Bis-Vinyl Diphenyl Dimethicone: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
Share:
Inside this article:

All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Bis-Vinyl Diphenyl Dimethicone?

Bis-Vinyl Diphenyl Dimethicone is a synthetic silicone polymer that belongs to the broader family of siloxanes. Its backbone is made of repeating oxygen and silicon units, with side groups that include both methyl and diphenyl vinyl segments. These vinyl ends let the molecule link into flexible networks once it is applied to skin or hair, creating the thin breathable film that makes the ingredient so useful.

The material does not come from plants or animals; it is produced in a lab. Chemists start with dimethylsiloxane fluid, substitute some of the methyl groups with diphenyl vinyl groups, then use controlled polymerization so the chains reach the right length and viscosity. The resulting clear fluid is stable, non-volatile and odorless, qualities that help cosmetic chemists formulate products with a silky feel.

Silicones first moved into beauty products in the 1950s for their smooth sensory properties. Bis-Vinyl Diphenyl Dimethicone appeared later as brands looked for longer wear and better water resistance in makeup. Today you will find it in foundations, primers, BB creams, long-lasting lip products, waterproof mascaras, sunscreens, leave-in hair serums, anti-frizz sprays, overnight masks and premium anti-aging moisturizers.

Bis-Vinyl Diphenyl Dimethicone’s Cosmetic Benefits/Uses

Below are the main roles this ingredient plays when it is added to personal care products

  • Film forming – Creates a light flexible layer that holds pigments in place, boosts water resistance and helps active ingredients stay on the skin or hair for longer
  • Hair conditioning – Coats each strand to improve slip, reduce frizz, add shine and make detangling easier without weighing hair down
  • Skin protecting – Forms a breathable barrier that locks in moisture, shields against environmental pollutants and leaves a smooth soft finish

Who Can Use Bis-Vinyl Diphenyl Dimethicone

This silicone is generally considered safe for all skin types, including dry, oily, combination and mature skin. Its lightweight film permits the skin to breathe so it rarely feels heavy or greasy, even on oilier complexions. Very acne-prone users who already struggle with clogged pores may prefer lighter water-based formulas, since any film former can trap sebum if layered too thickly.

Because the compound is fully synthetic and contains no animal derivatives it is suitable for vegans and vegetarians.

Current research shows no specific risks for women who are pregnant or breastfeeding when Bis-Vinyl Diphenyl Dimethicone is applied topically. That said this is not medical advice and expectant or nursing mothers should run any skincare or haircare product past their doctor to be safe.

The ingredient does not make skin more sensitive to sunlight so there is no added risk of photosensitivity. It also plays well with common actives such as retinoids, vitamin C and exfoliating acids, making it easy to fit into almost any routine.

Potential Side Effects/Adverse Reactions

Side effects and reactions to topical Bis-Vinyl Diphenyl Dimethicone can vary from person to person. The points below list potential issues that could occur, yet they are uncommon when the ingredient is used correctly in a well-formulated product.

  • Mild skin congestion or breakouts in individuals who are extremely prone to clogged pores
  • Rare cases of contact dermatitis such as redness itchiness or a rash in those with a silicone sensitivity
  • Temporary scalp build-up or dullness if heavy silicone products are not cleansed out of hair properly
  • Stinging or watering if the product accidentally gets into the eyes

If you notice irritation or any unexpected reaction stop using the product and consult a healthcare professional or dermatologist.

Comedogenic Rating

Rating: 1/5

Bis-Vinyl Diphenyl Dimethicone forms a lightweight breathable film that sits on top of the skin rather than sinking deeply into pores. Its large silicone structure makes it less likely to clog follicles compared with heavier oils or waxes, earning it a low score of 1. Those extremely prone to acne may still see issues if they layer multiple silicone-rich products without proper cleansing, but for most users this polymer is considered low risk for breakouts.

In short it is generally suitable for acne-prone skin, though keeping the rest of your routine light and washing thoroughly at night will further reduce any chance of congestion.

Worth noting: comedogenic ratings are guides based on typical usage levels. Final product texture, concentration and the full formula all influence whether a product will clog pores.

Summary

Bis-Vinyl Diphenyl Dimethicone is a lab-made silicone that creates a flexible film, conditions hair and protects skin by locking in moisture and shielding against pollution. It excels in long-wear makeup, waterproof sunscreens and anti-frizz hair care because its vinyl-terminated chains link into a durable yet airy network that resists water and sweat while leaving a silky finish.

The ingredient enjoys steady popularity in prestige and mass market formulas that aim for smoother application and improved wear time, although some minimalist or natural brands skip it in favor of plant-derived alternatives.

Safety studies and decades of use show it is well tolerated with a very low irritation profile. Still, everyone’s skin is unique so patch testing any new product that contains Bis-Vinyl Diphenyl Dimethicone is a smart way to confirm personal compatibility.

Was this article helpful?
More from Glooshi:
ADVERTISEMENT
Get all our top headlines in beauty.
Delivered right to your inbox each week. Zero spam, all goodness, opt-out at anytime.
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Get the latest beauty news, top product recommendations & brand-exclusive discount codes direct to your inbox.
Send good feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Send bad feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Search