Bis-Hpma Poly(1,4-Butanediol)-14/Ipdi Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Bis-Hpma Poly(1,4-Butanediol)-14/Ipdi Copolymer?

Bis-Hpma Poly(1,4-Butanediol)-14/Ipdi Copolymer is a lab-engineered polymer created by linking isophorone diisocyanate with a mid-length chain of poly(1,4-butanediol) that has been capped off with hydroxypropyl methacrylate. The result is a large flexible molecule that forms a lightweight film on skin. First developed as part of research into long-lasting coatings, it caught the attention of cosmetic chemists in the early 2000s when they noticed its ability to leave skin feeling soft and supple without a greasy after-feel. Manufacturing involves controlled step-growth polymerization in a closed reactor where temperature and pH are carefully monitored to keep the chain length consistent, followed by purification and drying into a white free-flowing powder. You will usually find it in moisturizers, anti-aging serums, leave-on masks, lightweight lotions and hand creams where formulators want a silky finish and improved skin feel.

Bis-Hpma Poly(1,4-Butanediol)-14/Ipdi Copolymer’s Cosmetic Benefits/Uses

This ingredient is valued for one main job in skincare.

Skin conditioning: It forms a breathable film that smooths the surface of the skin helping it feel softer and more hydrated. This film can also improve the spreadability of a formula so moisturizers and serums glide on evenly and leave a velvety touch rather than a heavy or sticky residue.

Who Can Use Bis-Hpma Poly(1,4-Butanediol)-14/Ipdi Copolymer

This polymer suits most skin types including oily, combination, normal and moderately dry skin because it forms a light breathable film that does not feel greasy or heavy. Sensitive skin usually tolerates it well since it is non reactive and fragrance free, though people with a history of contact allergies should still be mindful of the full formula. Very dehydrated or severely compromised skin might need richer occlusives alongside it for adequate comfort.

The ingredient is synthesized entirely from laboratory raw materials and contains no animal derived substances so it is considered suitable for vegans and vegetarians.

Current data shows no specific concerns for pregnant or breastfeeding women because the molecule is large and stays on the skin surface, limiting absorption. This is not medical advice and anyone who is pregnant or nursing should show the product to a healthcare professional before use to be safe.

Bis-Hpma Poly(1,4-Butanediol)-14/Ipdi Copolymer does not induce photosensitivity and it can be worn day or night under sunscreen without issue.

Potential Side Effects/Adverse Reactions

Responses to topical Bis-Hpma Poly(1,4-Butanediol)-14/Ipdi Copolymer differ from person to person. The points below list potential side effects that are uncommon when the ingredient is correctly formulated and most users will not experience them.

  • Mild redness or itching if the skin is already irritated
  • Transient stinging on very sensitive or freshly exfoliated skin
  • Rare allergic contact dermatitis for individuals allergic to polyurethane type materials
  • Eye irritation if the product accidentally gets into the eyes
  • Occlusive buildup leading to occasional clogged pores in those extremely prone to acne

If any of these reactions occur stop using the product and seek advice from a healthcare professional.

Comedogenic Rating

Rating: 1 out of 5. Bis-Hpma Poly(1,4-Butanediol)-14/Ipdi Copolymer forms a thin breathable film that sits on the surface and has a low oil content so it is unlikely to block pores. Its large molecular size keeps it from seeping into follicles where comedogenic buildup typically starts. For most acne-prone users it should be well tolerated, though exceptionally clog-prone skin could still react if the overall formula is heavy. No special interactions with other pore-clogging ingredients are known.

Summary

Bis-Hpma Poly(1,4-Butanediol)-14/Ipdi Copolymer is mainly a skin-conditioning film former that smooths texture, boosts softness and gives formulas a silky glide. It does this by creating a lightweight flexible layer over the skin that locks in light moisture without a greasy feel. The ingredient is still relatively niche and found mostly in newer moisturizers and serums aimed at a velvety finish rather than in mass-market staples, but interest is growing as brands look for non-sticky alternatives to silicones.

Current research and usage data show it to be very safe for topical use with low irritation and virtually no systemic absorption. While adverse reactions are rare, it is always best to patch test any new product that contains this or any other active just to be sure your skin agrees with it.

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