Dipentaerythrityl Hexacaprylate/Hexacaprate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 27, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Dipentaerythrityl Hexacaprylate/Hexacaprate?

Dipentaerythrityl Hexacaprylate/Hexacaprate is a synthetic ester created by linking fatty acids, mainly caprylic (C8) and capric (C10) acids, to a sugar-derived alcohol known as dipentaerythritol. The fatty acids are typically sourced from renewable plant oils such as coconut or palm, while dipentaerythritol is produced from glycerin and formaldehyde. When these components are combined through a controlled esterification process, the result is a clear, lightweight liquid that blends easily with other cosmetic ingredients.

The material first gained traction in the 1990s as formulators searched for non-greasy alternatives to mineral oil and heavier plant oils. Because the ester sits between an oil and a silicone in feel, it became popular in modern skin care where a silky, fast-absorbing finish is prized.

Production starts with refining the fatty acids from plant oils, purifying the dipentaerythritol, then reacting them together at elevated temperatures in the presence of a catalyst. The final mixture is filtered, deodorized and quality-checked before being shipped to cosmetic labs.

You will typically see Dipentaerythrityl Hexacaprylate/Hexacaprate in lightweight facial moisturizers, anti aging creams, sunscreens, makeup primers, liquid foundations, hair serums, body lotions, sheet masks and eye treatments where a smooth touch and stable texture are essential.

Dipentaerythrityl Hexacaprylate/Hexacaprate’s Cosmetic Benefits/Uses

This multitasking ester improves both the feel and performance of many personal care products.

  • Skin conditioning: Softens and hydrates the surface of the skin, leaving it feeling supple without a heavy or oily residue
  • Smoothing: Provides a silky slip that helps products glide on evenly, blurs the look of fine lines and creates a refined finish that enhances makeup wear
  • Emulsifying: Helps oil- and water-based ingredients stay mixed, resulting in stable creams and lotions that do not separate over time
  • Viscosity controlling: Adjusts thickness so formulators can create anything from fluid serums to rich creams while still maintaining a pleasant, spreadable texture

Who Can Use Dipentaerythrityl Hexacaprylate/Hexacaprate

This lightweight ester suits most skin types, including normal, dry, combination and mature skin. Its fast-absorbing nature makes it a good option for oily or acne-prone skin because it delivers softness without a greasy film, though people extremely prone to clogged pores may still prefer to limit rich emollients.

The ingredient is produced from plant-derived fatty acids and a synthetically made sugar alcohol, so products using it are typically considered vegan and vegetarian friendly as no animal raw materials or by-products are involved.

Current safety data show no specific risks for women who are pregnant or breastfeeding when the ingredient is used topically at standard cosmetic levels. This is not medical advice and anyone who is pregnant or nursing should have their healthcare provider review any skincare products they plan to use.

Dipentaerythrityl Hexacaprylate/Hexacaprate is not known to increase photosensitivity, so it will not make skin more prone to sunburn. It is also fragrance free and non-volatile, which further reduces the chance of irritation for sensitive users.

Potential Side Effects/Adverse Reactions

Reactions to topical Dipentaerythrityl Hexacaprylate/Hexacaprate vary from person to person. The points below outline potential issues that could occur, although they are uncommon when the ingredient is properly formulated and used as intended.

  • Mild skin irritation such as redness or stinging, especially on very sensitive skin
  • Contact allergy in individuals already sensitized to fatty acid esters
  • Breakouts or clogged pores in those highly prone to comedones
  • Eye irritation if the product accidentally gets into the eyes

If any of these reactions develop discontinue use and seek medical advice if symptoms persist or worsen.

Comedogenic Rating

Dipentaerythrityl Hexacaprylate/Hexacaprate scores a 1 on the 0-5 comedogenic scale. Its molecules are branched and lightweight so they spread easily without forming the thick film that can trap dead cells and oil inside pores. Unlike richer plant butters or straight fatty acids, this ester absorbs quickly and leaves minimal residue, which lowers the chance of blocked pores.

Because the rating is low it is generally fine for skin that is prone to acne or breakouts, though individual responses can still differ.

Formulas that pair this ester with heavier oils, waxes or high levels of silicones could raise the overall pore-clogging potential of the finished product, so looking at the full ingredient list is always smart.

Summary

Dipentaerythrityl Hexacaprylate/Hexacaprate acts as a skin conditioner, slip enhancer, emulsifier and viscosity controller. Its branched ester structure lets it soften the skin while creating a silky feel, it keeps water and oil phases stable in creams and it adjusts thickness without greasiness. These traits make it useful in everything from light serums to rich night creams.

The ester is not a household name like glycerin yet formulators value it for giving a modern, fast-absorbing finish. You will spot it more often in mid- to high-end skincare and makeup than in basic drugstore lotions.

Current safety data show a very low risk of irritation or sensitization at normal use levels. As with any new product it is wise to do a quick patch test to confirm personal compatibility before applying it all over the face or body.

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