Peg-2 Coco-Benzonium Chloride: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg-2 Coco-Benzonium Chloride?

Peg-2 Coco-Benzonium Chloride is a cationic surfactant made by linking coconut-derived fatty acids with two units of polyethylene glycol, then adding a benzyl chloride group to give it a permanent positive charge. This positive charge makes the molecule attracted to the slightly negative surface of hair and skin, which is why it stays in place and does its job even after rinsing. Quaternary ammonium compounds like this one have been used in personal care since the mid-twentieth century when formulators searched for conditioners that could tame static and improve rinse-off. Today the ingredient is produced in a controlled, multi-step process: first the coconut fatty acids are ethoxylated, then the intermediate is reacted with benzyl chloride to quaternize the nitrogen atom, and finally the product is purified and standardized for cosmetic use. You will most often find Peg-2 Coco-Benzonium Chloride in shampoos, conditioners, detangling sprays, facial cleansers, body washes and wet wipes where a light conditioning or antistatic touch is needed without a heavy feel.

Peg-2 Coco-Benzonium Chloride’s Cosmetic Benefits/Uses

Formulators pick this ingredient for two main reasons that improve how a product performs and feels:

  • Antistatic: The positive charge neutralizes the negative charge that builds up on hair fibers during washing or brushing which cuts flyaways and makes hair easier to comb while adding a smooth feel to skin
  • Cleansing: Its surfactant nature loosens dirt oil and residue so they can be rinsed away yet it is mild enough to avoid stripping the skin or hair of all its natural moisture

Who Can Use Peg-2 Coco-Benzonium Chloride

This conditioning cleanser is generally gentle enough for all skin and hair types including oily, dry, combination and sensitive skin thanks to its mild surfactant base and low use levels. Those with very sensitive or eczema-prone skin may want to keep an eye on how their skin feels since any quaternary ammonium compound has a small chance of causing irritation if left on too long or used in a leave-on formula that is too strong.

The coconut source of the fatty acids means the ingredient is plant derived so it is normally suitable for vegans and vegetarians, provided the finished product is not tested on animals and any other raw materials in the formula are also animal free.

No data show that Peg-2 Coco-Benzonium Chloride poses a special risk during pregnancy or while breastfeeding when used in rinse-off levels typical of shampoos and cleansers. Still this is not medical advice and anyone who is pregnant or nursing should ask a doctor before starting a new personal care product just to be safe.

The molecule does not make skin more prone to sunburn so it is not considered photosensitising. It also plays well with most other cosmetic ingredients although it can lose some of its conditioning power if mixed with large amounts of very strong anionic (negatively charged) surfactants.

Potential Side Effects/Adverse Reactions

Reactions to topical Peg-2 Coco-Benzonium Chloride differ from person to person. The points below cover potential side effects that could occur even though most people will not experience them when the ingredient is used at the low levels found in cosmetics formulated by reputable brands.

  • Skin irritation such as redness or a stinging sensation, especially on broken or very dry skin
  • Contact dermatitis in individuals allergic to quaternary ammonium compounds
  • Eye irritation if the product accidentally gets into the eyes before rinsing
  • Scalp dryness or flaking when used in a leave-on hair product at higher than recommended levels
  • Hair build up over time leading to a weighed-down feeling if the product is not rinsed thoroughly

If any of these effects occur stop using the product and seek advice from a healthcare professional or pharmacist.

Comedogenic Rating

Rating: 1 / 5

Peg-2 Coco-Benzonium Chloride is water soluble and does not leave an oily film that can trap dead cells or sebum in pores. Its positive charge helps it rinse away cleanly so it rarely builds up on facial skin. For these reasons it scores a low 1 meaning it is unlikely to clog pores.

Suitable for acne-prone or breakout-prone skin in the low concentrations used in rinse-off products.

Because it bonds lightly to hair and skin a very small amount might linger after rinsing. If you notice product build-up on the face consider a gentle double cleanse to keep pores clear.

Summary

Peg-2 Coco-Benzonium Chloride acts as a mild cleanser and an antistatic conditioner. Its surfactant part loosens dirt and oil so they rinse away while the permanently positive quaternary head sticks to negatively charged hair and skin to smooth cuticles and calm static.

You will see it in some shampoos, light conditioners, body washes and wipes but it is not as widespread as better-known quats like Behentrimonium Chloride. Formulators choose it when they want a very light conditioning feel.

Overall safety is good at cosmetic use levels with irritation only in a small number of sensitive users. As with any new product a patch test on a small area is a smart way to check personal tolerance before regular use.

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