Peg-6 Caprylic/Capric Glycerides: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg-6 Caprylic/Capric Glycerides?

Peg-6 Caprylic/Capric Glycerides is an ingredient made by attaching an average of six units of ethylene oxide to glycerides that come from medium-chain fatty acids found in coconut and palm kernel oils. The result is a clear to pale-yellow liquid that blends the skin-friendly nature of natural oils with the water-loving character of polyethylene glycol. This balance allows it to mix oil and water smoothly, which is why it is valued in modern skin care.

The path to its cosmetic use began in the late 20th century when formulators searched for milder alternatives to harsh detergents. By tweaking the number of ethylene oxide units, chemists created a family of PEG glycerides with different solubility profiles. Peg-6 struck a sweet spot of mildness and performance, so it quickly found a place in cleansers and lotions.

Manufacturing starts with caprylic and capric fatty acids combined with glycerol to form mono-, di-, and triglycerides. These glycerides are then reacted with ethylene oxide under controlled heat and pressure. The six-unit average keeps the molecule small enough to remain light in texture yet large enough to disperse oils evenly in water-based formulas.

You will most often see Peg-6 Caprylic/Capric Glycerides in facial cleansers, micellar waters, makeup removers, lightweight moisturizers, hydrating toners, sheet mask essences, and baby care products that call for a gentle touch.

Peg-6 Caprylic/Capric Glycerides’s Cosmetic Benefits/Uses

This ingredient serves one main purpose in skin care formulas.

Emulsifying: Peg-6 Caprylic/Capric Glycerides helps oil and water stay blended, creating stable lotions and cleansers that feel smooth and rinse off easily. A good emulsifier prevents separation, improves texture, and can enhance the delivery of nourishing oils without leaving a greasy residue.

Who Can Use Peg-6 Caprylic/Capric Glycerides

This emulsifier is generally well tolerated by all skin types. Its lightweight non occlusive nature suits oily and combination skin while its mildness makes it comfortable for dry and sensitive skin. People with very compromised or highly reactive skin should still monitor how their skin feels since any surfactant, even a gentle one, can sometimes add to dryness if used in high amounts.

Peg-6 Caprylic/Capric Glycerides is plant derived when manufacturers source the caprylic and capric fatty acids from coconut or palm kernel oil and the glycerin from vegetable feedstocks. No animal byproducts are required so the ingredient itself is considered suitable for vegans and vegetarians. Formulas that include it may still contain other animal derived ingredients, so label reading is advised.

Based on available safety data this ingredient is viewed as low risk for use during pregnancy or while breastfeeding. That said this information does not replace medical advice and pregnant or nursing individuals should clear any skin care routine with their healthcare provider.

It is non sensitizing to sunlight and does not increase photosensitivity so it will not make skin burn faster in the sun. There are no known incompatibilities with common actives like retinol or vitamin C, which lets formulators pair it freely in multi-benefit products.

Potential Side Effects/Adverse Reactions

Responses to topical Peg-6 Caprylic/Capric Glycerides vary from person to person. The following list covers potential side effects that could occur, though most users experience none of these issues when the ingredient is formulated and used correctly.

Skin irritation mild redness or itching can occur in those with very sensitive or damaged skin barriers

Eye stinging if a cleanser containing high levels of the ingredient gets into the eyes it can cause temporary discomfort

Dryness or tightness overuse of products with a high surfactant load may strip natural oils leading to a dry feel

Allergic contact dermatitis rare allergy to polyethylene glycol structures or trace manufacturing impurities can trigger rash or swelling

1,4-dioxane residue concern improper purification during production of PEG materials can leave traces of this solvent which can in turn irritate very sensitive skin, although reputable suppliers use vacuum stripping to remove it

If any of these reactions develop stop using the product and consult a healthcare professional for guidance.

Comedogenic Rating

Rating: 1/5  Peg-6 Caprylic/Capric Glycerides is highly water soluble and leaves very little oily residue on skin, so it has a low likelihood of blocking pores. The medium-chain fatty acids are bonded to polyethylene glycol, which keeps the molecule lightweight and rinsable rather than greasy. Most acne-prone users can comfortably use products containing this emulsifier.

Keep in mind that a finished formula’s pore-clogging potential also depends on the other ingredients and the overall oil load, not just this single component.

Summary

Peg-6 Caprylic/Capric Glycerides is mainly an emulsifier that lets water and oil stay blended, creating smooth cleansers, milks and lotions that rinse clean without film. Its small size and balance of oil-loving and water-loving parts let it dissolve makeup and sebum while remaining gentle on skin.

It is a behind-the-scenes helper rather than a headline act, but you will see it quite often in micellar waters, baby cleansers and lightweight moisturizers because formulators like its mildness and versatility.

Safety reviews rate it low risk, with irritation or allergy being uncommon and usually linked to very sensitive skin or poorly purified batches. As with any new product, do a quick patch test when it first joins your routine so you can spot any personal sensitivities early.

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