Peg/Ppg-7/50 Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg/Ppg-7/50 Copolymer?

Peg/Ppg-7/50 Copolymer is a synthetic ingredient created by linking together two small molecules, ethylene oxide and propylene oxide. The first forms polyethylene glycol (PEG) units while the second forms polypropylene glycol (PPG) units. In this particular grade the finished chain averages seven PEG links and fifty PPG links, giving the material a balanced mix of water-loving and oil-loving sections. The raw building blocks are mainly sourced from refined petroleum derivatives, though some manufacturers also start with plant-based alcohols that are chemically transformed into the same oxirane intermediates. Large cosmetic suppliers began producing this copolymer in the late twentieth century when formulators needed safer replacements for more aggressive solvents found in fragrances and makeup removers. Production involves controlled ring-opening polymerization where ethylene oxide and propylene oxide are fed into a reactor under heat and pressure, then neutralized and purified until a clear slightly viscous liquid forms. Because it can mingle with water and oils at the same time, Peg/Ppg-7/50 Copolymer shows up in an array of products such as sheet masks, gel moisturizers, lightweight sunscreens, cleansing oils, makeup setting sprays, hair serums and fragrance mists.

Peg/Ppg-7/50 Copolymer’s Cosmetic Benefits/Uses

In formulas Peg/Ppg-7/50 Copolymer serves mainly as a solvent. By dissolving oily fragrances or active ingredients into water-based bases it allows chemists to create clear stable products that would otherwise separate. This improves texture, keeps the formula uniform from the first pump to the last and helps key ingredients spread evenly across skin or hair for consistent results.

Who Can Use Peg/Ppg-7/50 Copolymer

The balanced water-oil nature of Peg/Ppg-7/50 Copolymer makes it compatible with nearly every skin type. Dry skin benefits from its light emollient feel while oily or acne-prone skin usually tolerates it because it does not leave a heavy residue. Sensitive skin users seldom report problems since the ingredient is considered low in irritation potential, though each person’s tolerance can differ.

The material is made by reacting petro- or plant-derived alcohols with ethylene oxide and propylene oxide, with no animal-derived steps, so products that rely on this copolymer fit vegan and vegetarian preferences as long as the rest of the formula also stays animal free.

Available safety data shows no link between Peg/Ppg-7/50 Copolymer and hormonal activity or developmental risks, so it is generally viewed as suitable for pregnant or breastfeeding women. This is not medical advice and anyone who is expecting or nursing should have a doctor review their full skincare lineup for added peace of mind.

The ingredient does not absorb UV light or make skin more reactive to sunlight, so there is no known photosensitivity concern. It is also odorless and non-volatile which helps keep formulas gentle around the eyes and lungs.

Potential Side Effects/Adverse Reactions

Side effects from topical Peg/Ppg-7/50 Copolymer differ from person to person. The points below cover potential reactions only and most users will not experience them when the ingredient is used at standard cosmetic levels.

  • Mild skin irritation – a temporary stinging or burning sensation, usually in people with very reactive skin
  • Contact dermatitis – rare red or itchy patches that resolve once the product is stopped
  • Eye irritation – watering or slight discomfort if a high-concentration product accidentally gets into the eyes
  • Enhanced penetration of other actives – by improving solubility it might increase how fast potent ingredients like retinoids enter the skin which could raise the chance of irritation from those actives
  • Allergic reaction – extremely uncommon swelling or hives in people allergic to polyethylene glycol structures

If any of these effects occur discontinue use and consult a healthcare professional or pharmacist for guidance.

Comedogenic Rating

Rating: 0 (non-comedogenic)

Peg/Ppg-7/50 Copolymer is a large water-soluble molecule that rinses off easily and does not lodge inside pores. It lacks the heavy oils or waxy chains that usually lead to clogs so the likelihood of it causing blackheads or pimples is considered very low.

Because of this the ingredient is generally suitable for acne-prone skin. If breakouts do occur they are more likely linked to other richer components in the same product rather than the copolymer itself.

Summary

Peg/Ppg-7/50 Copolymer works mainly as a solvent letting oily fragrances actives or pigments blend into water-based formulations. Its split personality—PEG parts love water while PPG parts love oil—keeps products clear stable and smooth during use.

It is not a buzzword ingredient yet it shows up in many modern lotions sprays and cleansers because it solves formulating hurdles without adding heaviness scent or color.

Research and decades of use point to a strong safety record with minimal irritation or toxicity concerns at the doses found in cosmetics. Still every skin is unique so doing a quick patch test when trying a new product that contains this copolymer is always a wise move.

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