Methyl Behenate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Methyl Behenate?

Methyl behenate, also called methyl docosanoate, is the ester that forms when behenic acid, a 22-carbon saturated fatty acid, reacts with methanol. Behenic acid itself occurs naturally in a range of vegetable oils such as rapeseed, peanut and Moringa seed oil. Turning the fatty acid into an ester makes it lighter, less greasy and easier to blend into modern skin care formulas.

The cosmetic industry began looking at long-chain esters like methyl behenate in the 1970s as brands searched for plant-based alternatives to heavy mineral oils. Today manufacturers usually create it through a simple, food-grade esterification process: refined behenic acid from seed oils is combined with methanol in the presence of a catalyst, then the finished ester is purified and filtered.

Thanks to its smooth texture and stability, methyl behenate shows up in a variety of personal care items. You will most often find it in moisturizers, night creams, anti-aging serums, face masks, lip balms, sunscreens and leave-in hair conditioners where it helps products feel silky without leaving an oily film.

Methyl Behenate’s Cosmetic Benefits/Uses

Here is how this ingredient supports the performance and feel of your favorite products:

  • Humectant – attracts and holds water on the skin surface helping to keep dryness and tightness at bay so skin feels soft and refreshed
  • Skin conditioning – smooths the skin surface and improves overall texture giving formulas a pleasant glide while leaving skin supple and comfortable

Who Can Use Methyl Behenate

Methyl behenate is gentle and lightweight so it suits most skin types including dry, normal and combination skin. Because it is less greasy than many fatty ingredients it can also work for oily skin, though anyone who clogs easily may still prefer to use it only in rinse-off or lighter leave-on products.

The ester is sourced from vegetable oils and contains no animal-derived matter so it is considered vegan and vegetarian friendly.

Current data shows no specific risks for pregnant or breastfeeding women when the ingredient is used in cosmetics. This is not medical advice and anyone who is expecting or nursing should ask a healthcare professional before adding new products to a routine just to be safe.

Methyl behenate does not make skin more sensitive to sunlight and there are no known conflicts with common active ingredients such as retinoids or exfoliating acids.

Potential Side Effects/Adverse Reactions

Side effects from topical methyl behenate are uncommon and can differ from one person to the next. The following points list potential reactions but most users will not run into these problems when the product is properly formulated and used as directed.

  • Skin redness or mild irritation
  • Allergic contact dermatitis in people sensitive to fatty alcohols or esters
  • Minor breakouts in very acne-prone skin
  • Stinging or watering if the product accidentally gets into the eyes

If any of these issues develop stop using the product and speak with a medical professional if symptoms persist or worsen.

Comedogenic Rating

Rating: 2 / 5

Methyl behenate is a long chain fatty ester that sits lightly on the surface rather than sinking deep into pores, so it is less likely to clog than heavier plant butters or mineral oils. Still, its fatty backbone can create a thin occlusive layer and in very oily or congestion-prone skin that layer may trap debris leading to small pimples. Most users will have no issue, but those who break out easily might prefer low-percentage or rinse-off formulas.

Keep in mind that comedogenicity can vary with the final product’s overall blend, concentration and how often it is applied.

Summary

Methyl behenate acts mainly as a humectant and skin-conditioning agent. It pulls in moisture while laying down a smooth lightweight film, leaving skin soft hydrated and comfortable without a greasy afterfeel.

The ingredient is more of a behind-the-scenes workhorse than a headline grabber. It appears in a steady stream of moisturizers, sunscreens and lip products because formulators value its silky slip and stability even if most shoppers have never heard of it.

Safety data rate it as low risk with minimal irritation or allergy reports. As with any new cosmetic though, patch test on a small area first to make sure your skin agrees before using a product more broadly.

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