Peg/Ppg-35/40 Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg/Ppg-35/40 Copolymer?

PEG/PPG-35/40 Copolymer is a synthetic ingredient created by linking polyethylene glycol (PEG) and polypropylene glycol (PPG) blocks. Chemically it results from reacting 35 units of ethylene oxide with 40 units of propylene oxide, producing a water-soluble liquid with both hydrophilic and lipophilic portions. This dual character lets it mix oil and water which is why formulators like it.

The first PEG-PPG block copolymers appeared in the 1960s as scientists searched for mild surfactants that rinsed clean without leaving residue. Over time their safety record and versatility earned them a spot in everyday personal care items.

Manufacturing begins with propylene oxide polymerised to form a PPG backbone. Ethylene oxide is then added, capping the chain with PEG segments. The finished copolymer is purified and quality-checked to meet cosmetic standards.

You will usually spot PEG/PPG-35/40 Copolymer in rinse-off cleansers, micellar waters, facial masks, lightweight moisturisers, hair conditioners and makeup removers where it helps the formula spread evenly and rinse away impurities.

Peg/Ppg-35/40 Copolymer’s Cosmetic Benefits/Uses

This multitasking ingredient supports a formula in several practical ways

  • Cleansing: Its surfactant nature lifts dirt oil and makeup from the skin or hair so they can be rinsed away, promoting a fresh comfortable feel without harshness
  • Solvent: It dissolves both water-soluble and some oil-soluble ingredients helping to keep the product uniform and ensuring active ingredients are evenly distributed every time you use it

Who Can Use Peg/Ppg-35/40 Copolymer

Because it is mild and water soluble PEG/PPG-35/40 Copolymer fits most skin types including oily combination normal and even sensitive skin. Its cleansing action is gentle so it rarely strips moisture yet people with very dry or compromised skin might prefer formulas that balance it with richer emollients.

The ingredient is produced synthetically from petroleum-derived building blocks and contains no animal components which makes it suitable for both vegans and vegetarians.

Current safety assessments rate it as low risk for pregnant or breastfeeding women when used in rinse-off or leave-on cosmetics. That said this is not medical advice and anyone who is pregnant or nursing should run all skincare choices past a qualified healthcare professional just to be safe.

Peg/Ppg-35/40 Copolymer does not cause photosensitivity so it will not make skin more prone to sunburn. It also has no known interactions with common active ingredients such as retinoids acids or vitamin C so it can sit comfortably in multi-step routines.

Potential Side Effects/Adverse Reactions

Responses to any cosmetic ingredient can vary from person to person. The points below outline potential side effects linked to Peg/Ppg-35/40 Copolymer though most users experience none when the product is formulated and used correctly.

  • Mild skin irritation – rare but may appear as transient redness or itching especially on very sensitive skin
  • Contact allergy – uncommon cases of allergic contact dermatitis have been reported with PEG-based ingredients
  • Eye stinging – possible if a high-foam cleanser containing the copolymer gets into the eyes
  • Dryness or tightness – may occur if used in an overly aggressive cleansing routine or on already dehydrated skin
  • Impurity concerns – trace levels of manufacturing by-products like 1,4-dioxane could be present but reputable brands remove them to meet safety limits

If you notice any irritation or discomfort stop using the product and consult a healthcare professional for guidance

Comedogenic Rating

Rating: 0 / 5

PEG/PPG-35/40 Copolymer is highly water soluble and designed to rinse clean, leaving little to no residue that could clog pores. It lacks heavy oils or waxes and is used in very small amounts to help a formula cleanse or dissolve other ingredients. These qualities place it at the bottom of the comedogenic scale.

Because of this low rating it is generally considered suitable for people who are prone to acne or breakouts.

As with any surfactant the overall comedogenicity of a finished product depends on the full formula, not just one ingredient, so oily or acne prone users should still check the rest of the ingredient list.

Summary

PEG/PPG-35/40 Copolymer acts mainly as a mild cleansing agent and solvent. Its dual water loving and oil loving structure lifts grime, makeup and excess sebum then helps them rinse away while also keeping active ingredients evenly dispersed throughout the bottle. This makes it handy in facial washes, micellar waters, light lotions and hair care products.

It is not a headline ingredient like hyaluronic acid or niacinamide yet formulators reach for it often because it is reliable, easy to work with and plays nicely with many actives without adding heaviness.

Safety reviews rate it low risk when purified to cosmetic standards. Most users tolerate it well, irritation is uncommon and it scores a zero for pore clogging. Still, skin can be unpredictable so it is smart to patch test any new product containing this copolymer before making it part of a daily routine.

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