Calcium Behenate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 24, 2025
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All information on this page is verified using publicly available nomenclature standards and reference materials from The Personal Care Products Council (PCPC) and the European Commission's CosIng database. Our analyses are based on technical data from these sources to ensure accuracy and reliability.

What Is Calcium Behenate?

Calcium behenate, also called calcium didocosanoate, is the calcium salt of behenic acid, a long-chain fatty acid that naturally occurs in seeds like rapeseed and peanut as well as in animal fats. When behenic acid reacts with calcium ions it forms a fine, white, powdery substance that is insoluble in water yet disperses well in oils. It first appeared in personal care labs in the late 1970s as chemists searched for plant-derived alternatives to talc and other mineral additives. Today manufacturers typically produce it by isolating behenic acid from vegetable oils, purifying it, then neutralizing it with calcium hydroxide under controlled heat and pH conditions. The resulting powder is milled to a specific particle size to ensure smooth blending into cosmetic bases. You will spot calcium behenate in pressed powders, cream and stick foundations, sunscreens, lipsticks, mascaras, antiperspirant sticks, clay masks, body butters and rich night creams where a silky, non greasy texture is desired.

Calcium Behenate’s Cosmetic Benefits/Uses

This ingredient carries several roles that improve both the look and feel of a product

  • Anticaking: Keeps powders free flowing and prevents clumping so compacts press evenly and loose powders shake out smoothly
  • Opacifying: Increases coverage by scattering light which helps mask skin imperfections and gives makeup a more uniform finish
  • Viscosity controlling: Thickens oil phases and stabilizes emulsions allowing creams to feel richer without greasiness while helping sticks hold their shape in warm weather

Who Can Use Calcium Behenate

Most skin types can comfortably use products containing calcium behenate. Its silky feel suits normal and dry skin while its oil-absorbing ability helps keep combination and oily skin looking fresh. Sensitive skin generally tolerates it well because it is chemically inert and fragrance-free. Those with very blemish-prone skin should note that, although the ingredient itself is considered low on the clogging scale, heavy cream or stick formulas that include it might still feel too occlusive for them.

Nearly all commercial grades come from vegetable oils so they fit into vegan and vegetarian routines. If avoiding animal by-products is essential, look for brands that specify plant sourcing or carry a certified vegan logo.

Current safety data shows no reproductive or developmental concerns so pregnant or breastfeeding users can typically apply products with calcium behenate. This is not medical advice and anyone expecting or nursing should clear all skincare choices with their doctor just to be safe.

The ingredient does not make skin more sensitive to sunlight and has no known interactions with sunscreen filters or actives like retinol or vitamin C.

Potential Side Effects/Adverse Reactions

Responses to any cosmetic ingredient vary from person to person. The following list covers potential side effects of topical calcium behenate though most users will not experience them when the product has been properly formulated.

  • Mild skin irritation such as redness or itching in very sensitive individuals
  • Temporary pore congestion if used in rich formulations on acne-prone areas
  • Eye stinging or watering if loose powder accidentally gets into the eyes
  • Minor respiratory discomfort from inhaling airborne powder during application of loose products

If any unwanted reaction occurs stop using the product and consult a healthcare professional.

Comedogenic Rating

Rating: 1/5. Calcium behenate itself is a dry, powdery salt that sits on the skin’s surface rather than melting into pores, so it has a very low tendency to clog them. It lacks the heavy oily feel of some fatty acid derivatives, and most studies as well as anecdotal reports link it to little to no breakout activity. Still, if it is blended into thick balms or cream sticks the total formula could feel occlusive which may raise the risk of congestion in very oily zones.

Overall it is acceptable for acne-prone users, although extremely breakout-sensitive individuals might prefer it only in lightweight or powder formats.

Summary

Calcium behenate acts as an anticaking agent that keeps powders loose, an opacifier that boosts coverage, and a viscosity controller that thickens oils so creams feel plush without greasiness. It achieves these roles thanks to its fine particle size and partial oil affinity, which lets it disperse smoothly and influence texture without dissolving.

The ingredient is moderately popular: common enough in pressed makeup and stick formulations but far from a household name since it stays behind the scenes as a texture helper rather than a headline active.

Safety reviews rate it as low risk with minimal irritation potential. As with any new cosmetic, a quick patch test is wise to rule out individual sensitivities before regular use.

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