolymer. Chemists then add 2-hydroxyethyl acrylate to “end-cap” the chains, giving the material sites that can later crosslink when exposed to UV light or chemical catalysts. The finished copolymer arrives as a viscous liquid or solid resin ready to be blended into cosmetic formulas.

You will most often find Bis-Hea Poly(1,4-Butanediol)-9/Ipdi Copolymer in nail polishes, gel systems, hybrid lacquers, base coats, top coats and nail strengtheners where a durable, high-shine film is required. It is less common in skin or hair care because its main benefit targets the hard keratin of nails.

Bis-Hea Poly(1,4-Butanediol)-9/Ipdi Copolymer’s Cosmetic Benefits/Uses

The primary role of this ingredient in cosmetics is nail conditioning. By forming a flexible, glossy film on the nail plate, it helps reinforce weak or peeling nails, reduces surface chipping, locks in natural moisture and boosts the lasting power of colored polishes. Users gain a smoother finish, longer wear time and overall healthier-looking nails.

Who Can Use Bis-Hea Poly(1,4-Butanediol)-9/Ipdi Copolymer

Because this polymer forms a film on the hard surface of the nail rather than soaking into living skin, it is broadly suitable for all skin types including dry, oily and sensitive. People with extremely reactive skin around the cuticles may want to monitor for any tingling or redness since acrylate chemistry can occasionally trigger sensitivity in that area.

The ingredient is fully man-made and contains no animal derivatives so it is appropriate for vegans and vegetarians.

Available safety data have not flagged specific concerns for pregnant or breastfeeding women when the ingredient is used as part of a finished nail product. Still, this is not medical advice and anyone who is expecting or nursing should show the product and its ingredient list to a healthcare professional for personalized guidance.

Bis-Hea Poly(1,4-Butanediol)-9/Ipdi Copolymer does not make skin or nails more prone to sunburn, so photosensitivity is not an issue. It is also odor-neutral once cured which makes it a good choice for people who are sensitive to strong nail polish fumes.

Potential Side Effects/Adverse Reactions

Responses to topical Bis-Hea Poly(1,4-Butanediol)-9/Ipdi Copolymer vary from person to person. The points below outline potential effects but most users will not experience them when the ingredient is formulated and applied correctly.

Skin irritation around the nail folds

Allergic contact dermatitis in individuals sensitized to acrylates or polyurethane compounds

Mild eye irritation if uncured product splashes or vapors reach the eyes

Respiratory discomfort if dust from filing cured gel is inhaled without a mask

Nail brittleness or peeling if the cured film is over-buffed or removed aggressively

If any of these effects occur discontinue use and seek advice from a healthcare professional.

Comedogenic Rating

Rating: 0/5

Bis-Hea Poly(1,4-Butanediol)-9/Ipdi Copolymer is a large synthetic polymer that sits on the hard surface of the nail rather than soaking into facial pores or mixing with skin oils. It is not oil based, does not clog follicles and is removed with polish remover rather than breaking down on the skin. For these reasons it is considered non-comedogenic.

Suitable for those who are prone to acne or breakouts.

Only trace transfer to surrounding skin might occur during application or removal and that limited contact still carries virtually no clogging potential.

Summary

Bis-Hea Poly(1,4-Butanediol)-9/Ipdi Copolymer acts mainly as a nail conditioning film former. Once applied it crosslinks into a tough yet flexible layer that improves adhesion of color, adds gloss, reinforces weak nails and helps lock in moisture. Its stretchy polyurethane backbone supplies flexibility while the acrylate ends enable quick curing for long wear.

The ingredient is fairly common in modern gel and hybrid nail systems though most consumers are unaware of the chemistry behind their polish’s staying power.

Current safety reviews show low irritation and zero comedogenic risk when used as directed. As with any new cosmetic it is wise to patch test a finished product on a small area first to rule out personal sensitivity.

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