Peg-40 Glyceryl Cocoate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg-40 Glyceryl Cocoate?

Peg-40 Glyceryl Cocoate is a plant-derived liquid made by joining coconut fatty acids with glycerin and then attaching about forty units of ethylene oxide. This combination creates a mild, water-friendly ingredient that can mix oil and water with ease. Interest in such gentle surfactants started in the 1950s when brands looked for alternatives to harsher soaps, and Peg-40 Glyceryl Cocoate quickly gained ground because it offered the cleaning power chemists wanted without stripping skin and hair.

The ingredient is produced in two main steps. First, coconut oil is split to release its fatty acids, which are then bonded to glycerin to form glyceryl cocoate. Second, the mixture is treated with controlled amounts of ethylene oxide, giving it the “PEG-40” part of its name. The result is a clear to pale yellow liquid that dissolves in water yet still grabs onto oils, making it a versatile helper in many beauty formulas.

You will find Peg-40 Glyceryl Cocoate in facial cleansers, micellar waters and body washes, as well as makeup removers, moisturizers, sunscreens, hair conditioners, bath oils and even pre-shave lotions. Its ability to keep formulas stable and leave a soft after-feel makes it a favorite of chemists working on products for sensitive skin.

Peg-40 Glyceryl Cocoate’s Cosmetic Benefits/Uses

Here is how this multitasking ingredient earns its spot on an ingredient list

  • Cleansing  Peg-40 Glyceryl Cocoate lifts away dirt oil and makeup then rinses off easily so skin and hair feel fresh yet not tight
  • Emulsifying  It binds water and oil into a smooth stable mixture which keeps creams and lotions from separating and gives them a pleasant light texture

Who Can Use Peg-40 Glyceryl Cocoate

This gentle surfactant suits nearly every skin type including oily, combination, normal, dry and even sensitive because it cleans without stripping natural moisture. People with severely compromised or allergy-prone skin should still read labels carefully, as any polyethylene glycol derivative can occasionally trigger sensitivity in those groups.

Peg-40 Glyceryl Cocoate is typically acceptable for vegans and vegetarians since its fatty acids come from coconut and the glycerin used in cosmetics is almost always plant sourced. Anyone seeking guaranteed animal-free status should look for a vegan certification logo or ask the brand directly.

Current safety assessments show no specific risks for pregnant or breastfeeding women when this ingredient is applied topically at the levels found in finished products. This is not medical advice so expectant or nursing mothers should review their routine with a qualified health professional just to be sure.

The ingredient does not increase skin photosensitivity and can be used morning or night alongside sunscreen. It is also found in both rinse-off and leave-on formulas, making it versatile for face, body and hair care.

Potential Side Effects/Adverse Reactions

Responses to Peg-40 Glyceryl Cocoate vary from person to person. The points below describe potential reactions but they are uncommon when the ingredient is used correctly in a finished product.

  • Mild skin irritation temporary redness or itching can appear on very sensitive or damaged skin
  • Eye stinging formulas with higher amounts may cause discomfort if they get into the eyes
  • Allergic contact dermatitis rare cases of localized rash have been reported in people allergic to polyethylene glycol derivatives
  • Dryness or tightness high surfactant levels in a product could leave skin feeling dry especially with frequent use
  • Enhanced penetration of other ingredients damaged skin may allow small amounts of this PEG to carry irritants deeper leading to secondary sensitivity

If you notice burning itching swelling or any other unexpected reaction stop using the product and consult a healthcare professional

Comedogenic Rating

Rating: 1 / 5

Peg-40 Glyceryl Cocoate is highly water soluble and does not leave an oily film on skin. The PEG groups make the coconut fatty acids more hydrophilic which reduces their tendency to sit in pores and form blockages. Published ingredient databases and anecdotal reports rarely link this surfactant to clogged pores which supports the low score.

With such a low rating the ingredient is generally considered suitable for people prone to acne or breakouts.

Keep in mind that a finished product’s overall comedogenicity depends on the full formula so the presence of Peg-40 Glyceryl Cocoate does not guarantee a product will be non clogging if heavier oils or waxes are also included.

Summary

Peg-40 Glyceryl Cocoate acts mainly as a cleanser and emulsifier. Its surfactant head attracts water while its fatty tail grabs onto oils letting grime lift away and rinse off cleanly. The same dual nature stabilizes creams by holding water and oil phases together which gives formulas a smooth light feel.

The ingredient enjoys solid popularity in face washes micellar waters and lightweight lotions because it is effective gentle and compatible with many other materials though it is not as talked about as newer exotic surfactants.

Current safety reviews show it is well tolerated at the levels used in cosmetics with only rare irritation or allergy reports. As with any new product it is wise to perform a simple patch test to make sure your skin agrees with the full formula.

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