Peg-20 Methyl Glucose Sesquistearate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg-20 Methyl Glucose Sesquistearate?

Peg-20 Methyl Glucose Sesquistearate is a plant-derived ingredient made by joining glucose from corn with stearic acid from vegetable oils and then adding about twenty units of ethylene oxide. The result is a nonionic surfactant that looks like an off-white waxy solid. Chemists first explored sugar-and-oil combinations in the 1980s while searching for milder alternatives to traditional emulsifiers. Over time this particular blend proved stable, gentle and easy to manufacture at scale, so formulators adopted it for creams and lotions. Production starts with methyl glucose, which reacts with stearic acid to form methyl glucose sesquistearate. The mixture is then “PEGylated,” meaning ethylene oxide units are attached to increase water solubility and improve performance in emulsions. You will most often see Peg-20 Methyl Glucose Sesquistearate in moisturizers, sunscreens, light facial lotions, makeup removers, sheet mask essences and hair conditioners where it helps oil and water stay perfectly mixed.

Peg-20 Methyl Glucose Sesquistearate’s Cosmetic Benefits/Uses

The ingredient plays one key role in topical products.

As an emulsifying agent it keeps oil-based and water-based ingredients blended into a smooth, uniform texture. This stability prevents separation, improves spreadability, enhances the feel on skin and helps deliver active ingredients evenly with each application.

Who Can Use Peg-20 Methyl Glucose Sesquistearate

This emulsifier is considered gentle enough for almost all skin types including normal, dry, oily and combination. Its nonionic nature keeps it from upsetting the skin’s acid mantle which makes it a good option for sensitive skin as well. Those with extremely reactive or allergy-prone skin may still want to monitor for any individual sensitivities but there is no widespread concern about irritation.

The raw materials are plant derived so the ingredient is suitable for vegans and vegetarians. No animal by-products are used in its standard manufacturing process and it is not tested on animals by most reputable suppliers.

Current safety data show no specific risks for pregnant or breastfeeding women when the ingredient is used topically at the low levels found in finished cosmetics. This is not medical advice and anyone who is expecting or nursing should have a doctor review their skincare routine to be safe.

Peg-20 Methyl Glucose Sesquistearate does not make skin more prone to sunburn and has no known photosensitizing effect. It also plays well with common actives such as retinol, vitamin C, niacinamide and sunscreen filters without destabilizing them.

Potential Side Effects/Adverse Reactions

Responses to topical Peg-20 Methyl Glucose Sesquistearate vary from person to person. The following is a list of potential side effects that could occur, though they are uncommon when the ingredient is used within standard cosmetic concentrations.

  • Mild stinging or burning on very compromised or freshly exfoliated skin
  • Transient redness due to individual sensitivity
  • Rare allergic contact dermatitis triggered by stearic acid or polyethylene glycol residues
  • Eye irritation if a high-concentration formula accidentally enters the eyes

If you experience any of these reactions stop using the product and consult a healthcare professional or dermatologist for guidance.

Comedogenic Rating

Rating: 1 / 5

Peg-20 Methyl Glucose Sesquistearate sits at the low end of the scale because the bulky PEG chains make it highly water compatible, so it does not readily lodge inside pores. It is used at small percentages and mostly stays on the surface to stabilize the formula rather than penetrating into follicles. In practical terms it is unlikely to trigger blackheads or pimples, which makes it generally appropriate for acne-prone skin.

Keep in mind the overall formulation matters; if the product also contains rich oils or waxes the breakout risk will depend on the blend, not this emulsifier alone.

Summary

Peg-20 Methyl Glucose Sesquistearate is a plant-based, PEG-modified emulsifier whose chief job is to keep oil and water mixed so lotions, creams and cleansers stay smooth, spread well and deliver actives evenly. Its nonionic structure gives products a pleasant, non-greasy feel and helps stabilize a wide pH range.

While not a headline ingredient, it is quietly popular with formulators because it is reliable, mild and compatible with most actives. You will spot it in everything from budget moisturizers to premium sunscreens.

Current research and decades of use show it to be very safe for topical application with only rare reports of irritation or allergy. Still, skin can be unpredictable so it is wise to patch test any new product that contains this or any other unfamiliar ingredient.

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