Polyacrylate-33: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Polyacrylate-33?

Polyacrylate-33 is a synthetic polymer created by linking together small units derived from acrylic acid, ethyl acrylate and several specialty methacrylate monomers that carry long fatty chains or polyethylene glycol side groups. This mix of building blocks gives the final polymer a balance of oil-loving and water-loving parts, which lets it work well in many different formulas. First explored in the late twentieth century as a thickening agent for household goods, the ingredient was soon adapted for skin care when formulators noticed how smoothly it dispersed and how stable it kept emulsions under heat or shear.

Production starts with a controlled free-radical polymerization, where the monomers are reacted in water or solvent inside a large stainless-steel kettle. Temperature, pH and the amount of initiator are carefully managed so the chains grow to the right length and branch pattern. Once the reaction is complete, the mixture is neutralized, filtered and dried or kept as an aqueous gel ready to be shipped to cosmetic labs.

Because of its dependable thickening power and gentle skin feel, Polyacrylate-33 shows up in a wide range of products such as lightweight gels, sheet-mask serums, peel-off masks, moisturizing creams, sun care lotions, hair styling gels and color cosmetics like liquid foundations.

Polyacrylate-33’s Cosmetic Benefits/Uses

Formulators reach for Polyacrylate-33 mainly for one key reason

As a viscosity controlling agent it gives a formula the right body and texture so it spreads easily, stays where you put it and delivers active ingredients evenly across the skin or hair. By preventing separation of oil and water phases it also boosts shelf life and keeps the product looking fresh from the first use to the last squeeze.

Who Can Use Polyacrylate-33

Thanks to its neutral pH and non reactive nature Polyacrylate-33 suits most skin types including oily, dry, combination and sensitive skin. It does not penetrate deeply or interact with cell function so the chance of triggering stinging or breakouts is very low. People with highly compromised or broken skin may still wish to steer clear until the skin barrier is restored because any film forming polymer can feel tight or uncomfortable on raw areas.

The ingredient is fully synthetic and contains no animal sourced components which makes it appropriate for vegans and vegetarians. Suppliers typically confirm that no animal testing is performed on the polymer itself in line with cosmetic regulations.

Current safety data shows no reproductive or developmental concerns at the concentrations used in cosmetics so products containing Polyacrylate-33 are generally considered safe for women who are pregnant or breastfeeding. This is not medical advice and anyone who is expecting or nursing should review their routine with a doctor just to be safe.

Polyacrylate-33 does not absorb UV light or increase skin sensitivity to sunlight so it is not regarded as photosensitising. It also plays well alongside common actives like vitamin C, niacinamide and retinoids because it mainly affects texture rather than chemistry.

Potential Side Effects/Adverse Reactions

Responses to any cosmetic ingredient vary from person to person. The effects listed below are possible yet uncommon and most users will not notice any problems when the product is formulated correctly.

  • Mild skin irritation such as tingling or warmth in people with very sensitive skin
  • Redness or itching if an allergy to acrylate polymers is present
  • Eye irritation if the raw gel or a product containing it gets into the eyes before it sets
  • Transient tightness or flaking when a high level of the polymer forms a strong film on dry skin
  • Rare clogged pores when used in heavy leave on creams for acne prone users

If you notice any of the symptoms above stop using the product and consult a healthcare professional or dermatologist.

Comedogenic Rating

Rating: 1 / 5

Polyacrylate-33 is a large, water-dispersible polymer that sits on the surface rather than sinking into pores. It carries no fatty acids or oils that feed acne-causing bacteria and is used at low levels, which keeps its pore-blocking potential minimal. The slight chance of clogged pores comes when it forms a thick film in rich leave-on products, so most gels and lotions pose little risk.

Overall it is usually fine for skin that breaks out easily, though very acne-prone users may prefer lighter textures to stay on the safe side.

Formulation style matters more than the ingredient itself. A lightweight gel with Polyacrylate-33 is unlikely to cause issues while a heavy cream packed with butters plus the same polymer might feel occlusive.

Summary

Polyacrylate-33’s main job is to control viscosity, giving creams, gels and serums a smooth body that spreads well and resists separation. It does this by swelling in water and lightly gelling the formula, locking oil and water droplets in place so the product stays stable from factory line to bathroom shelf.

The ingredient is a quiet workhorse rather than a trending superstar, yet its reliable thickening power keeps it in countless everyday products that need a clean, nongreasy feel.

Current safety data classifies Polyacrylate-33 as low risk with minimal irritation potential at typical use levels. As with any new cosmetic, it is smart to patch test first to confirm your skin agrees before applying it all over.

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