Peg/Ppg-116/66 Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg/Ppg-116/66 Copolymer?

Peg/Ppg-116/66 Copolymer is a synthetic polyether made by linking two well-known building blocks, ethylene oxide and propylene oxide, in an average ratio of 116 to 66 units. The raw materials usually come from refined petroleum derivatives or plant-based alcohols that are converted into the two oxides, then reacted step by step to form long chains. This process, called sequential polymerization, lets chemists control the final chain length and balance of hydrophilic (water-loving) and lipophilic (oil-loving) portions, giving the ingredient its useful dissolving power.

Polyether blends like this began showing up in personal care labs in the mid-20th century as makers searched for ingredients that could keep formulas clear and stable. Over time, formulators noticed that the Peg/Ppg family could dissolve oily actives, help them stay evenly dispersed, and feel light on skin, so the copolymers earned a spot in moisturizers, lightweight serums, sunscreens, foundations, cleansing balms, sheet mask essences, hair conditioners, and even some gentle exfoliating gels.

Peg/Ppg-116/66 Copolymer’s Cosmetic Benefits/Uses

In skin and hair care formulas Peg/Ppg-116/66 Copolymer serves one main purpose that can make a big difference in texture and performance.

As a solvent it helps dissolve oils, fragrances, and certain active ingredients so they mix smoothly with water-based phases. This keeps a product clear, prevents separation, and allows the beneficial ingredients to spread evenly over skin or hair, improving feel and overall effectiveness.

Who Can Use Peg/Ppg-116/66 Copolymer

This solvent is considered gentle enough for all skin types including dry, oily, combination and sensitive skin because it sits on the surface briefly then evaporates or rinses away without clogging pores or leaving a film. People with a badly compromised skin barrier may still want to watch for stinging since any solvent can feel tingly on broken skin.

The ingredient is produced entirely from petrochemical or plant-derived alcohols and contains no animal material so it is suitable for vegans and vegetarians.

No data suggest special risks in pregnancy or while breastfeeding when used topically in normal cosmetic concentrations. Still this is not medical advice and anyone who is pregnant or nursing should clear every product with a doctor first just to be safe.

Peg/Ppg-116/66 Copolymer does not make skin more prone to sunburn and has no known interactions with UV exposure.

Potential Side Effects/Adverse Reactions

Reactions to any cosmetic ingredient vary from person to person. The effects listed below are possible but unlikely for most users when the product is well formulated and used as directed.

  • Mild transient stinging or warmth on very sensitive or broken skin
  • Temporary redness or itching due to irritation
  • Contact dermatitis in individuals allergic to polyethylene glycol classes
  • Eye irritation if the product accidentally gets into the eyes
  • Enhanced penetration of other actives which could amplify their own side effects

If you experience any of the above stop using the product and consult a healthcare professional.

Comedogenic Rating

Rating: 0 / 5

Peg/Ppg-116/66 Copolymer is a lightweight water-soluble solvent that does not form an oily film or stay on the skin long enough to block pores. Its large, highly hydrated molecules rinse away easily and are not metabolized by skin surface bacteria, factors that keep it from encouraging clogged pores or breakouts.

Because of this it is generally considered safe for acne-prone skin.

No published data suggest it aggravates fungal acne, and it does not interact with sebum in a way that would create waxy residues.

Summary

Peg/Ppg-116/66 Copolymer is used in cosmetics as a clear, efficient solvent that helps dissolve oils, fragrances and active ingredients so they stay evenly mixed in water-based products. Its balanced polyethylene glycol and polypropylene glycol structure lets it mingle with both water and oil, giving formulators a handy tool for keeping products stable and pleasant to use.

The ingredient is not as famous as glycerin or dimethicone but it quietly appears in a fair number of modern lotions, serums, sunscreens and hair conditioners where a light non-greasy feel is desired.

Safety reviews find it low in irritation potential and free from major health concerns at the low concentrations used in cosmetics. Still every skin is different so it is wise to patch test any new product to rule out personal sensitivity.

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