Pentaerythrityl Triacrylate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Pentaerythrityl Triacrylate?

Pentaerythrityl Triacrylate is made by combining pentaerythritol, a sugar-like alcohol often sourced from plants, with acrylic acid. The result is a triester that behaves like a lightweight plastic when it dries. Chemists first explored this material in the 1970s while looking for better ways to keep pigments and other ingredients from separating in paints. Its clean finish and strong yet flexible film soon caught the attention of cosmetic formulators.

To manufacture it, pentaerythritol reacts with acrylic acid under carefully controlled heat and the presence of a catalyst. The mixture is then purified so no acid remains, leaving a clear liquid that blends smoothly with other cosmetic ingredients.

You will most often spot Pentaerythrityl Triacrylate in products that need to stay put after application. Common examples include nail polish, long wear foundations, liquid lipsticks, waterproof mascaras, peel-off face masks, brow gels and certain sunscreens.

Pentaerythrityl Triacrylate’s Cosmetic Benefits/Uses

When added to a formula, Pentaerythrityl Triacrylate mainly helps with texture and staying power.

  • Binding: It holds pigments, powders and other particles together so the formula applies evenly and resists cracking or flaking.
  • Film Forming: As it dries it creates a thin flexible film on the skin or nail surface that locks in color, improves water resistance and boosts the product’s wear time.

Who Can Use Pentaerythrityl Triacrylate

This film former is generally suitable for all skin types including dry, oily, combination and sensitive skin because it sits on the surface rather than soaking in deeply. Those with very reactive or allergy-prone skin may still want to keep an eye on the ingredient list since rare sensitivities are possible.

Pentaerythrityl Triacrylate is synthesized from plant-derived pentaerythritol and lab-made acrylic acid with no animal by-products, so it is considered vegan and vegetarian friendly.

Pregnant or breastfeeding individuals can usually use products containing this ingredient because topical exposure leads to minimal systemic absorption, but this is not medical advice. Anyone who is expecting or nursing should check with a doctor before adding new cosmetics to their routine to be safe.

The molecule itself is not known to cause photosensitivity and does not make skin more prone to sunburn. Standard sun protection is still recommended whenever you spend time outdoors.

Potential Side Effects/Adverse Reactions

Reactions to topical Pentaerythrityl Triacrylate differ from person to person. The following points list potential side effects that could occur, though most users will not experience them when the ingredient is used correctly in a well-formulated product.

  • Mild skin irritation such as redness or itching
  • Contact dermatitis in individuals with an acrylic allergy
  • Stinging or burning if applied to broken or freshly exfoliated skin
  • Eye irritation if the product accidentally gets into the eyes
  • Nail brittleness or peeling when used in high concentrations in nail coatings

If you notice any of these effects stop using the product and consult a healthcare professional.

Comedogenic Rating

Rating: 1 out of 5. Pentaerythrityl Triacrylate is a lightweight polymer that forms a breathable film on top of the skin without adding oils or waxes that can clog pores. Because it stays mostly on the surface and is used at fairly low levels, it is unlikely to trap sebum or dead cells in a way that sparks breakouts. People who are prone to acne can usually use products with this ingredient without added concern. The only time it might pose a risk is if the overall formula is already heavy or occlusive.

Summary

Pentaerythrityl Triacrylate acts mainly as a binder and film former. It links pigments and powders together so makeup spreads smoothly then dries into a clear flexible film that locks color in place and boosts water resistance. This practical performance explains why you will see it in long wear foundations, waterproof mascaras and gel nail polishes even though it is not the hottest buzzword on ingredient lists. Usage is steady rather than trendy.

Current safety data shows low irritation potential and almost no systemic absorption, making it a reliable choice for most skin types. Still, everyone’s skin is different so it is smart to patch test any new product that contains it before full use.

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