Polyglyceryl-2 Tetrabehenate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Polyglyceryl-2 Tetrabehenate?

Polyglyceryl-2 Tetrabehenate is a plant-derived ester made by linking two glycerin molecules to behenic acid, a fatty acid commonly sourced from canola or rapeseed oil. Chemically it sits in the family of polyglycerin fatty acid esters, ingredients known for pairing the moisture-loving nature of glycerin with the softening feel of long-chain fatty acids. It first appeared in skincare in the early 2000s when formulators looked for alternatives to petroleum-based emollients that still offered a rich cushion on the skin. To create it, manufacturers heat and condense glycerin until it forms short chains, then react those chains with behenic acid under vacuum. The result is a waxy, biodegradable material that melts easily into creams. You will often spot Polyglyceryl-2 Tetrabehenate in moisturizers, overnight masks, barrier-repair balms, creamy foundations and age-defying eye treatments where a velvety afterfeel is desired.

Polyglyceryl-2 Tetrabehenate’s Cosmetic Benefits/Uses

This ingredient serves a single but valuable role in skincare.

As a skin-conditioning agent it glides over the surface forming a light, flexible film that slows water loss, leaving skin feeling smoother and more supple. Its fatty structure adds a plush texture to formulas so creams feel rich without turning greasy. Over time regular use can help soften rough patches and boost overall comfort for dry or compromised skin.

Who Can Use Polyglyceryl-2 Tetrabehenate

This silky emollient suits most skin types. Dry, normal and combination complexions tend to love its cushioning feel while sensitive skin usually tolerates it because it is free of added fragrance and common irritants. Oily or acne-prone users can still use it in low concentrations although very heavy balms rich in fatty esters may feel too occlusive for those who dislike any residue.

The molecule is manufactured from vegetable glycerin and plant-sourced behenic acid, so it fits vegan and vegetarian lifestyles with no animal by-products involved.

Current safety data shows no concerns for pregnancy or breastfeeding when the ingredient is used topically in cosmetic amounts. This is not medical advice and anyone who is pregnant or nursing should check with a healthcare professional before adding new products to their routine.

Polyglyceryl-2 Tetrabehenate does not absorb UV light and does not increase photosensitivity. It is also odorless which makes it a good pick for people avoiding added fragrance.

Potential Side Effects/Adverse Reactions

Reactions to Polyglyceryl-2 Tetrabehenate vary from person to person. The following is a list of potential side effects that may occur in rare cases. When the ingredient is formulated and used correctly most people will not experience any problems.

  • Mild skin irritation such as redness or itching
  • Contact allergy resulting in localized rash
  • Temporary clogged pores in individuals very prone to comedones
  • Stinging if applied to broken or highly inflamed skin
  • Eye irritation if the product migrates into the eye area

If any of these effects occur discontinue use and seek guidance from a healthcare professional.

Comedogenic Rating

Rating: 1/5 (low likelihood of clogging pores)

Polyglyceryl-2 Tetrabehenate has a large molecular size and stays mostly on the surface of the skin, so it is not readily absorbed into pores. Its fatty acid chain is long and waxy which gives slip without the heavy, sticky feel linked to more comedogenic oils. Most formulation data and anecdotal reports show few breakout complaints even when used daily.

Because of this low score the ingredient is generally considered fine for people prone to acne, provided the overall product is not loaded with other high-comedogenic ingredients.

Keep in mind that thickness of the finished formula, how often it is applied and individual skin chemistry can all shift real-world results.

Summary

Polyglyceryl-2 Tetrabehenate functions as a skin-conditioning emollient. It smooths over the surface forming a light breathable film that slows water loss and leaves skin feeling cushioned and soft. The dual nature of glycerin and behenic acid lets it deliver moisture while adding a velvety, non-greasy finish to creams, balms and color cosmetics.

It is not the most talked-about ingredient on social media but formulators appreciate its plant origin, biodegradable profile and reliability, so you will quietly find it in many mid to high-end moisturizers and makeup bases.

Current research shows it is safe for topical use with a very low risk of irritation or sensitization. As with any new skincare product a quick patch test is the easiest way to make sure your skin agrees with it before applying to larger areas.

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