Polyacrylate-42: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Polyacrylate-42?

Polyacrylate-42 is a synthetic copolymer built from a mix of acrylic acid, butyl acrylate, t-butyl acrylate, ethylhexyl acrylate, maleic acid, methyl styrene and styrene. When these small building blocks are linked together they create long repeating chains that form a lightweight flexible film on skin or hair. The ingredient traces its cosmetic use back to the late 1990s when formulators searched for easy to spread alternatives to traditional gums and resins. Modern production relies on controlled free-radical polymerization carried out in water or solvent. The individual monomers are fed into a reactor, triggered to join, then purified to remove unreacted material and solvents, leaving a smooth white powder or milky liquid dispersion. Polyacrylate-42 shows up most often in leave-on products such as moisturizers, primers, sunscreens, styling gels, sheet masks, BB creams, anti-aging serums and waterproof make-up where a thin flexible film is needed.

Polyacrylate-42’s Cosmetic Benefits/Uses

As a film forming agent Polyacrylate-42 creates an invisible breathable layer that locks in moisture, smooths surface texture and improves product wear time. This film helps active ingredients stay in place longer, boosts water resistance in sunscreens, stabilizes pigments in make-up and adds light hold to hair styling products without a stiff or sticky feel.

Who Can Use Polyacrylate-42

Polyacrylate-42 is generally friendly to all skin types including dry, oily, combination and sensitive skin because the finished film is light and non-clogging. People with highly reactive or allergy-prone skin should still watch for irritation since the ingredient is synthetic, but it is not known to be a common trigger.

The polymer is made entirely from lab-produced raw materials with no animal by-products so it is suitable for vegans and vegetarians.

No data suggest that Polyacrylate-42 is harmful during pregnancy or while breastfeeding when used topically. This is not medical advice and anyone who is pregnant or nursing should check with a healthcare professional before starting a new cosmetic product just to be safe.

The ingredient does not increase photosensitivity, so it will not make skin more prone to sunburn.

Potential Side Effects/Adverse Reactions

Side effects from topical Polyacrylate-42 can differ from person to person. The points below outline potential reactions, but most users will not notice any problems when the ingredient is used correctly in a finished product.

  • Mild redness or stinging right after application
  • Contact dermatitis in individuals with acrylic or latex allergies
  • Eye irritation if the product accidentally gets into the eyes
  • Build-up on hair leading to dullness if not washed out regularly

If you experience any of the reactions listed above stop using the product and consult a healthcare professional.

Comedogenic Rating

Rating: 1/5 (very low)

Polyacrylate-42 is a large water-soluble polymer that stays on the surface of skin rather than seeping into pores. It forms a weightless breathable film that is unlikely to trap excess oil or dead cells, so the risk of clogged pores is minimal. The rating is not a perfect zero because any film former can theoretically hold debris against skin if layered over rich occlusive creams. On its own the ingredient is generally considered suitable for acne-prone or breakout-prone users. If breakouts occur they are more likely linked to other ingredients in the formula than to Polyacrylate-42 itself.

Summary

Polyacrylate-42 is primarily a film former that locks in moisture smooths texture extends wear time of makeup and boosts water resistance in sunscreens while adding light flexible hold to hair products. It delivers these benefits by creating an invisible polymer network that sits evenly across skin or hair without a heavy feel.

The ingredient enjoys steady but quiet popularity among formulators because it is inexpensive easy to process and compatible with many actives, yet it rarely makes marketing headlines the way buzzy botanicals do.

Overall safety is high with low irritation potential and virtually no comedogenicity for most users. As with any new cosmetic it is wise to perform a quick patch test when trying a product that contains Polyacrylate-42 just to be cautious.

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