Polyglyceryl-3 Caprylate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Polyglyceryl-3 Caprylate?

Polyglyceryl-3 Caprylate is a plant-derived ingredient created by linking three glycerin molecules to caprylic acid, a fatty acid usually sourced from coconut or sustainable palm oil. The result is an ester known as triglyceryl monocaprylate that mixes the skin-friendly nature of glycerin with the oil-loving character of caprylic acid. Interest in mild, biodegradable cleansers grew in the 1990s and chemists began turning to polyglycerol esters like this one to replace harsher surfactants. Manufacturing starts with food-grade glycerin that is heated to form short chains called polyglycerols. These chains are then reacted with purified caprylic acid under controlled temperatures to create the final ester without the need for solvents. Thanks to its gentle profile it now appears in micellar waters, gel and milk cleansers, makeup removers, lightweight lotions, hydrating masks, baby wipes and even natural deodorant sticks.

Polyglyceryl-3 Caprylate’s Cosmetic Benefits/Uses

This multitasker improves both the feel and performance of many formulas

  • Cleansing: Its amphiphilic structure lifts away makeup, sunscreen and excess oil while staying mild enough for sensitive skin so products feel soft rather than stripped
  • Emulsifying: Helps blend water and oil into a stable mixture which allows brands to create light textures without synthetic PEGs while preventing separation over time

Who Can Use Polyglyceryl-3 Caprylate

This ingredient suits nearly all skin types including dry, oily, combination and sensitive because it cleanses without stripping natural moisture. Those with very reactive or allergy-prone skin usually tolerate it well since it has a low irritation profile, though individual allergies are always possible.

Polyglyceryl-3 Caprylate is made from plant-derived glycerin and coconut or sustainable palm oil, so it is suitable for vegans and vegetarians. No animal by-products or animal testing are required to produce it when sourced from cruelty-free suppliers.

Current research shows no known risks for pregnant or breastfeeding women when the ingredient is used in rinse-off or leave-on cosmetics at typical levels. This is not medical advice and anyone who is pregnant or nursing should always check new products with a doctor to be safe.

The molecule does not increase sun sensitivity and will not interfere with SPF products. It also works well alongside common actives such as vitamin C, retinoids and niacinamide without destabilizing them.

Potential Side Effects/Adverse Reactions

Side effects from topical Polyglyceryl-3 Caprylate can vary from person to person. The issues listed below are possible but unlikely for most users when the ingredient is formulated correctly.

  • Mild redness or stinging on very sensitive or broken skin
  • Allergic contact dermatitis in individuals allergic to coconut or palm derivatives
  • Temporary eye irritation if a cleanser containing it is rubbed into the eyes
  • Rare clogged pores if used in an overly rich formula on acne-prone skin

If you notice any discomfort stop using the product and consult a healthcare professional or dermatologist.

Comedogenic Rating

Rating: 1 / 5

Polyglyceryl-3 Caprylate earns a very low score because it is an ester that rinses clean and has a light molecular structure that does not stay on the skin in a thick oily film. It helps remove excess sebum rather than adding to it, and formulators typically use it at modest percentages. For these reasons it is considered generally suitable for people who are prone to acne or breakouts.

Its rating can creep higher if it appears in a heavy cream packed with other rich emollients, so the overall formula matters more than the ingredient alone.

Summary

Polyglyceryl-3 Caprylate acts as a gentle cleanser and a plant derived emulsifier. Its amphiphilic nature lets the glycerin part grab water while the caprylic tail loves oil, so it can surround dirt or makeup then lift it away while also holding oil and water together in smooth stable lotions.

The ingredient is not as famous as classic surfactants like sodium laureth sulfate yet it is gaining steady popularity in micellar waters, natural cleansers and baby care thanks to its mildness and eco friendly sourcing.

Overall safety is excellent with a low irritation record and a very low comedogenic rating, but everyone’s skin is different so it is wise to do a small patch test when trying any new product that contains it.

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