Peg-40 Sorbitan Peroleate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg-40 Sorbitan Peroleate?

Peg-40 Sorbitan Peroleate is a nonionic surfactant created by linking sorbitol, a sugar alcohol usually sourced from corn or other starch rich crops, with roughly forty units of ethylene oxide and then reacting the result with oleic acid, the main fatty acid in olive oil and many seed oils. The finished ingredient is a waxy or thick liquid that mixes well with both water and oil, which makes it useful when formulating beauty products.

Scientists began combining sorbitan esters with polyethylene glycol in the 1950s while searching for milder alternatives to soap based surfactants. Since then Peg-40 Sorbitan Peroleate has become a staple in cleansers, lotions and haircare because it helps oil and water stay blended without the need for strong detergents or heavy thickeners.

Manufacturing starts with dehydrating sorbitol to form sorbitan, adding ethylene oxide under controlled heat and pressure, then esterifying the product with purified oleic acid. The outcome is filtered and tested for purity before being supplied as a cosmetic raw material.

You will most often spot it in facial cleansing oils, makeup removers, moisturizers, sheet masks, hair conditioners, mild body washes and spray on treatments that need a stable oil in water mix.

Peg-40 Sorbitan Peroleate’s Cosmetic Benefits/Uses

Peg-40 Sorbitan Peroleate offers a couple of key actions that improve how a product feels and performs on skin or hair.

  • Cleansing: Its surfactant nature lifts away dirt, makeup and excess sebum while remaining gentler than many sulfate based cleaners, so formulas can cleanse without leaving skin tight
  • Emulsifying: It keeps oil and water evenly blended which prevents separation, gives lotions a smooth texture and allows light, non greasy emulsions that absorb quickly

Who Can Use Peg-40 Sorbitan Peroleate

Peg-40 Sorbitan Peroleate is generally suitable for all skin types including dry, oily, combination and sensitive skin because it is a mild surfactant that does not drastically disturb the skin’s natural oils. Extremely reactive or allergy-prone skin may still want to approach with caution since any surfactant can cause issues in rare cases.

The ingredient is usually sourced from plant materials like corn and vegetable oils and contains no animal-derived components, so it is considered appropriate for vegans and vegetarians as long as the finished formula follows the same sourcing standards.

Current safety data show no specific risks for people who are pregnant or breastfeeding. That said this information is not medical advice and anyone who is expecting or nursing should confirm the suitability of any skincare product with a qualified healthcare provider.

Peg-40 Sorbitan Peroleate does not make skin more prone to sunburn and it is stable under normal daylight, so no extra sun precautions are required beyond regular sunscreen use.

The ingredient is compatible with most common actives and does not interfere with makeup wear or hair color, making it a versatile option across many product categories.

Potential Side Effects/Adverse Reactions

Responses to topical Peg-40 Sorbitan Peroleate differ from person to person. The effects listed below are possibilities, not the norm, and most people will not notice any problems when the ingredient is used correctly in a well-formulated product.

  • Skin irritation – mild redness or itching can occur in very sensitive individuals
  • Contact allergy – rare cases of allergic dermatitis have been reported in people already sensitized to polyethylene glycol derivatives
  • Eye stinging – higher concentrations near the eye area may cause temporary discomfort
  • Dryness – overuse in leave-on products could strip natural oils in those with already dry skin
  • Increased absorption of other ingredients – as a surfactant it can slightly enhance penetration of actives which may amplify their own irritant potential

If you notice persistent redness, itching or any other concerning reaction stop using the product and seek advice from a medical professional.

Comedogenic Rating

Rating: 1 / 5

Peg-40 Sorbitan Peroleate is highly water-soluble and its fatty acid portion is heavily modified by polyethylene glycol, which keeps the molecule from behaving like pure oleic acid on skin. Studies and anecdotal reports show little tendency to clog pores, so it earns a low score of 1. This means it is generally suitable for people prone to acne or breakouts.

Because the ingredient also helps rinse away excess sebum rather than sitting on the skin, the risk of buildup is minimal even in leave-on products formulated at typical use levels (1-4%).

Summary

Peg-40 Sorbitan Peroleate acts mainly as a mild cleanser and an oil-in-water emulsifier. Its surfactant head attracts water while the fatty tail grabs oils, letting it lift away dirt and makeup and keep lotions or sprays from separating. These dual abilities let formulators create lightweight textures that spread easily and rinse clean.

The ingredient is not as famous as some newer green emulsifiers yet remains a quiet workhorse in cleansers, creamy serums and hair treatments because it is reliable, cost-effective and easy to incorporate.

Current safety data show a low risk of irritation or sensitization when used within recommended limits, making it safe for most consumers. As with any new cosmetic product it is smart to patch test first to check personal tolerance.

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