Peg/Ppg-6/4 Dimethicone: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg/Ppg-6/4 Dimethicone?

PEG/PPG-6/4 Dimethicone is a modified form of dimethicone, the silky silicone often used for its smoothing feel. Chemists attach an average of six units of ethylene oxide and four units of propylene oxide to the dimethicone backbone, creating a lightweight liquid that can mix with both water and oil. This tweak gives formulators a versatile ingredient that spreads easily, feels non-greasy and plays well with many other cosmetic raw materials.

The first dimethicone-based products appeared in the 1950s when silicones moved from industrial uses into beauty care. Over time researchers learned that adding polyethylene glycol (PEG) and polypropylene glycol (PPG) blocks made dimethicone more water-friendly, leading to the PEG/PPG family we know today. PEG/PPG-6/4 Dimethicone gained popularity in the 1990s as brands searched for lighter textures that still delivered a protective finish.

Manufacturing starts with medical-grade dimethicone. Through controlled polymerization, chemists graft ethylene oxide and propylene oxide units onto the silicone chain. The result is purified, tested for skin safety and supplied as a clear fluid that stays stable over a wide temperature range.

You will spot PEG/PPG-6/4 Dimethicone in facial moisturizers, hydrating serums, primers, BB creams, sunscreens, leave-in hair conditioners, sheet masks and anti-aging lotions where a soft touch and long-lasting hydration are key.

Peg/Ppg-6/4 Dimethicone’s Cosmetic Benefits/Uses

Formulators rely on this ingredient for several practical benefits that improve both the product and the user experience.

  • Emulsion stabiliser: Keeps oil and water phases from separating, so creams and lotions stay smooth throughout their shelf life and perform the same from the first pump to the last
  • Humectant: Attracts and holds moisture on the skin surface helping to maintain hydration which can leave skin feeling softer and looking plumper

Who Can Use Peg/Ppg-6/4 Dimethicone

This silicone derivative suits most skin types including dry, normal, combination and oily because it provides light moisture without a heavy or greasy after-feel. People with sensitive or redness-prone skin usually tolerate it well since it is inert and non-reactive. Those with very acne-prone skin can also use it as its low occlusivity lets pores breathe, though any new ingredient should be monitored for individual response.

The material is fully synthetic so it contains no animal by-products, making it acceptable for vegans and vegetarians. Standard manufacturing does not rely on animal-derived catalysts or processing aids.

No research indicates that PEG/PPG-6/4 Dimethicone poses risk to pregnant or breastfeeding women when used in topical cosmetics. Still this is not medical advice and anyone expecting or nursing should review their skincare routine with a qualified healthcare provider to be safe.

The ingredient does not make skin more sensitive to sunlight and it has no known interactions with UV filters or self-tanning agents. It is fragrance-free and non-volatile so it will not trigger photosensitivity or photo-allergy.

Potential Side Effects/Adverse Reactions

Reactions to topical PEG/PPG-6/4 Dimethicone differ from person to person. The points below list potential side effects but most users will not experience them if the product has been formulated and preserved correctly.

  • Mild redness or stinging on very sensitive skin
  • Temporary clogged pores or surface buildup in individuals who layer many silicone-rich products
  • Contact dermatitis in the rare case of an individual allergy to silicones or to residual processing impurities
  • Watery eyes or slight irritation if the product accidentally gets into the eye area

If any unwanted reaction occurs stop use immediately and seek advice from a healthcare professional or pharmacist.

Comedogenic Rating

Rating: 1 / 5

PEG/PPG-6/4 Dimethicone is a lightweight silicone with partial water solubility, so it sits on skin as a thin breathable film rather than a heavy plug. Its low occlusivity means it is unlikely to trap sebum or dead cells that could form comedones, earning it a rating of 1. Most acne-prone users tolerate it well, though over-layering several silicone products without thorough cleansing can occasionally lead to buildup.

Summary

PEG/PPG-6/4 Dimethicone works mainly as an emulsion stabiliser and humectant. The silicone backbone gives it slip and spreads oils evenly while the attached PEG and PPG units attract water, locking in lightweight moisture. This dual action keeps creams uniform and skin comfortably hydrated.

Its silky feel and versatility have made it a common pick in modern moisturisers, primers, sunscreens and leave-in hair products, though it is not as wildly popular as classic dimethicone because some brands prefer completely water-soluble alternatives.

Safety data show a very low risk of irritation or sensitisation, so most people can use it without concern. As with any new cosmetic ingredient it is wise to patch test a product first to rule out individual sensitivities.

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