Glyceryl Diethylsiloxanes: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 27, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Glyceryl Diethylsiloxanes?

Glyceryl Diethylsiloxanes is a hybrid ingredient created when glycerin, the well loved humectant drawn from plant oils, reacts with diethylsiloxane, a lightweight silicone unit. The result is a smooth, silky fluid that blends the moisturizing feel of glycerin with the flexible, water resistant traits of silicones. Chemists first explored this combination in the late 1990s while looking for gentler substitutes for heavier silicone films used in hair serums and facial primers. Today the process is fairly straightforward: glycerin and diethylsiloxane are combined in controlled conditions, the mix is heated to start a condensation reaction, then purified to remove any unreacted material. The finished mixture is stable, clear and easy to add to creams, lotions, masks, leave in conditioners, makeup primers, anti aging serums and even sunscreens where a light protective film is wanted without a greasy after feel.

Glyceryl Diethylsiloxanes’s Cosmetic Benefits/Uses

When formulators drop this ingredient into a product they look to it for several key actions

  • Film forming: It lays down an invisible, flexible layer that locks moisture into skin or hair, helps makeup stay put longer and gives products a smooth glide during application
  • Hair conditioning: The silicone part smooths lifted cuticles, reducing frizz, increasing shine and making combing easier while the glycerin side attracts light moisture for bounce
  • Skin protecting: The soft film shields skin from daily pollutants and irritation, creating a gentle barrier that still allows skin to breathe

Who Can Use Glyceryl Diethylsiloxanes

This ingredient suits most skin types including normal, dry and combination thanks to the balance of light silicone slip and gentle glycerin moisture. Oily or acne prone skin may want to monitor use in very rich formulas because the film it forms could trap excess sebum if the rest of the product is not well balanced.

Glyceryl Diethylsiloxanes is produced from glycerin derived from plant oils and lab made silicone units so it contains no animal material. That makes it acceptable for both vegetarians and vegans as long as the finished product is certified cruelty free.

The compound is considered low risk for people who are pregnant or breastfeeding when used as directed in rinse off or leave on cosmetics. This is not medical advice and anyone expecting or nursing should review all personal care products with a qualified healthcare provider just to be safe.

It does not cause photosensitivity and will not make skin more prone to sunburn. Because it forms a breathable film it can even support the wear of daily sunscreen by reducing rub off. No other special lifestyle restrictions are known.

Potential Side Effects/Adverse Reactions

Side effects linked to topical Glyceryl Diethylsiloxanes vary from person to person. The points below list potential issues yet most users will not notice any problems when the ingredient is included at standard levels in well formulated products.

  • Mild skin irritation in very sensitive individuals
  • Temporary clogged pores if heavy layers are applied on oily skin
  • Build up on hair shafts leading to limp feel if not cleansed regularly
  • Contact dermatitis in rare cases of silicone allergy
  • Reduced penetration of certain active ingredients due to its protective film

If any discomfort, rash or unexpected reaction occurs stop use immediately and seek advice from a healthcare professional.

Comedogenic Rating

Rating: 2/5. Glyceryl Diethylsiloxanes relies on lightweight silicone units that sit on the surface rather than sinking deep into pores, which keeps the risk of blockage fairly low. The glycerin portion attracts a bit of water that can thin the film further. Still, its film forming nature can trap existing oil if heavy layers build up, so it is not entirely free of breakout potential.

Most people prone to acne can usually tolerate it in well balanced formulas, though very oily or congested skin might prefer lighter products or occasional use.

Comedogenicity often depends on the entire formula and how thoroughly the product is cleansed off, not just the presence of this single ingredient.

Summary

Glyceryl Diethylsiloxanes acts as a film former, hair conditioner and skin protectant. The silicone side lays down a smooth flexible shield that locks in moisture, tames frizz and helps makeup or sunscreen stay put, while the glycerin side attracts light hydration for a softer feel. This dual action lets products deliver slip without greasy weight.

The ingredient is not as famous as dimethicone or pure glycerin but formulators appreciate its balanced texture, so it shows up in a growing number of primers, leave in conditioners and lightweight lotions.

Current safety data classifies it as low risk with minimal irritation potential when used at normal cosmetic levels. While most users enjoy trouble free wear, it is always smart to patch test any new product to confirm personal compatibility.

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