Peg-5 Tricapryl Citrate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg-5 Tricapryl Citrate?

Peg-5 Tricapryl Citrate is a synthetic ingredient created by linking citric acid, plant-derived caprylic fatty acids and a short chain of ethylene oxide units. The result is a clear to pale yellow liquid that acts like both oil and water, which is why chemists place it in the family of PEG (polyethylene glycol) esters. It first entered cosmetic labs in the late 1980s when formulators were looking for gentler alternatives to heavy waxes for keeping water and oil mixed. Production begins with food-grade citric acid. Each of its three hydroxyl groups is reacted, or esterified, with caprylic fatty alcohols taken from coconut or palm kernel oil. A controlled amount of ethylene oxide is then added to create an average of five repeating units, giving the molecule the “Peg-5” label. After purification, the liquid is ready to blend into cosmetic bases at low levels, usually between 0.5 and 4 percent. You will most often spot Peg-5 Tricapryl Citrate in lightweight moisturizers, anti-aging serums, masks, sunscreens, creamy cleansers and leave-on treatments where a smooth non-greasy feel is important.

Peg-5 Tricapryl Citrate’s Cosmetic Benefits/Uses

In skin and hair care formulas Peg-5 Tricapryl Citrate serves one key job that supports both product performance and sensory appeal.

As an emulsifying agent it helps water and oil stay blended, preventing separation during storage and use. A stable emulsion spreads more evenly, allows active ingredients to be delivered consistently and gives the finished product a pleasing silky texture. Its lightweight nature also cuts down on the greasy after-feel that heavier emulsifiers can leave behind, which is why it is favored in modern fast-absorbing creams and sprays.

Who Can Use Peg-5 Tricapryl Citrate

Peg-5 Tricapryl Citrate is generally well tolerated by all skin types, including dry, oily, combination and sensitive skin, because it is lightweight and nonocclusive. People with very reactive or damaged skin should still monitor how their skin feels, as any new ingredient can sometimes trigger a response.

The ingredient is produced from plant sourced fatty acids and synthetically derived ethylene oxide, with no animal inputs, so it is suitable for vegetarians and vegans.

Current safety data show no specific risks for pregnant or breastfeeding women when the ingredient is used at the low levels found in cosmetics. This is not medical advice and anyone who is pregnant or nursing should discuss any skincare products with a qualified health professional before use.

Peg-5 Tricapryl Citrate does not absorb UV light or make skin more sensitive to the sun, so it is not considered photosensitising. It is also odor free and has no known interactions with common active ingredients like retinoids or vitamin C.

Potential Side Effects/Adverse Reactions

Reactions to topical Peg-5 Tricapryl Citrate can vary from person to person. The points below describe potential side effects only. When the ingredient is formulated and used correctly most people will not experience any problems.

  • Mild skin irritation such as burning or stinging, usually in those with a compromised skin barrier
  • Redness or itching caused by a true allergy to the PEG portion of the molecule, which is rare
  • Contact dermatitis if the product contains high levels of other irritants that work synergistically with the emulsifier
  • Breakouts or clogged pores in individuals who are extremely acne prone and react to any fatty esters, though the ingredient itself has a low comedogenic profile

If any of these effects occur stop using the product immediately and seek advice from a healthcare provider or dermatologist.

Comedogenic Rating

Rating: 1 out of 5. Peg-5 Tricapryl Citrate is a small lightweight ester that spreads easily and rinses off without leaving a thick film. Its molecular structure does not readily block pores and it is used at low percentages in finished products, so the chance of it trapping oil or dead skin is minimal. It is generally suitable for acne prone or breakout prone skin. Very sensitive or highly reactive skin types could still notice congestion if a formula contains other heavier ingredients that sit on top of Peg-5 Tricapryl Citrate, but the emulsifier itself is unlikely to be the culprit.

Because it helps keep water and oil mixed, it can actually improve the feel of acne treatments by making them lighter and less greasy, cutting down on the surface residue that sometimes contributes to clogged pores.

Summary

Peg-5 Tricapryl Citrate is primarily an emulsifier that lets water based and oil based ingredients coexist in a smooth, stable lotion or serum. By anchoring both phases at once it prevents separation, enhances even spread and leaves a clean non greasy finish.

While not as famous as big name emulsifiers like polysorbates it shows up steadily in modern lightweight skincare because formulators appreciate its gentle feel and reliable performance. It is most common in mid market moisturizers and treatment serums aimed at consumers looking for fast absorbing textures.

Current research and decades of safe use point to a low risk profile with very rare reports of irritation or allergy. Still, individual skin can react unpredictably so it is wise to patch test any new product that features Peg-5 Tricapryl Citrate before applying it all over the face.

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