Polyglyceryl-5 Stearate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
Share:
Inside this article:

We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Polyglyceryl-5 Stearate?

Polyglyceryl-5 Stearate is made by linking five glycerin molecules together, then attaching stearic acid, a fatty acid that can be sourced from plants such as palm or coconut. The result is a mild, plant-derived ingredient that helps oil and water blend smoothly. It first appeared in food science as a cleaner alternative to older emulsifiers, and its gentle nature soon caught the eye of cosmetic chemists looking for skin-friendly options. Production involves heating glycerin in the presence of a catalyst to create polyglycerin-5, then reacting this with stearic acid to form the monoester. Because it is naturally free of animal by-products and rated low in irritation, brands use it in a wide range of leave-on and rinse-off products. You will commonly find it in lightweight facial creams, sheet and wash-off masks, daily moisturizers, sun care formulas, creamy cleansers and makeup like foundations or BB creams that need stable texture.

Polyglyceryl-5 Stearate’s Cosmetic Benefits/Uses

In skincare and makeup Polyglyceryl-5 Stearate shines for one main reason.

As an emulsifying agent it keeps oil and water mixed so lotions stay silky and do not separate on the shelf or on your skin. This stability means a product feels smoother, spreads more evenly and delivers its active ingredients in a consistent way from the first use to the last.

Who Can Use Polyglyceryl-5 Stearate

Because it is gentle and non greasy Polyglyceryl-5 Stearate works well for dry oily sensitive and acne prone skin alike. It helps create lightweight emulsions that will not clog pores or leave a heavy film so most complexions tolerate it without trouble. The ingredient is derived from plant based glycerin and stearic acid which makes it suitable for vegans and vegetarians when the finished formula does not include animal sourced co-ingredients.

Current safety data shows no specific risks for women who are pregnant or breastfeeding when this emulsifier is used in normal cosmetic concentrations. Still this is not medical advice and anyone who is expecting or nursing should ask a doctor before adding new products to their routine.

Polyglyceryl-5 Stearate does not increase photosensitivity so it will not make skin more prone to sunburn. It is odorless free of added color and carries a low irritation profile making it compatible with most daily face and body products.

Potential Side Effects/Adverse Reactions

Every skin is unique so reactions to Polyglyceryl-5 Stearate can vary. The points below cover possible side effects but most users will not experience them when the ingredient is used correctly in a well formulated product.

  • Mild irritation a brief feeling of stinging or warmth in very sensitive skin
  • Contact dermatitis rare cases of redness itching or rash in individuals allergic to glycerin derivatives or fatty acids
  • Eye stinging temporary discomfort if a product containing the emulsifier accidentally gets into the eyes

If any uncomfortable reaction occurs stop using the product and seek guidance from a medical professional

Comedogenic Rating

Rating: 1/5

Polyglyceryl-5 Stearate is a large, water-loving molecule that sits mostly on the skin’s surface and does not easily clog pores. While its stearic acid portion has a mild tendency to be comedogenic on its own, turning it into a bulky polyglyceryl ester drastically lowers that risk which is why the overall rating is a low 1. This makes the ingredient generally suitable for people who are prone to acne or breakouts. Only highly reactive or severely congested skin types might want to monitor how their skin responds when first using a product containing it.

Summary

Polyglyceryl-5 Stearate is a plant derived emulsifier that keeps oil and water phases blended so creams remain smooth, stable and pleasant to apply. By linking five glycerin units to stearic acid it offers the perfect balance of water friendliness and oil compatibility helping formulas feel light while maintaining a uniform texture from the first pump to the last. Its popularity sits in the middle of the pack: not as famous as traditional emulsifiers like glyceryl stearate yet increasingly chosen by clean beauty and vegan brands that value its gentle nature and sustainable sourcing.

Safety data shows it to be low in irritation non sensitizing and practically non comedogenic at normal use levels. Even so skin can be unpredictable which is why it is always wise to perform a quick patch test when trying any new product containing Polyglyceryl-5 Stearate.

Was this article helpful?
More from Glooshi:
ADVERTISEMENT
Get all our top headlines in beauty.
Delivered right to your inbox each week. Zero spam, all goodness, opt-out at anytime.
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Get the latest beauty news, top product recommendations & brand-exclusive discount codes direct to your inbox.
Send good feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Send bad feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Search