Methylbutylphenyl Hexyloxybenzoate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Methylbutylphenyl Hexyloxybenzoate?

Methylbutylphenyl Hexyloxybenzoate is a lab made ester derived from benzoic acid that is joined with a hexyloxy group and a branched alcohol called 2-methyl-1-butanol. Chemists link these parts together through a simple reaction known as esterification, where the acid and alcohol are heated with a catalyst until water is removed and the new molecule forms. Because the starting materials are easy to source from plant based feedstocks or petroleum, the ingredient can be produced in large batches with tight purity controls.

The cosmetic industry became interested in this ester in the early 2000s when formulators were searching for lightweight skin conditioners that would not feel greasy. Its balanced chain length gives it a silky glide that rivals some silicones while staying friendly to a wide range of skin types. Today you will most often see Methylbutylphenyl Hexyloxybenzoate in leave-on products such as daily moisturizers, anti-aging creams, facial masks, lightweight lotions, sunscreens that aim for a pleasant skin feel, and specialty serums designed to smooth rough texture.

Methylbutylphenyl Hexyloxybenzoate’s Cosmetic Benefits/Uses

In skin care formulas this ingredient serves mainly one purpose that brings several practical perks.

Skin conditioning: Methylbutylphenyl Hexyloxybenzoate softens and smooths the skin surface, helping creams and lotions spread easily and leave a velvety after-feel. By forming a thin flexible layer it can reduce the look of dry flakes, enhance suppleness and boost the overall sensory appeal of a product without clogging pores or feeling heavy.

Who Can Use Methylbutylphenyl Hexyloxybenzoate

This silky ester is generally considered friendly for most skin types including dry, normal, combination and even oily or breakout prone skin because it is lightweight and has a very low likelihood of clogging pores. Sensitive skin can usually tolerate it as the molecule is non reactive and fragrance free, though individual responses always vary.

Methylbutylphenyl Hexyloxybenzoate is made entirely from synthetic or plant derived feedstocks without any animal sourced materials so it fits vegan and vegetarian lifestyles.

No studies have flagged the ingredient as a concern for women who are pregnant or breastfeeding since skin absorption is minimal and the body can break the ester down into benign substances. This is not medical advice and anyone who is expecting or nursing should still show their doctor any product they plan to use to be sure it aligns with personal health needs.

The molecule does not make skin more sensitive to sunlight and does not break down in a way that would generate photosensitising by products so daytime use is considered safe when paired with a regular sunscreen.

Potential Side Effects/Adverse Reactions

Side effects from topical use of Methylbutylphenyl Hexyloxybenzoate can differ from person to person. The following points list potential reactions yet they remain uncommon for the average user when the ingredient is correctly formulated.

  • Mild skin irritation such as temporary redness or stinging, typically in very sensitive individuals
  • Contact allergy presenting as itchiness or localized rash in those with a specific sensitivity to benzoate esters
  • Eye irritation if the product accidentally gets into the eyes, causing watering or a brief burning sensation
  • Acne like breakouts in rare cases where the user is extremely clog prone or layer multiple occlusive products on top
  • Interaction with other actives like high concentration acids or retinoids potentially increasing overall skin dryness

If any discomfort or persistent reaction occurs stop using the product and consult a qualified healthcare professional or dermatologist.

Comedogenic Rating

Rating: 1 out of 5

Methylbutylphenyl Hexyloxybenzoate is a lightweight ester that spreads thinly and does not create a heavy film on the skin. Its molecular size and branched structure limit its ability to block pores which is why it earns a low score of 1. That means it is very unlikely to trigger blackheads or whiteheads for most people. Those who are prone to acne or breakouts can generally use products containing this ingredient without added worry. Because it is an ester rather than a wax or thick oil it also plays well with water based and silicone based formulas further lowering clogging risk.

Summary

Methylbutylphenyl Hexyloxybenzoate is primarily a skin conditioning agent. It smooths and softens by laying a thin flexible layer over the skin surface which helps reduce the look of dryness and gives lotions or serums a silky glide. It pulls off this task without feeling greasy thanks to its balanced chain length and branched alcohol side.

While it is not the most famous name on an ingredient list it has gained a quiet following among formulators who want the slip of a silicone but prefer an ester that can be labeled as skin friendly. You will see it pop up more often in modern lightweight moisturizers and hybrid skincare makeup.

Current data shows the molecule is low risk for irritation or pore clogging which makes it suitable for a wide range of skin types. Still, everyone’s skin is unique so do a small patch test when trying a new product that features this ester to make sure it agrees with you.

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