Peg-6 Dioleate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg-6 Dioleate?

Peg-6 Dioleate is a synthetic ingredient made by attaching roughly six units of ethylene oxide to dioleic acid, a fatty acid commonly obtained from plant oils such as olive or sunflower oil. The result is a waxy fluid that mixes well with both water and oil. Chemists first explored this type of material in the mid-20th century when the beauty industry needed reliable ingredients that could help water and oil stay blended. By adjusting the number of ethylene oxide units, they found a balance that felt light on skin yet still kept formulas stable, leading to the six-unit version widely used today.

The manufacturing process starts with natural dioleic acid that is cleaned and purified. This acid then reacts with ethylene oxide gas in a controlled setting. Temperature and pressure are carefully managed to add exactly six units of the gas to each fatty acid segment. The finished Peg-6 Dioleate is filtered, quality checked and supplied as either a liquid or soft paste for easy mixing into cosmetic bases.

Because it helps oil and water mingle, Peg-6 Dioleate shows up in many product types. It is common in facial cleansers, makeup removers, lightweight lotions, hydrating masks and hair conditioners. Some brands also add it to exfoliating scrubs and tanning creams whenever they need a smooth, uniform texture that does not separate on the shelf.

Peg-6 Dioleate’s Cosmetic Benefits/Uses

The main role of Peg-6 Dioleate in cosmetics is as an emulsifying agent. By lowering the surface tension between water and oil, it keeps formulas from splitting, which means creams stay creamy and cleansers rinse off cleanly. A well-emulsified product spreads more evenly on skin, feels nicer to the touch and delivers active ingredients in a uniform way.

Who Can Use Peg-6 Dioleate

Peg-6 Dioleate is considered gentle enough for most skin types, including normal, dry, oily and combination skin. Its lightweight feel and non-greasy finish make it especially handy in products for oily or acne-prone skin, while its fatty acid base can add a touch of emollience that dry or mature skin appreciates. People with very sensitive or highly reactive skin may want to keep an eye on formulations with high levels of any PEG ingredient, as their skin can sometimes react to large molecule blends, but this tends to be uncommon.

The ingredient is generally suitable for vegans and vegetarians because the dioleic acid is typically sourced from plant oils and the remaining components are synthetic. Brands that follow strict vegan guidelines often confirm the plant origin of the fatty acid portion and avoid animal testing, so it is worth checking brand ethics if that is important to you.

No specific restrictions have been issued for pregnant or breastfeeding women when it comes to topical use of Peg-6 Dioleate. Current safety assessments show low systemic absorption and no known reproductive concerns, yet this is not medical advice. Anyone who is expecting or nursing should review their entire skincare routine with a healthcare professional to be extra cautious.

Peg-6 Dioleate does not increase photosensitivity, meaning it will not make skin more prone to sunburn. As always, daily sunscreen is still recommended to protect against UV damage.

Potential Side Effects/Adverse Reactions

Reactions to any cosmetic ingredient can vary from person to person. The points below outline potential side effects of Peg-6 Dioleate, though most users will not experience them when the ingredient is properly formulated and used as directed.

  • Mild skin irritation
  • Transient redness or warmth at the application site
  • Rare allergic contact dermatitis in individuals already sensitized to PEG compounds
  • Eye irritation if a product containing the ingredient accidentally enters the eyes

If you notice persistent irritation, redness or any other concerning reaction while using a product that contains Peg-6 Dioleate, discontinue use and consult a healthcare professional or dermatologist.

Comedogenic Rating

Rating: 1/5. Peg-6 Dioleate is largely water dispersible thanks to its polyethylene glycol portion, which keeps the fatty acid chains from building up on skin and clogging pores. Most studies and anecdotal reports place PEG-based emulsifiers at the lower end of the comedogenic scale because they rinse away easily. Therefore it is generally acceptable for acne-prone or breakout-prone skin. Formulas that pair it with heavy oils or waxes could still pose a clogging risk, so the full ingredient list always matters.

Summary

Peg-6 Dioleate works mainly as an emulsifier, binding oil and water so creams stay smooth, cleansers rinse clean and actives are delivered evenly. Its structure combines a plant-derived fatty acid with about six ethylene oxide units, giving it both oil-loving and water-loving sections that line up at the oil-water interface and keep mixtures stable.

The ingredient is moderately popular; you will spot it in everyday cleansers, makeup removers, light lotions and some hair products, but it is not as ubiquitous as classic emulsifiers like polysorbates. Formulators appreciate its balanced feel and reliability, which keeps it in steady though not headline-grabbing demand.

Current safety data show low irritation rates, minimal systemic absorption and a very low comedogenic score, making Peg-6 Dioleate a safe choice for most users. As with any new cosmetic product, a simple patch test on a small area of skin is wise before full-face or body use.

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