Polyglyceryl-4 Olivate/Polyricinoleate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Polyglyceryl-4 Olivate/Polyricinoleate?

Polyglyceryl-4 Olivate/Polyricinoleate is a plant-based ingredient created by joining Polyglycerin-4 with fatty acids from olive oil and polyricinoleic acid from castor oil. The result is a gentle, oil-compatible ester that acts a lot like natural skin lipids. It entered the beauty scene in the early 2000s when formulators began looking for milder, more sustainable alternatives to traditional petroleum or animal-derived emulsifiers. To make it, chemists heat and blend the vegetable-sourced raw materials in a controlled reaction that links them together without using harsh solvents. You will spot this multifunctional helper in lotions, face masks, creamy cleansers, makeup removers, tinted moisturizers, water-resistant sunscreens and many “clean beauty” anti-aging creams that aim for a smooth, rich feel without silicones.

Polyglyceryl-4 Olivate/Polyricinoleate’s Cosmetic Benefits/Uses

This ingredient pulls double duty in formulas, helping products look better, feel better and stay mixed over time

  • Emulsion stabilising: Keeps oil and water phases from separating so creams stay silky and uniform during shelf life and daily use
  • Skin conditioning: Adds a light, moisturizing film that softens skin and boosts the overall comfort of a product without feeling greasy
  • Dispersing: Spreads pigments, sunscreen filters or actives evenly throughout a base giving a consistent color or SPF in every drop
  • Emulsifying: Allows water and oil to blend in the first place making it possible to create smooth lotions and milks without high amounts of synthetic surfactants

Who Can Use Polyglyceryl-4 Olivate/Polyricinoleate

This gentle ester fits most skin types including dry, normal, combination and sensitive skin because it mimics the skin’s own lipids and has a lightweight finish. Those with very oily or acne-prone skin usually tolerate it well too since it helps stabilize low-oil emulsions without leaving a greasy film, though individual responses can vary.

The ingredient is sourced entirely from plants so it is suitable for vegans and vegetarians who prefer to avoid animal-derived additives.

Current safety data show no specific risks for women who are pregnant or breastfeeding when the ingredient is used topically in cosmetic amounts. This is not medical advice and anyone expecting or nursing should still check with a doctor before adding new products just to be safe.

Polyglyceryl-4 Olivate/Polyricinoleate does not absorb UV light or make skin more sensitive to the sun, so it is not considered photosensitizing. It also plays well with most other skincare actives, making it a versatile choice in multi-step routines.

Potential Side Effects/Adverse Reactions

Side effects from topical use of Polyglyceryl-4 Olivate/Polyricinoleate can vary from person to person. The points below outline potential reactions, yet they are uncommon when the ingredient is formulated and used correctly.

  • Mild skin irritation such as stinging or itching
  • Redness or transient flushing in very sensitive skin
  • Contact dermatitis in individuals allergic to olive or castor derivatives
  • Clogged pores or breakouts if used in an overly rich formula on acne-prone skin

If any of these effects occur discontinue use and consult a healthcare professional.

Comedogenic Rating

Rating: 1/5. Polyglyceryl-4 Olivate/Polyricinoleate is built from small glycerin units linked to lightweight fatty acids, which lets it spread thinly and rinse off more easily than whole olive or castor oils. Its molecular size and balanced water-loving and oil-loving parts help prevent it from sitting in pores long enough to cause blockages. Most acne-prone users tolerate it well, though the richness of the full formula still matters. If blended into a very heavy cream it could contribute to congestion, but on its own it is considered low risk.

Suitable for people prone to breakouts in the majority of formulations.

Keep in mind comedogenicity ratings are guidelines for single ingredients tested in isolation. The final product’s overall oil level, thickeners and waxes influence clogging potential far more than this emulsifier does.

Summary

Polyglyceryl-4 Olivate/Polyricinoleate is a plant sourced multifunctional helper that stabilises emulsions, binds oil and water, disperses pigments or UV filters and leaves skin feeling softly conditioned. It manages all of that because its glycerin backbone loves water while its olive and ricinoleic tails love oil, letting it park itself at the oil-water interface and create a smooth, uniform texture.

It enjoys moderate popularity, especially in natural and “clean beauty” lines looking for vegan alternatives to traditional emulsifiers, though it is still less common than long-standing workhorses like polysorbates.

Current data rate the ingredient as low-irritation and non-sensitising for most users, with no flagged reproductive or environmental concerns at cosmetic use levels. As with any new skincare ingredient it is smartest to patch test a product first and watch your skin’s response before committing to daily use.

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