Dibehenyl Methylamine: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 27, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Dibehenyl Methylamine?

Dibehenyl Methylamine, also listed on ingredient labels as N-Methyldidocosylamine, is a long-chain fatty amine that comes from behenic acid, a fatty acid naturally present in rapeseed and peanut oils. By reacting behenic acid with methylamine chemists create this cationic, or positively charged, compound that easily binds to the surface of hair fibers. The ingredient first appeared in professional salon products in the late 1990s when formulators were searching for gentler alternatives to early quaternary ammonium conditioners. Today its use has expanded into mainstream hair care thanks to its smoothing effect and light feel. The production process starts with purifying behenic acid, converting it to behenyl chloride then reacting it with methylamine under controlled heat. After neutralization and purification the finished material is a waxy solid that melts into emulsions and creams.

You will most often spot Dibehenyl Methylamine in rinse-off or leave-in conditioners, anti-frizz serums, hair masks and styling creams aimed at taming static. It is less common in skin-focused products because its main benefits shine on hair although small amounts may appear in multi-use creams that promise silky texture for both skin and hair.

Dibehenyl Methylamine’s Cosmetic Benefits/Uses

This ingredient is valued because it tackles two common hair care concerns at once

  • Antistatic – its positive charge neutralizes the negative charge that builds up on hair strands after washing or brushing, cutting down flyaways and helping hair lie smoothly
  • Hair Conditioning – it forms a thin conditioning layer that makes hair feel softer, improves slip during combing and adds a subtle shine without weighing the hair down

Who Can Use Dibehenyl Methylamine

Dibehenyl Methylamine is generally suitable for all skin and hair types because it stays mostly on the hair shaft and rinses off easily, leaving only a light conditioning film. People with very sensitive or allergy-prone skin may want to keep an eye on the ingredient list since any cationic conditioning agent can occasionally trigger irritation on the scalp or around the hairline, but reports are rare.

The compound is plant derived because its fatty acid backbone comes from rapeseed or peanut oil and the remaining reagents are synthetic, so it is considered appropriate for both vegans and vegetarians. No animal by-products or animal testing are involved in its standard supply chain, although consumers who avoid peanuts for allergy reasons may still prefer to verify the source with the brand.

Available safety data show no specific risks for women who are pregnant or breastfeeding when the ingredient is used in rinse-off or leave-in hair products. This information is not medical advice and anyone who is pregnant or nursing should run any cosmetic formula past a qualified healthcare professional to be on the safe side.

Dibehenyl Methylamine is not known to cause photosensitivity, so it will not increase the skin or scalp’s sensitivity to sunlight. It is also free of common sensitizers like fragrance allergens and formaldehyde releasers, making it a fairly low-risk choice for daily use.

Potential Side Effects/Adverse Reactions

Reactions to topical Dibehenyl Methylamine vary from person to person. The following points outline potential side effects, although most users will not experience them when the ingredient is properly formulated and used as directed.

  • Mild scalp or skin irritation in individuals with very sensitive skin
  • Allergic contact dermatitis in rare cases for those already sensitized to fatty amines
  • Eye irritation if the product accidentally drips into the eyes during application or rinsing
  • Product buildup on fine or low-porosity hair which can make hair feel limp or greasy over time

If you notice redness, itching or any persistent discomfort while using a product that contains Dibehenyl Methylamine stop using it and consult a healthcare professional or dermatologist.

Comedogenic Rating

Rating: 1 / 5 – Dibehenyl Methylamine is a large, positively charged molecule that tends to stay on the hair shaft and rinses away easily, so it has very little chance of clogging facial pores. Because it is used mostly in hair care and not designed to sit on facial skin the likelihood of breakouts is low.

Suitable for acne-prone or breakout-prone users in the concentrations typically found in hair products.

When this ingredient appears in multi-use creams that may touch facial skin users who already struggle with heavy waxes or butters might notice a slight occlusive feel, though reports of pimples are uncommon.

Summary

Dibehenyl Methylamine conditions hair and tames static by laying a light, positively charged film over each strand which smooths the cuticle reduces flyaways and improves slip. Thanks to these benefits it shows up in conditioners, masks and anti-frizz serums but it is still a niche choice compared with better-known quats like behentrimonium chloride.

Current safety data label it as low risk for irritation, allergy and comedogenicity making it generally safe for daily use. As with any new cosmetic ingredient it is wise to do a quick patch test when trying a fresh product that contains it just to make sure your skin or scalp agrees.

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