Fibroin/Peg-16/Sodium Acrylate Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 27, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Fibroin/Peg-16/Sodium Acrylate Copolymer?

Fibroin/Peg-16/Sodium Acrylate Copolymer is a blended polymer made from three parts: fibroin, a protein spun by silkworms to build their cocoons; PEG-16, a short chain form of polyethylene glycol that gives water solubility; and sodium acrylate, a synthetic building block used to make flexible gels. Scientists combine these components through controlled polymerization, creating a lightweight network that dissolves in water yet dries to form a clear flexible film on skin or hair.

Silk proteins have been prized for centuries for their smooth feel, and modern labs began extracting fibroin in the mid-20th century for wound dressings and later for beauty formulas. By grafting fibroin onto PEG and sodium acrylate chemists produced a more stable ingredient that handles well in water-based creams and sprays. Today the copolymer shows up in sheet masks, leave-on moisturizers, makeup primers, anti-aging serums, hair styling products and long-wear foundations where a thin protective layer is desired.

Fibroin/Peg-16/Sodium Acrylate Copolymer’s Cosmetic Benefits/Uses

This ingredient is mainly valued for one key role in formulas.

Film forming: When the product dries the copolymer sets into an invisible breathable film that helps hold moisture on the surface, smooths rough texture and gives a soft silky finish. The film can also boost the staying power of makeup, limit smudging, reduce flyaways in hair care and shield skin from everyday pollution.

Who Can Use Fibroin/Peg-16/Sodium Acrylate Copolymer

The copolymer is generally well tolerated by every major skin type. It feels weightless which suits oily and combination skin, yet its water-binding film can help relieve surface tightness on dry or mature skin. Those with very sensitive skin or a known allergy to silk proteins should proceed cautiously because the fibroin portion could trigger redness or itching in rare cases.

Since fibroin is harvested from silkworm cocoons the ingredient is of animal origin, making it unsuitable for vegans or strict vegetarians who avoid insect-derived materials.

No research links the topical use of this copolymer to hormonal disruption or birth defects, so it is generally viewed as pregnancy and breastfeeding friendly. This is not medical advice and anyone who is pregnant or nursing should confirm product choices with a doctor to be safe.

The film former is not photo-reactive and does not increase sun sensitivity. It also plays well with most common actives, though its tight surface layer can slightly slow the penetration of heavier serums applied on top.

Potential Side Effects/Adverse Reactions

Responses to Fibroin/Peg-16/Sodium Acrylate Copolymer vary from person to person. The following issues are possible yet unlikely for the average user when the ingredient is formulated correctly.

  • Mild skin irritation such as redness stinging or itching, usually in very sensitive or compromised skin
  • Allergic reaction in individuals with a specific sensitivity to silk proteins
  • Transient tightness if the film is layered too thick or used alongside strong drying agents
  • Pilling or flaking when incompatible products are layered over the dried film
  • Minor pore congestion in users who are highly prone to buildup, although the risk is low

If any discomfort swelling or rash develops stop use immediately and consult a healthcare professional.

Comedogenic Rating

Rating: 1 / 5 — Very low likelihood of clogging pores

This copolymer is water soluble and forms a lightweight breathable film that tends to sit on the surface rather than seeping deep into follicles. Its molecules are large and do not carry heavy oils or waxes so they are unlikely to block pores. A small number of users who are extremely prone to buildup might notice mild congestion if multiple layers are applied without proper cleansing, which is why the rating is a cautious 1 instead of 0.

Overall it is considered suitable for acne-prone skin.

Formulation matters: when the copolymer is blended with richer emollients or occlusive agents in a product the overall clogging risk can rise, but that comes from the companion ingredients not the copolymer itself.

Summary

Fibroin/Peg-16/Sodium Acrylate Copolymer is a modern film former that glides on, dries clear and locks in lightweight moisture. The silk-derived fibroin adds a soft touch, PEG-16 keeps the polymer water friendly and sodium acrylate gives flexible hold. Together they create a thin breathable layer that smooths skin, boosts makeup wear and tames frizz in hair.

It is not as famous as hyaluronic acid or silicone blends yet formulators like it because it is easy to use in water-based products and gives a distinct silky finish without heaviness. You will most often spot it in sheet masks, long-wear makeup and light styling creams.

Current research and consumer reports point to a strong safety profile with only rare irritation in those sensitive to silk proteins. As with any new cosmetic ingredient it is smart to patch test a small area first to make sure your skin agrees before incorporating a full-size product into daily use.

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