Dihydroxypropyl Peg-5 Linoleammonium Chloride: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 27, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Dihydroxypropyl Peg-5 Linoleammonium Chloride?

Dihydroxypropyl Peg-5 Linoleammonium Chloride is a conditioning agent made by joining plant sourced linoleic acid with a short chain of polyethylene glycol, then turning the mix into a quaternary ammonium salt and neutralizing it with chloride. The result is a water friendly molecule that loves both oil and water, letting it spread easily across hair and skin.

The ingredient first appeared in the early 1990s when formulators searched for milder alternatives to traditional quats. By adding the dihydroxypropyl group and using a smaller PEG chain they kept the smoothing effect while lowering buildup and irritation risk. Production starts with refined vegetable oils such as sunflower or safflower, which supply linoleic acid. Chemists attach the PEG-5 chain, add a glycerin derived dihydroxypropyl arm, create phosphate triesters for extra slip, then quaternize the amine and finish with a chloride counter-ion.

You will most often see it in hair care like shampoos, rinse-off and leave-in conditioners, detangling sprays, anti-frizz serums and deep masks. Some lightweight skin lotions and anti-static fabric sprays also use it for its soft feel and static control.

Dihydroxypropyl Peg-5 Linoleammonium Chloride’s Cosmetic Benefits/Uses

In a formula this multitasker mainly brings two helpful actions:

  • Antistatic: Neutralizes the electric charge that makes hair strands repel each other so it tames flyaways, keeps styles neat and adds a smooth touch to the surface.
  • Hair conditioning: Forms a thin breathable film that makes combing easier, reduces breakage during styling and leaves hair feeling soft without a heavy waxy residue.

Who Can Use Dihydroxypropyl Peg-5 Linoleammonium Chloride

This conditioner suits most skin and scalp types thanks to its lightweight non occlusive nature. Oily and combination users appreciate the lack of greasy residue while dry or damaged hair gains softness and slip. Sensitive skin generally tolerates it well since the molecule was designed to be milder than traditional quats, though anyone with a known allergy to quaternary ammonium compounds or polyethylene glycol should be cautious.

The raw materials come from plant oils and glycerin so the ingredient is routinely considered vegan and vegetarian friendly. No animal derived substances are used during standard production however formulas vary, so strict vegans may want to confirm the full product remains free of animal additives.

There is no published evidence that topical use poses risks for people who are pregnant or breastfeeding. The molecule is large, water soluble and expected to stay on the surface rather than penetrate skin. This is not medical advice and anyone expecting or nursing should show the full product ingredient list to a doctor before use.

Dihydroxypropyl Peg-5 Linoleammonium Chloride is not known to cause photosensitivity so daylight exposure does not increase irritation or pigment issues. Color treated hair also tolerates it well as it helps smooth the cuticle without stripping dye.

Potential Side Effects/Adverse Reactions

Responses to topical Dihydroxypropyl Peg-5 Linoleammonium Chloride differ from person to person. The following outlines potential side effects that could occur although most users will experience none of them when the ingredient is formulated and used correctly.

Mild scalp or skin irritation

Allergic contact dermatitis

Eye irritation if product drips into eyes

Product buildup on hair leading to limp feel when overused or not rinsed completely

If you notice any troubling reaction stop using the product and consult a healthcare professional or dermatologist.

Comedogenic Rating

Rating: 1/5 (very low)

Dihydroxypropyl Peg-5 Linoleammonium Chloride is highly water soluble, lightweight and designed to rinse clean. Its large, charged structure keeps it sitting on the surface rather than sinking into pores where clogging occurs. The PEG-5 segment also improves rinsability, further reducing any chance of buildup inside follicles.

Because of this low rating, the ingredient is generally considered suitable for people prone to acne or breakouts.

As with any conditioning agent, overuse in leave-on products can lead to residue that might trap other comedogenic materials, so balanced formulation is still important.

Summary

Dihydroxypropyl Peg-5 Linoleammonium Chloride acts mainly as an antistatic and hair conditioning agent. Its positively charged ammonium head latches onto the negatively charged sites on hair, forming a thin flexible film that smooths the cuticle, eases detangling and cuts static. The PEG-5 and dihydroxypropyl parts keep the molecule water loving so it spreads evenly and rinses away without heaviness.

It is not one of the beauty world’s headline ingredients but formulators appreciate its mildness so you will see it crop up in a growing number of modern shampoos, conditioners and sprays that aim for a clean feel.

Safety data show a low irritation and sensitization profile when used as intended. Still, everyone’s skin is different so it is wise to patch test new products that contain this or any other unfamiliar ingredient.

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