Bis-Hpma Poly(Butylene/Hexamethylene Carbonate)/Ipdi Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using publicly available nomenclature standards and reference materials from The Personal Care Products Council (PCPC) and the European Commission's CosIng database. Our analyses are based on technical data from these sources to ensure accuracy and reliability.

What Is Bis-Hpma Poly(Butylene/Hexamethylene Carbonate)/Ipdi Copolymer?

Bis-Hpma Poly(Butylene/Hexamethylene Carbonate)/Ipdi Copolymer is a man-made polymer that belongs to the urethane family. Chemically it is formed by linking together small building blocks: butanediol, hexanediol and dimethyl carbonate are first combined to create a flexible base chain, this prepolymer is then reacted with isophorone diisocyanate to add strength and durability, and finally hydroxypropyl methacrylate is attached to cap the ends and make the finished material more stable. The result is a clear lightweight film former that behaves almost like an invisible wrap on skin or hair.

The idea of using such polymers in beauty care grew out of coatings technology in the 1980s when chemists searched for safe plastic-like layers that could sit comfortably on living tissue. Over time the recipe was refined to be mild enough for daily use and to avoid the heavy feel of older film formers. Today it is produced in controlled batches where each reaction step is carefully monitored so that any unreacted monomers are kept to a minimum.

You are most likely to meet this ingredient in long-wear makeup, setting sprays, peel-off masks, waterproof sunscreens, anti-aging serums that claim to give an instant smoothing effect and hair styling products that promise flexible hold.

Bis-Hpma Poly(Butylene/Hexamethylene Carbonate)/Ipdi Copolymer’s Cosmetic Benefits/Uses

This ingredient is prized for one main job in cosmetics: film forming. Once the product is applied and the water or solvent evaporates, the polymer sets into a thin breathable layer. This film helps makeup last longer, keeps actives such as antioxidants close to the skin, reduces transepidermal water loss for a temporary plumping effect, and provides light resistance against sweat or rubbing. In hair care it offers gentle hold without stiffness and adds shine.

Who Can Use Bis-Hpma Poly(Butylene/Hexamethylene Carbonate)/Ipdi Copolymer

This polymer is generally well tolerated by all skin types, including oily, dry and combination skin. Its breathable film does not add oil or draw out moisture so both acne-prone and dehydrated complexions can usually use it without trouble. Very sensitive or eczema-prone skin might notice tightness if a high level is used because the film can feel slightly occlusive, though most formulas balance this with emollients.

The ingredient is fully synthetic and contains no animal-derived matter so it is suitable for vegans and vegetarians. During manufacturing no animal testing is required under current cosmetic regulations in many regions but consumers who follow strict cruelty-free standards should still check the brand’s policy as that sits outside the raw material itself.

No data suggest any specific risk for pregnant or breastfeeding women when the polymer is used topically at cosmetic levels. It does not absorb through skin in measurable amounts. This is not medical advice and anyone who is expecting or nursing should show the product to a qualified healthcare provider before use to be extra safe.

Bis-Hpma Poly(Butylene/Hexamethylene Carbonate)/Ipdi Copolymer is not known to cause photosensitivity and does not make skin more prone to sunburn. It can even help sunscreen stay put by forming a water-resistant layer.

Potential Side Effects/Adverse Reactions

Side effects from topical use of Bis-Hpma Poly(Butylene/Hexamethylene Carbonate)/Ipdi Copolymer vary from person to person. The following list covers potential reactions that could arise in rare cases. Assuming the ingredient is properly purified and blended most users will not notice any of these issues.

  • Mild skin irritation such as itching or redness, usually due to individual sensitivity
  • Contact allergy presenting as small bumps or a rash after repeated exposure
  • Eye irritation if the product accidentally gets into the eyes, leading to stinging or watering
  • Buildup on hair shafts that can leave strands feeling coated if the formula is not rinsed out thoroughly
  • Very low risk of clogged pores in people who are extremely prone to comedones when using heavy leave-on products

If any adverse reaction occurs stop using the product immediately and consult a healthcare professional if symptoms persist or worsen.

Comedogenic Rating

Rating: 1/5. Bis-Hpma Poly(Butylene/Hexamethylene Carbonate)/Ipdi Copolymer forms a lightweight breathable film that sits on top of the skin rather than seeping into pores, so it rarely traps oil or debris. Its molecules are too large to penetrate deeply, limiting the chance of blockage. That said, very heavy leave-on formulas that include high levels of the polymer can create a slight occlusive feel which might not suit extremely congestion-prone users.

Overall it is usually fine for acne-prone skin, especially in makeup or sunscreen where it is balanced with volatile solvents and mattifying agents.

If you use multiple film-forming products in the same routine, cleanse well at night to prevent layer build-up that could indirectly contribute to clogged pores over time.

Summary

Bis-Hpma Poly(Butylene/Hexamethylene Carbonate)/Ipdi Copolymer is chiefly a film former. After application it dries into a clear flexible layer that locks makeup in place, keeps skincare actives close to the surface, reduces moisture loss for a temporarily smoother look and provides light water and rub resistance. In hair care it supplies soft hold and shine without crispness.

The polymer is not a headline ingredient like hyaluronic acid or vitamin C but formulators appreciate its reliability so you will find it quietly supporting long-wear foundations, setting sprays and waterproof sunscreens.

Current evidence shows it is low in irritation risk, non-sensitizing and largely non-comedogenic. As with any new cosmetic, do a simple patch test when trying a product that contains this polymer to make sure your individual skin responds well.

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