Polyglyceryl-10 Hexacaprylate/Caprate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Polyglyceryl-10 Hexacaprylate/Caprate?

Polyglyceryl-10 Hexacaprylate/Caprate is a plant-derived ingredient created by linking ten glycerin units to fatty acids that come from coconut or palm oil. The result is a hexaester, which simply means six fatty acid chains are attached to the polyglycerin backbone. This smart pairing of water-loving glycerin and oil-loving caprylic and capric acids gives the molecule an excellent balance of hydration and mild cleansing power.

The cosmetic industry began exploring polyglyceryl esters in the 1990s as gentler alternatives to traditional surfactants and emulsifiers. As green beauty grew, suppliers refined the process for making versions like Polyglyceryl-10 Hexacaprylate/Caprate that rely on renewable plant oils and avoid ethoxylation. Production involves heating plant-based fatty acids with polyglycerin in the presence of a food-grade catalyst, then purifying the finished ester.

You will usually find this ingredient in lightweight facial moisturizers, hydrating toners, makeup removers, creamy cleansers, micellar waters and rinse-off masks where brands want a soft, non-greasy feel with gentle cleansing ability.

Polyglyceryl-10 Hexacaprylate/Caprate’s Cosmetic Benefits/Uses

In formulas this multitasker pulls its weight in several ways:

  • Skin conditioning: At low levels it helps water bind to the surface of the skin, leaving it feeling smooth and comfortable rather than tight after cleansing.
  • Emollient: The fatty acid portion softens rough patches and gives products a silky slip that spreads easily without a heavy or oily after-feel.
  • Cleansing: Its amphiphilic structure lifts away makeup, sunscreen and daily grime while staying mild enough for sensitive skin, making it a popular choice in micellar waters and gentle face washes.

Who Can Use Polyglyceryl-10 Hexacaprylate/Caprate

This ingredient is considered friendly for all major skin types. Its light emollient touch works well for normal and combination skin while the added moisture helps soothe dry or mature skin. Oily and acne-prone users generally tolerate it because it has a low tendency to clog pores and rinses away clean. People with very sensitive or reactive skin also tend to do well with it since it lacks harsh surfactants and fragrance.

Polyglyceryl-10 Hexacaprylate/Caprate is sourced from plant oils and contains no animal-derived materials so it meets vegan and vegetarian standards.

Current data shows no specific risk for women who are pregnant or breastfeeding when this ingredient is used topically at normal cosmetic levels. Still, this is not medical advice and anyone who is pregnant or nursing should ask a healthcare professional before adding new skincare products just to be safe.

The molecule is non-photosensitizing, meaning it does not make skin more prone to sunburn. Standard daily sunscreen habits are still recommended, but no extra precautions are needed because of this ingredient.

Potential Side Effects/Adverse Reactions

Responses to topical Polyglyceryl-10 Hexacaprylate/Caprate vary from person to person. The effects listed below are possible yet uncommon when the ingredient is used in well-formulated products.

  • Mild redness or irritation in individuals with extremely sensitive skin
  • Rare cases of stinging if applied to broken or compromised skin barriers
  • Allergic contact dermatitis in people with a specific sensitivity to coconut or palm derivatives

If you experience any persistent irritation or discomfort stop using the product and consult a healthcare professional.

Comedogenic Rating

Rating: 1 out of 5

The short, lightweight caprylic and capric chains combined with a highly water-friendly polyglycerin backbone make this ester easy to rinse and unlikely to build up inside pores. Its mild surfactant action further helps lift excess oil away, so it scores very low on the comedogenic scale.

With this rating it is considered suitable for acne-prone or breakout-prone skin.

In fact formulators often add it to high-oil cleansers to improve rinse-off, which can lower the overall clogging potential of a finished product.

Summary

Polyglyceryl-10 Hexacaprylate/Caprate conditions skin, softens rough spots and gently lifts away makeup by pairing moisture-drawing glycerin units with oil-dissolving fatty acids. This dual nature lets it hydrate and cleanse at the same time without leaving a greasy film.

While not a buzzword ingredient it has quietly gained popularity in modern micellar waters, lightweight creams and clean beauty formulas thanks to its plant origin and PEG-free profile.

Safety reviews show a low risk of irritation or pore clogging at normal cosmetic levels and global authorities allow its use without strict limits. Still, patch testing any new product that contains it is a smart habit to make sure your individual skin stays happy.

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