Octoxynol-20 Carboxylic Acid: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 30, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Octoxynol-20 Carboxylic Acid?

Octoxynol-20 Carboxylic Acid is a synthetic ingredient made by attaching roughly 20 units of ethylene oxide to a starting material called octylphenol then adding a carboxylic acid group at one end. The resulting molecule has a water-loving (hydrophilic) chain and an oil-loving (lipophilic) tail, giving it excellent surfactant properties. It was first introduced in the mid-20th century when chemists began modifying nonionic surfactants to improve their mildness and rinsability in personal care products. Today manufacturers produce it through controlled polymerization of ethylene oxide followed by carboxylation, steps carried out under strict temperature and pressure to ensure a consistent average of 19 to 20 ethylene oxide units.

Because it helps water mix with oils and dirt, Octoxynol-20 Carboxylic Acid is commonly found in facial cleansers, micellar waters, exfoliating masks, makeup removing lotions, refreshing body washes and some mild shampoos. Formulators like it for gentle daily-use products aimed at sensitive or combination skin since it lifts impurities without leaving a heavy residue or tight feel.

Octoxynol-20 Carboxylic Acid’s Cosmetic Benefits/Uses

This ingredient appears on labels primarily for one reason, and that is cleansing.

As a cleansing agent it lowers the surface tension of water so it can spread easily and surround oils, makeup and environmental grime. When the product is rinsed away the trapped impurities go with it, leaving skin or hair feeling fresh yet comfortable. The molecule’s balanced hydrophilic-lipophilic nature means it can remove oily build-up without stripping natural moisture, which helps maintain the skin barrier and reduces the chance of post-wash dryness.

Who Can Use Octoxynol-20 Carboxylic Acid

Most skin types can tolerate Octoxynol-20 Carboxylic Acid because it is classified as a mild nonionic surfactant. Oily, combination and normal skin generally appreciate its ability to lift excess sebum without leaving a residue. Sensitive skin often does well too, provided the final formula contains soothing ingredients and an appropriate pH. Very dry or severely compromised skin may sometimes feel a bit tight after repeated use since any surfactant has the potential to wash away some lipids, so those users might prefer richer cream cleansers or shorter contact time.

The ingredient is synthesized entirely from petrochemical feedstocks and contains no animal-derived substances, so it is considered suitable for vegans and vegetarians. Manufacturers usually list it in cruelty-free lines, although shoppers should still check the brand’s overall animal testing stance.

Current cosmetic safety assessments have not flagged Octoxynol-20 Carboxylic Acid as problematic during pregnancy or breastfeeding. Concentrations used in rinse-off products are typically low and the molecule does not readily penetrate intact skin. This is not medical advice; pregnant or nursing individuals should review any skincare routine with their physician to stay on the safe side.

The molecule does not absorb UV light and is not known to make skin more sensitive to the sun, so no special photo-precaution is required beyond normal daily SPF habits.

Potential Side Effects/Adverse Reactions

Responses to topical Octoxynol-20 Carboxylic Acid vary from person to person. The effects listed below are possible yet uncommon when the ingredient is used at the low levels typical of well-formulated cosmetic cleansers.

  • Mild skin irritation slight burning or stinging can occur if the product is left on too long or used on very compromised skin
  • Dryness or tightness especially after frequent washing or in high concentrations without added moisturizers
  • Transient redness usually subsides quickly once the product is rinsed away
  • Allergic contact dermatitis rare sensitization may lead to itching bumps or a rash
  • Eye irritation possible watering or stinging if the cleanser accidentally enters the eyes

If any of these reactions develop stop using the product and seek advice from a healthcare professional.

Comedogenic Rating

Rating: 1 / 5

Octoxynol-20 Carboxylic Acid is a small nonionic surfactant that rinses away almost completely and does not leave an oily film. Because it helps remove excess sebum rather than sit on the skin, the likelihood of clogged pores is very low, which is why it earns a score of 1.

People who are prone to acne or breakouts can usually use products containing this ingredient without added concern.

As with any cleanser the final formula matters. Heavy emollients or fragrances paired with it could influence pore clogging more than the surfactant itself.

Summary

Octoxynol-20 Carboxylic Acid is a synthetic surfactant used in cleansers and makeup removers to help water mix with oil, dirt and product residue. Its balanced hydrophilic and lipophilic structure surrounds grime then lifts it off the skin once rinsed, leaving a clean yet comfortable feel.

It is not as famous as big-name surfactants like sodium lauryl sulfate but formulators appreciate its mildness, easy incorporation and cost effectiveness, so it quietly shows up in many gentle wash-off products.

Safety reviews find it non-sensitizing at typical rinse-off levels with only rare reports of irritation. Still, every skin is unique so do a quick patch test when trying a new product that lists Octoxynol-20 Carboxylic Acid to make sure it plays well with your skin.

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