Isobutylene/Ma Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 30, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Isobutylene/Ma Copolymer?

Isobutylene/MA Copolymer is a synthetic polymer created by combining isobutylene, a small hydrocarbon gas, with maleic anhydride, an organic acid derivative. When these two building blocks react they form long repeating chains that give the final material flexible film forming properties. The ingredient was first explored by the plastics industry in the mid-20th century for its ability to create clear tough coatings. Formulators soon noticed that those same qualities could help cosmetics stay put on skin and hair, so it made its way into beauty products during the late 1970s as an alternative to older resins that felt stiff or flaky.

Production starts with refining petroleum to isolate isobutylene gas. Maleic anhydride is obtained through the oxidation of benzene or butane. Under controlled heat and pressure, the two react to form a copolymer that is then purified, dried and milled into a fine powder or small granules. It dissolves in specific solvents and swells in water, letting chemists tailor texture and hold.

You will most often find Isobutylene/MA Copolymer in hair sprays, styling gels, brow setters, long-wear makeup, peel-off face masks, certain sunscreens and serums that need a light protective film. It appears in both mass and professional lines because it is stable, colorless and works at low use levels.

Isobutylene/Ma Copolymer’s Cosmetic Benefits/Uses

This versatile polymer earns its spot on an ingredient list by delivering several practical benefits:

  • Film forming: Creates an invisible, flexible layer on skin or hair that locks in active ingredients, boosts water resistance and helps makeup last longer without smudging
  • Hair fixing: Provides controlled hold and definition in sprays, mousses and gels so styles keep their shape while still feeling touchable
  • Viscosity controlling: Thickens or stabilizes formulas, giving creams, lotions and serums a smooth glide and preventing separation during shelf life

Who Can Use Isobutylene/Ma Copolymer

Because Isobutylene/MA Copolymer is an inert, non-reactive film former it is generally considered suitable for all skin types, including oily, combination, normal, dry and even most sensitive complexions. It does not clog pores or leave a heavy occlusive layer, so acne prone and congested skin usually tolerate it well. People with very compromised or highly sensitized skin should still proceed cautiously, as any polymer film can occasionally feel tight or drying if the formula lacks enough emollients.

The ingredient is made from petroleum derived raw materials and contains no animal by-products so it is appropriate for vegans and vegetarians.

Current safety data indicate no hormonal or systemic concerns, which means products using Isobutylene/MA Copolymer are generally viewed as safe for use during pregnancy and breastfeeding. This is not medical advice and pregnant or nursing individuals should review any skincare routine with their physician to be sure it meets their personal needs.

Isobutylene/MA Copolymer does not make skin more sensitive to sunlight and it has no known interactions with UV exposure, so there is no added risk of photosensitivity.

Potential Side Effects/Adverse Reactions

Responses to topical Isobutylene/MA Copolymer can differ from person to person. The following is a list of potential but uncommon side effects. When a product is formulated and used correctly most users will not experience any of these issues.

  • Skin irritation or redness
  • Allergic contact dermatitis in individuals already sensitized to similar resins
  • Temporary scalp buildup or flaking when used in heavy styling products
  • Mild eye stinging if aerosol or gel migrates into the eye area
  • Acne flare ups in very breakout prone skin if combined with highly occlusive ingredients

If you develop any uncomfortable reaction stop using the product and consult a healthcare professional for guidance.

Comedogenic Rating

Rating: 1/5. Isobutylene/MA Copolymer builds a lightweight film on the surface rather than seeping into pores and it contains no oily or waxy fractions that typically trigger clogging. Its large molecular size prevents deep follicular penetration which keeps the risk of pore blockages low. The score is not a perfect zero since any film former could trap existing sebum and debris if layered heavily with greasy ingredients.

With this very low rating most people prone to acne or breakouts can use products containing Isobutylene/MA Copolymer without extra concern.

Formulation matters: pairing the polymer with highly occlusive butters or heavy silicones may raise the practical comedogenicity of the finished product even though the copolymer itself stays non-pore-clogging.

Summary

Isobutylene/MA Copolymer acts as a film former that keeps makeup, sunscreen and active ingredients in place, a hair-fixing agent that provides flexible hold and a viscosity controller that stabilizes texture and flow. It achieves these tasks by creating a transparent lattice on skin or hair that resists water, adds structure and prevents separation.

The polymer shows up in a fair number of mainstream sprays, gels and long-wear cosmetics, though it is not as buzzworthy as plant-based gums or silicone elastomers so many users may not even notice it on the label.

Safety data classify it as non-sensitizing, non-photosensitizing and free of systemic concerns. While reactions are rare it is smart to patch test any new product since individual sensitivities vary.

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