Polyglyceryl-20 Docosabehenate/Laurate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Polyglyceryl-20 Docosabehenate/Laurate?

Polyglyceryl-20 Docosabehenate/Laurate is a plant-derived ingredient created by linking twenty glycerin units with a blend of behenic acid, a long-chain fatty acid from sources like rapeseed or peanut oil, and lauric acid, the medium-chain fatty acid famously found in coconut oil. The result is a large, partly water-loving and partly oil-loving molecule that works well in modern skincare formulas. Chemists first explored polyglyceryl esters in the late 20th century as a gentler alternative to traditional surfactants, and this specific ester has grown popular as brands look for biodegradable, PEG-free options.

Manufacturing involves heating glycerin in the presence of an alkaline catalyst to form polyglycerin-20, then reacting it with refined behenic and lauric acids under controlled temperatures. The process yields a waxy, off-white material that melts smoothly into cosmetic bases and is easily dispersed in water-based or oil-based systems.

You will most often spot Polyglyceryl-20 Docosabehenate/Laurate in moisturizers, creamy cleansers, sheet mask essences, lightweight lotions, sunscreens, baby care products and anti-aging serums where a soft skin feel and stable emulsion are desired.

Polyglyceryl-20 Docosabehenate/Laurate’s Cosmetic Benefits/Uses

This multitasking ester supports both the performance and sensory appeal of a formula.

  • Skin Conditioning: Leaves a smooth, soft finish on the skin helping reduce dryness and rough patches
  • Emollient: Forms a thin comforting layer that seals in moisture making the complexion feel supple and less tight
  • Cleansing: Lifts away daily grime and makeup without stripping natural oils resulting in a gentle cleansing experience suitable for sensitive skin
  • Emulsifying: Binds water with oils so lotions and creams stay stable resist separation and maintain a pleasing texture over time

Who Can Use Polyglyceryl-20 Docosabehenate/Laurate

This ingredient is considered gentle and lightweight so it suits most skin types including dry, normal, combination and even sensitive skin that prefers mild, non-stripping formulas. Oily and acne-prone users usually tolerate it well thanks to its non-occlusive texture however very congestion-prone individuals may want to monitor how their skin responds when using richer creams that contain it.

Because it is produced from plant-derived glycerin plus behenic and lauric acids sourced from botanical oils it is suitable for vegans and vegetarians. No animal by-products or animal testing are involved in its standard manufacturing process.

Current safety data show no specific concerns for women who are pregnant or breastfeeding when the ingredient is used topically in cosmetics. This is not medical advice and anyone who is pregnant or nursing should ask their doctor before adding new skincare products just to be safe.

Polyglyceryl-20 Docosabehenate/Laurate is not known to cause photosensitivity so there is no added sun sensitivity risk beyond normal daily UV exposure. It also plays nicely with most actives and preservatives making it a low-maintenance choice in multi-step routines.

Potential Side Effects/Adverse Reactions

Reactions to topical Polyglyceryl-20 Docosabehenate/Laurate differ from person to person. The following are potential side effects that could occur, though they are uncommon when the ingredient is formulated and used as intended.

  • Mild skin irritation such as transient redness or a tingling sensation
  • Contact allergy in rare cases where an individual is sensitive to fatty acids derived from sources like peanut or coconut
  • Clogged pores for users who are extremely prone to comedones when using heavy or multilayered products
  • Eye discomfort if a product containing the ingredient accidentally gets into the eyes

If any negative reaction occurs stop using the product and consult a qualified healthcare professional or dermatologist.

Comedogenic Rating

Rating: 1/5

Although it contains fatty acid components, Polyglyceryl-20 Docosabehenate/Laurate is a large ester molecule that tends to sit on the skin without penetrating deeply or blocking pores. Its job in a formula is to emulsify and soften, not to create a heavy occlusive film, which is why it scores low on the comedogenic scale. This makes it generally suitable for acne-prone or breakout-prone users.

One point to keep in mind is that the finished product’s overall texture matters. When this ester appears in richer balms or butters, other ingredients in the blend may raise the clogging risk even if this specific component is low.

Summary

Polyglyceryl-20 Docosabehenate/Laurate acts as a skin conditioner, emollient, gentle cleanser and reliable emulsifier. Its structure features twenty glycerin units bound to behenic and lauric acids, giving it both water-loving and oil-loving ends so it can pull a formula together while leaving skin soft and comfortable.

The ingredient is gaining traction as brands look for plant-derived PEG-free options, yet it is still relatively niche compared with long-established emulsifiers. Those who have discovered it often praise the light velvety feel it lends to creams and cleansers.

Current safety data show it is low risk for irritation or sensitization when used as directed. As with any new skincare addition, patch testing a small area first is a smart habit to confirm personal compatibility.

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