Calcium Starch Octenylsuccinate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 24, 2025
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All information on this page is verified using publicly available nomenclature standards and reference materials from The Personal Care Products Council (PCPC) and the European Commission's CosIng database. Our analyses are based on technical data from these sources to ensure accuracy and reliability.

What Is Calcium Starch Octenylsuccinate?

Calcium Starch Octenylsuccinate is a modified starch that starts its life as corn starch, a familiar thickening agent found in many kitchens. Chemists react this plant-based starch with octenylsuccinic anhydride, then neutralize the product with calcium salts. The result is a powder that mixes easily with water and oils and has a silky, non-greasy feel on skin.

Starch modification has been around since the mid-20th century, but beauty brands began turning to this particular form in the past couple of decades when they needed a natural-leaning alternative to synthetic texture enhancers. Large-scale production involves washing the corn starch, treating it in a controlled reactor with octenylsuccinic anhydride, adding calcium hydroxide to lock in the salt form, then drying and milling the powder to a fine, uniform size.

You will spot Calcium Starch Octenylsuccinate in a wide range of personal care products. It appears in loose and pressed powders, liquid and stick foundations, tinted moisturizers, sunscreens, sheet and clay masks, dry shampoos, antiperspirant sticks, anti-aging creams and even some baby care items where a soft, lightweight texture is crucial.

Calcium Starch Octenylsuccinate’s Cosmetic Benefits/Uses

This ingredient is prized because it can play several helpful roles in a formula.

  • Absorbent – Soaks up excess oil and sweat, giving products a matte finish and helping makeup stay put longer
  • Emulsion stabilising – Keeps water and oil phases from separating so lotions and creams remain smooth throughout their shelf life
  • Emulsifying – Helps blend water and oil together in the first place, allowing brands to reduce reliance on synthetic surfactants
  • Viscosity controlling – Thickens or thins a formula to the desired consistency, creating textures that spread easily and feel pleasant on skin

Who Can Use Calcium Starch Octenylsuccinate

Calcium Starch Octenylsuccinate is gentle and non occlusive, so it can suit all major skin types. Oily and combination complexions often benefit the most because the powder absorbs excess sebum and leaves a matte finish. Dry or sensitive skin usually tolerates it well since it does not strip moisture or carry strong actives that might sting. There are no known reasons for acne prone or mature skin to avoid it, provided the overall formula meets their needs.

The ingredient is sourced from corn starch and calcium derived from minerals, with no animal based components. That makes it compatible with vegan and vegetarian lifestyles. While the raw material itself is free from animal testing in regions that accept alternative safety data, consumers concerned about cruelty free status should verify the policy of the finished brand.

No specific warnings exist for pregnant or breastfeeding women when the ingredient is used topically in cosmetics. It is an inert starch derivative that stays on the skin’s surface and has minimal absorption. Still, this is not medical advice and anyone who is pregnant or nursing should run new skincare products by a doctor just to be safe.

Calcium Starch Octenylsuccinate does not increase photosensitivity. Standard sun protection habits remain important, but this powder neither heightens nor reduces the skin’s response to UV exposure. It has no known conflicts with common actives such as retinoids or exfoliating acids, allowing it to be layered freely in most routines.

Potential Side Effects/Adverse Reactions

Side effects and reactions can differ from person to person. The following points list potential issues only, and most users will not experience them when the ingredient is used correctly by the product manufacturer.

  • Mild skin irritation in individuals who are extremely sensitive to corn derivatives or certain powders
  • Temporary dryness or tightness if a formula contains a very high starch load without balancing emollients
  • Respiratory discomfort during application when loose powder is inhaled accidentally
  • Allergic contact dermatitis in the rare case of a true corn or starch allergy

If any redness itching rash or breathing difficulty occurs discontinue use and seek medical advice

Comedogenic Rating

Rating: 1/5

Calcium Starch Octenylsuccinate is a large, water- and oil-friendly starch particle that sits on the skin surface without melting into pores. It absorbs excess sebum instead of adding heavy film-forming oils, so the likelihood of clogging is very low. A rating of 0 would apply only to ingredients proven completely inert on every skin type; because this starch still has slight thickening action and can bind to oils, it earns a cautious 1.

Suitable for acne-prone or breakout-prone skin.

As with most powders, risk rises if the finished product is packed with other potentially pore-clogging emollients or if heavy layers are left on skin overnight. Always judge the full formula, not the raw material alone.

Summary

Calcium Starch Octenylsuccinate acts as an absorbent, emulsion stabiliser, emulsifier and viscosity controller. Its modified starch backbone soaks up oil and moisture, while the octenylsuccinyl groups help it anchor at the water-oil interface, keeping creams uniform and giving formulas a smooth, cushiony feel. By adjusting particle size and concentration, chemists can thicken runny lotions or lighten rich creams without waxy heaviness.

The ingredient enjoys moderate popularity in modern clean-leaning makeup, sunscreens and skin care because it offers plant-based texture and oil control without silicones or talc. It is still less common than legacy fillers like mica or silica, but usage is climbing as more brands seek biodegradable alternatives.

Overall safety is high: it is non-sensitising, non-toxic and largely stays on the surface of the skin. That said, every formulation is different, so perform a simple patch test when trying a new product containing Calcium Starch Octenylsuccinate to confirm personal compatibility.

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