Hexanediol Distearate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 27, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Hexanediol Distearate?

Hexanediol Distearate, also known as hexamethylene distearate, is an ester created when hexanediol, a short synthetic diol, reacts with stearic acid, a fatty acid most often sourced from plant oils like coconut or palm. The result is a waxy, oil-soluble ingredient that combines the smooth feel of fatty acids with the stability of a diol. Chemists first explored it for personal care in the late twentieth century while searching for alternatives to petroleum-derived thickeners and to improve the skin feel of creams.

The manufacturing process is straightforward: stearic acid and hexanediol are heated together in the presence of an acid catalyst so the two molecules join and water is removed. The final material is filtered, cooled and flaked or pelletized for easy handling by formulators.

You will commonly spot Hexanediol Distearate in moisturizers, anti-aging creams, masks, solid balm cleansers, sunscreens, makeup foundations, hair conditioners and leave-on treatments where a velvety texture and light occlusive layer are desired.

Hexanediol Distearate’s Cosmetic Benefits/Uses

This ingredient serves a couple of key roles that make it valuable in modern formulations:

  • Skin Conditioning: Forms a soft, breathable film on the surface of skin that helps reduce moisture loss so skin feels smoother and better hydrated. The fatty acid portions deliver a silky after-feel without heaviness, which can enhance user sensory experience.
  • Viscosity Controlling: Thickens oil and emulsion systems, allowing formulators to achieve richer creams, stable balms or trendier “butter” textures without relying on heavier waxes. This stability helps keep the product uniform from the first to the last use.

Who Can Use Hexanediol Distearate

Because it is lightweight yet still provides a protective film, Hexanediol Distearate tends to suit most skin types including normal, dry, combination and even mildly oily skin that wants extra softness without a greasy after-feel. Those with very oily or acne-prone skin might prefer to patch test formulas that contain higher levels of this ester, as its occlusive nature can sometimes feel too rich for them.

The ingredient itself is synthesized from stearic acid that can be sourced from plants or animals, so strict vegans and vegetarians should check with the brand to confirm vegetable sourcing before purchase.

No data suggest that topical use of Hexanediol Distearate is unsafe during pregnancy or while breastfeeding. Still, this is not medical advice. Expectant or nursing mothers should review any skincare routine with their healthcare provider to be certain it meets their individual needs.

Hexanediol Distearate does not cause photosensitivity, meaning it does not make skin more prone to sunburn. Normal daily sun protection is still encouraged for overall skin health.

Potential Side Effects/Adverse Reactions

Responses to topical ingredients vary from person to person. The effects listed below are possible yet uncommon when Hexanediol Distearate is used at standard levels in well-formulated products.

  • Mild skin irritation
  • Redness or warmth at the application site
  • Temporary clogged pores in very oil-rich formulations
  • Allergic contact dermatitis in individuals sensitive to fatty acid esters

If any of these reactions occur discontinue use and consult a qualified medical professional.

Comedogenic Rating

Rating: 2/5

Hexanediol Distearate contains long stearic acid chains that can sit on skin and potentially trap dead cells but it is also an ester that spreads well and is usually included at modest percentages. This balance places it at the lower end of the mildly comedogenic range.

People who are prone to acne or frequent breakouts can often use it without problems but lighter formulas and lower use levels are generally preferred.

Keep in mind that overall formula design, concentration and the presence of other pore clogging ingredients will influence how any product performs on breakout-prone skin.

Summary

Hexanediol Distearate works mainly as a skin conditioning agent that leaves a silky protective film and as a viscosity controller that thickens oils and emulsions for richer textures. It achieves these effects thanks to its fatty stearate portions that soften skin and its diol core that lends stability in a wide temperature range.

While not as widely talked about as hyaluronic acid or shea butter it remains a reliable behind-the-scenes helper in moisturizers sunscreens makeup sticks and cleansing balms where a smooth buttery feel is desired.

Current safety data show it to be low risk for irritation or sensitization when used as intended. As with any new skincare ingredient try a small patch test first to be sure your skin agrees with it.

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