Heptyl Undecylenate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 27, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Heptyl Undecylenate?

Heptyl undecylenate, sometimes listed as heptyl undec-10-enoate, is an ester formed by joining heptanol, a seven-carbon alcohol, with undecylenic acid, an 11-carbon fatty acid that contains one double bond. Both building blocks are commonly sourced from renewable raw materials such as castor oil, coconut oil or sugarcane, making the final ingredient a plant-derived option prized by brands looking for more sustainable choices. The compound first attracted attention in the personal care world in the early 2000s when formulators began searching for lighter replacements for traditional mineral oils and silicones. Through interest in “green chemistry” it has since gained popularity as a naturally sourced, high-performance texture enhancer.

Commercially, heptyl undecylenate is created through an esterification reaction: the fatty acid and alcohol are heated together in the presence of a catalyst, water is removed and the mixture is purified until a clear, odorless liquid remains. The resulting material is lightweight, spreads easily and has a dry, non-oily feel on skin.

Because of those texture qualities you will often see heptyl undecylenate in facial and body moisturizers, lightweight lotions, sunscreens, primers, foundations, hair serums and even some sheet masks. It is especially popular in “clean beauty” and “silicone-free” formulas where silky slip and fast absorption are desired without relying on petroleum-derived ingredients.

Heptyl Undecylenate’s Cosmetic Benefits/Uses

In cosmetics heptyl undecylenate serves as an emollient. As an emollient it softens and smooths the skin surface by filling in microscopic gaps between cells, which helps maintain a supple feel and improves overall skin comfort. The ingredient also adds a light, silky glide to creams, lotions and makeup, making them easier to spread while leaving minimal residue or greasiness. Formulators value its ability to mimic the sensory profile of certain silicones yet remain biodegradable and plant based, so it can elevate product texture while supporting more eco-conscious marketing claims.

Who Can Use Heptyl Undecylenate

Heptyl undecylenate is lightweight and non greasy, so it suits most skin types including oily, combination, normal and even sensitive skin that dislikes heavy occlusive oils. Extremely dry or eczema prone complexions may find that they still need a richer occlusive on top, but the ingredient itself is not known to worsen dryness or flaking.

Because it is derived from plant sources such as castor or coconut oil, it is suitable for vegans and vegetarians and does not rely on any animal by products or animal testing when sourced from reputable suppliers.

Current data shows no known risks for women who are pregnant or breastfeeding when the ingredient is used topically at the low levels found in cosmetics. That said this is not medical advice and anyone who is expecting or nursing should review any skincare product with their physician to be sure it fits their personal situation.

Heptyl undecylenate is not photosensitising, so it does not make skin more prone to sunburn. It can safely be used in daytime formulas including sunscreens and makeup.

Potential Side Effects/Adverse Reactions

Responses to topical ingredients can vary between individuals. The points below outline potential side effects that have been reported or are theoretically possible with heptyl undecylenate, though they remain uncommon when the ingredient is correctly formulated and used as directed.

  • Mild skin irritation – a small number of users may notice temporary redness or stinging, especially if skin is already compromised
  • Contact dermatitis – very rare allergic reactions can manifest as itching, swelling or a rash
  • Breakouts in acne prone skin – while the ingredient is considered low clogging, a few individuals with highly reactive pores may experience pimples
  • Eye irritation – if a product containing the ester migrates into the eyes it can cause watering or discomfort until rinsed away

If you experience any persistent or severe reaction stop using the product and consult a healthcare professional for guidance.

Comedogenic Rating

Rating: 1 / 5 – Heptyl undecylenate is considered very low risk for clogging pores. Its ester structure makes it lightweight and fast spreading so it does not sit heavily on skin or create the kind of occlusive film that traps oil and debris. Limited anecdotal reports and in-house brand testing show minimal acne flare-ups compared with richer plant oils or butters.

Because of this low score most people prone to breakouts can use products containing heptyl undecylenate without issue. As always the final formula matters: if the ingredient is blended with heavier waxes or high percentages of other comedogenic agents the finished product could still pose a clogging risk.

Summary

Heptyl undecylenate is a plant-derived emollient that softens skin fills in microscopic gaps between cells and delivers a smooth silky glide to lotions makeup and hair products. By mimicking the feel of certain silicones while remaining biodegradable it helps brands create lightweight eco-minded formulas that absorb quickly and leave little to no residue.

Although not yet as common as long-standing esters or silicones it is gaining traction in clean beauty lines and sunscreen innovations thanks to its pleasant skin feel and sustainability story.

Current research labels the ingredient as low irritation and low comedogenic so it is generally safe for everyday use on most skin types. That said skin can be unpredictable so it is wise to patch test any new product that features heptyl undecylenate before applying it to larger areas.

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