Polyglyceryl-6 Hexastearate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Polyglyceryl-6 Hexastearate?

Polyglyceryl-6 Hexastearate is a plant-derived ingredient made by linking six glycerin units with six stearic acid molecules. Glycerin can be sourced from vegetable oils while stearic acid often comes from coconut or palm oil. Chemists began exploring polyglyceryl esters in the late twentieth century as a gentler alternative to traditional surfactants, and this particular form gained popularity once formulators noticed its ability to keep oil and water blended without leaving a greasy feel. Production involves heating glycerin so the molecules join into a short chain, then reacting that chain with stearic acid under controlled conditions to form a stable hexaester. Because it is mild and biodegradable, it shows up in many leave-on and rinse-off products such as facial moisturizers, cleansing balms, masks, baby lotions, makeup removers and natural-positioned sunscreens.

Polyglyceryl-6 Hexastearate’s Cosmetic Benefits/Uses

This ingredient is valued for one main job in skin care formulas.

As an emulsifying agent it binds oil and water into a smooth, uniform mixture. This keeps creams from separating, improves texture, enhances spreadability and can reduce the amount of heavier waxes or petrolatum needed. Stable emulsions also help active ingredients disperse more evenly across the skin which can boost overall product performance.

Who Can Use Polyglyceryl-6 Hexastearate

This emulsifier is considered gentle enough for most skin types including dry, normal, combination and oily. Its light feel and non greasy finish make it a good choice for acne-prone skin that often reacts to heavier waxes. Sensitive skin usually tolerates it well since it is free from common irritants like ethoxylated surfactants or fragrances. There are no specific skin types that need to avoid it unless an individual has a proven allergy to stearic acid derivatives.

Because the glycerin backbone and stearic acid can be sourced from plants, suppliers often label the ingredient as suitable for vegans and vegetarians. When shopping, look for brands that confirm their raw materials are plant derived rather than animal tallow.

No data links Polyglyceryl-6 Hexastearate to hormonal effects, so it is generally viewed as safe for pregnant or breastfeeding women. This is not medical advice and anyone who is expecting or nursing should clear new skincare products with a doctor first just to be safe.

The ingredient does not increase photosensitivity, so it will not make skin more prone to sunburn. Standard daytime sun protection is still recommended for overall skin health.

Potential Side Effects/Adverse Reactions

Reactions to topical Polyglyceryl-6 Hexastearate differ from person to person. The effects listed below are possible yet uncommon when the ingredient is used correctly in a finished cosmetic product.

  • Mild redness or stinging on very sensitive skin
  • Contact dermatitis in individuals allergic to stearic acid derivatives
  • Eye irritation if a product containing the ingredient accidentally gets into the eyes

If you notice irritation or any persistent discomfort stop using the product and seek advice from a healthcare professional.

Comedogenic Rating

On the standard 0 to 5 scale Polyglyceryl-6 Hexastearate rates around a 1. While stearic acid on its own can lean toward pore clogging, once it is bound to the polyglycerin backbone the molecule becomes larger and less likely to get trapped in follicles. It is also used at modest percentages and leaves a light, non greasy finish.

With such a low score the ingredient is considered fine for skin that is prone to acne or breakouts.

Keep in mind overall formulation still matters. If the rest of the product is heavy or waxy it could override the low risk profile of this single ingredient, so always take the full ingredient list into account.

Summary

Polyglyceryl-6 Hexastearate is a plant based emulsifier that keeps oil and water phases blended, smooths texture and helps spread active ingredients evenly across the skin. It does this by anchoring its water loving polyglycerin side in the water phase and its oil loving stearate side in the oil phase, locking the two together.

Although not as well known as classic emulsifiers like polysorbates it is gaining popularity in clean beauty, baby care and lightweight moisturizers thanks to its gentle nature and biodegradability.

Current research and real world use point to a very low risk of irritation or comedogenicity. Still, every skin type is unique, so perform a small patch test when trying any new product that contains this ingredient to stay on the safe side.

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