Chlorous Acid: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 24, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Chlorous Acid?

Chlorous Acid is an inorganic acid created when chlorine dioxide dissolves in water, resulting in a solution that contains the ion ClO2. Although it is rarely isolated as a pure compound, it is produced on demand in controlled facilities because it is most stable when freshly prepared and used quickly. The manufacturing process typically involves reacting sodium chlorite with a mild acid, then carefully adjusting pH so the acid remains effective yet safe for topical formulas.

Its pathway into cosmetics began with its long history in water purification and food sanitation, fields that value its strong yet fast-acting antimicrobial power. Formulators noticed that the same property could help keep cosmetic products free of unwanted microbes, reduce odor on skin and protect delicate ingredients from breaking down. Today you will most often find Chlorous Acid in mouthwashes, breath sprays, underarm deodorants, foot sprays, wipes, post-workout body mists, sheet masks and occasional rinse-off cleansers where quick antimicrobial action is desired without lingering residue.

Chlorous Acid’s Cosmetic Benefits/Uses

In skincare and personal care formulas Chlorous Acid brings several practical benefits that improve both product performance and consumer experience.

  • Anticorrosive – Helps protect metal parts of packaging and dispensing systems from rusting which keeps the product stable over time and prevents discoloration
  • Antimicrobial – Reduces bacteria, yeast and mold in the product and on the skin surface supporting a longer shelf life and helping cut down on odor-causing germs
  • Deodorant – Neutralizes odor molecules rather than masking them so products aimed at underarms, feet or sports gear can leave the area smelling fresh
  • Oral Care – Provides quick breath freshening by lowering the number of odor-producing microbes inside the mouth making it useful in mouthwashes, sprays and dental rinses
  • Oxidising – Acts as a gentle oxidiser that can break down stains or color-causing compounds which helps brighten surfaces like teeth or nails and boosts overall product clarity

Who Can Use Chlorous Acid

Because it is water based and non oily Chlorous Acid suits most skin types including oily, combination and acne prone skin that benefits from its quick antimicrobial effect. Dry or sensitive skin can generally tolerate it too when formulas are well buffered, though very reactive skin should start with lower concentrations since over-acidic solutions may cause a stinging feel.

The compound is synthetically produced from mineral sources so it contains no animal-derived materials making it acceptable for vegans and vegetarians.

No specific contraindications have been noted for pregnant or breastfeeding women when Chlorous Acid is used at the low levels common in cosmetics. This is informational only; anyone who is expecting or nursing should show the ingredient list to a qualified health professional before using a new product.

The ingredient does not absorb UV light and does not increase photosensitivity. It also rinses away cleanly which further lowers sun reactivity risk.

Potential Side Effects/Adverse Reactions

Responses to topical Chlorous Acid differ from person to person. The effects below are possible yet uncommon when products are correctly formulated and used as directed.

  • Mild skin irritation such as redness or burning if the formula is too acidic
  • Temporary dryness or tightness especially on already dehydrated skin
  • Allergic contact dermatitis in those with chlorine or chlorite sensitivities
  • Bleaching or fading of fabrics if solution spills onto clothing or towels
  • Metallic taste or mouth dryness when overused in oral rinses
  • Possible interaction with strong antioxidants like vitamin C leading to product instability

If any uncomfortable reaction occurs stop use immediately then consult a healthcare professional if symptoms persist.

Comedogenic Rating

Rating: 0/5 – Chlorous Acid is a water-soluble, non-oily molecule that evaporates or rinses away without leaving a residue that could clog pores. Its antimicrobial action can actually lower the surface load of acne-causing bacteria rather than encourage breakouts.

This makes Chlorous Acid generally suitable for people who are prone to acne or congestion, provided the finished product is balanced for skin pH.

Because it is often used in rinse-off or low-leave-on formats, real-world buildup on skin is minimal which further supports the zero rating.

Summary

Chlorous Acid functions as an anticorrosive, antimicrobial, deodorant, oral care aid and mild oxidiser. It performs these roles by releasing active chlorine species that disrupt microbial cells, neutralise odor molecules, slow metal rust and gently break down stains in a controlled, short-lived burst of oxidation.

In cosmetics it remains a niche ingredient found mainly in specialty mouthwashes, deodorising sprays and occasional skin treatments rather than mainstream creams or serums. Formulators appreciate its quick kill time on microbes yet many brands skip it in favour of better-known preservatives which keeps its popularity modest.

Safety data and everyday use levels show a low risk profile with irritation only when pH drifts too low or in those with chlorine sensitivities. As with any new product it is smart to patch test first to make sure your skin agrees with the formula.

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